EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data on potential hazardous substances, despite the fact that some data might not be related to pollution (e.g. collected by deep corer). Temperature, salinity and additional parameters are included when available. It covers the Mediterranean Sea. Data were harmonised and validated by the ‘Hellenic Centre for Marine Research, Hellenic National Oceanographic Data Centre (HCMR/HNODC)’ in Greece. The dataset contains water, sediment and biota profiles and timeseries. The temporal coverage is 1974–2020 for water measurements, 1971–2020 for sediment measurements and 1979-2021 for biota measurements. Regional datasets concerning contaminants are automatically harvested and the resulting collections are harmonised and validated using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.6092/8b52e8d7-dc92-4305-9337-7634a5cae3f4). Parameter names are based on P01 vocabulary, which relates to BODC Parameter Usage Vocabulary and is available at: https://vocab.nerc.ac.uk/search_nvs/P01/. The harmonised dataset can be downloaded as as an ODV spreadsheet, which is composed of a metadata header followed by tab separated values. This spreadsheet can be imported into ODV Software for visualisation (more information can be found at: https://www.seadatanet.org/Software/ODV). In addition, the same dataset is offered also as a txt file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms into subcomponents (substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications (e.g. LibreOffice Calc).

'''DEFINITION''' The OMI_EXTREME_SST_MEDSEA_sst_mean_and_anomaly_obs indicator is based on the computation of the 99th and the 1st percentiles from in situ data (observations). It is computed for the variable sea surface temperature measured by in situ buoys at depths between 0 and 5 meters. The use of percentiles instead of annual maximum and minimum values, makes this extremes study less affected by individual data measurement errors. The percentiles are temporally averaged, and the spatial evolution is displayed, jointly with the anomaly in the target year. This study of extreme variability was first applied to sea level variable (Pérez Gómez et al 2016) and then extended to other essential variables, sea surface temperature and significant wave height (Pérez Gómez et al 2018). '''CONTEXT''' Sea surface temperature (SST) is one of the essential ocean variables affected by climate change (mean SST trends, SST spatial and interannual variability, and extreme events). In Europe, several studies show warming trends in mean SST for the last years (von Schuckmann et al., 2016; IPCC, 2021, 2022). An exception seems to be the North Atlantic, where, in contrast, anomalous cold conditions have been observed since 2014 (Mulet et al., 2018; Dubois et al. 2018; IPCC 2021, 2022). Extremes may have a stronger direct influence in population dynamics and biodiversity. According to Alexander et al. 2018 the observed warming trend will continue during the 21st Century and this can result in exceptionally large warm extremes. Monitoring the evolution of sea surface temperature extremes is, therefore, crucial.The Mediterranean Sea has showed a constant increase of the SST in the last three decades across the whole basin with more frequent and severe heat waves (Juza et al., 2022). Deep analyses of the variations have displayed a non-uniform rate in space, being the warming trend more evident in the eastern Mediterranean Sea with respect to the western side. This variation rate is also changing in time over the three decades with differences between the seasons (e.g. Pastor et al. 2018; Pisano et al. 2020), being higher in Spring and Summer, which would affect the extreme values. '''COPERNICUS MARINE SERVICE KEY FINDINGS''' The mean 99th percentiles showed in the area present values from 25ºC in Ionian Sea and 26º in the Alboran sea and Gulf of Lion to 27ºC in the East of Iberian Peninsula. The standard deviation ranges from 0.6ºC to 1.2ºC in the Western Mediterranean and is around 2.2ºC in the Ionian Sea. Results for this year show a slight negative anomaly in the Ionian Sea (-1ºC) inside the standard deviation and a clear positive anomaly in the Western Mediterranean Sea reaching +2.2ºC, almost two times the standard deviation in the area. '''DOI (product):''' https://doi.org/10.48670/moi-00267

Here, our study aimed to first assess the influence of plastic on the bacterial community belonging to water, plastic and the microbiome of the giant clam and on the organism's physiology of this putative sentinel species. Our second objective was to identify bacteria whose abundance varies significantly with plastic concentration. Overall, this study will fill the gap towards a better understanding of the impact of plastic pollution on bacterial community assemblages in both inert and living environments.

This product displays for Cadmium, median values of the last 6 available years that have been measured per matrix and are present in EMODnet regional contaminants aggregated datasets, v2022. The median values ranges are derived from the following percentiles: 0-25%, 25-75%, 75-90%, >90%. Only "good data" are used, namely data with Quality Flag=1, 2, 6, Q (SeaDataNet Quality Flag schema). For water, only surface values are used (0-15 m), for sediment and biota data at all depths are used.

This product displays for Naphthalene, positions with values counts that have been measured per matrix for each year and are present in EMODnet regional contaminants aggregated datasets, v2022. The product displays positions for every available year.

'''DEFINITION''' The OMI_EXTREME_WAVE_NORTHWESTSHELF_swh_mean_and_anomaly_obs indicator is based on the computation of the 99th and the 1st percentiles from in situ data (observations). It is computed for the variable significant wave height (swh) measured by in situ buoys. The use of percentiles instead of annual maximum and minimum values, makes this extremes study less affected by individual data measurement errors. The percentiles are temporally averaged, and the spatial evolution is displayed, jointly with the anomaly in the target year. This study of extreme variability was first applied to sea level variable (Pérez Gómez et al 2016) and then extended to other essential variables, sea surface temperature and significant wave height (Pérez Gómez et al 2018). '''CONTEXT''' Projections on Climate Change foresee a future with a greater frequency of extreme sea states (Stott, 2016; Mitchell, 2006). The damages caused by severe wave storms can be considerable not only in infrastructure and buildings but also in the natural habitat, crops and ecosystems affected by erosion and flooding aggravated by the extreme wave heights. In addition, wave storms strongly hamper the maritime activities, especially in harbours. These extreme phenomena drive complex hydrodynamic processes, whose understanding is paramount for proper infrastructure management, design and maintenance (Goda, 2010). In recent years, there have been several studies searching possible trends in wave conditions focusing on both mean and extreme values of significant wave height using a multi-source approach with model reanalysis information with high variability in the time coverage, satellite altimeter records covering the last 30 years and in situ buoy measured data since the 1980s decade but with sparse information and gaps in the time series (e.g. Dodet et al., 2020; Timmermans et al., 2020; Young & Ribal, 2019). These studies highlight a remarkable interannual, seasonal and spatial variability of wave conditions and suggest that the possible observed trends are not clearly associated with anthropogenic forcing (Hochet et al. 2021, 2023). In the North Atlantic, the mean wave height shows some weak trends not very statistically significant. Young & Ribal (2019) found a mostly positive weak trend in the European Coasts while Timmermans et al. (2020) showed a weak negative trend in high latitudes, including the North Sea and even more intense in the Norwegian Sea. For extreme values, some authors have found a clearer positive trend in high percentiles (90th-99th) (Young et al., 2011; Young & Ribal, 2019). '''COPERNICUS MARINE SERVICE KEY FINDINGS''' The mean 99th percentiles showed in the area present a wide range from 2.5 meters in the English Channel with 0.3m of standard deviation (std), 3-5m in the southern and central North Sea with 0.3-0.6m of std, 4 meters in the Skagerrak Strait with 0.6m of std, 6-7m in the northern North Sea with 0.4-0.5m of std to 8 meters in the NorthWest of the British Isles with 0.8-1.0m of std. Results for this year show either low positive or negative anomalies between -0.3m and +0.4m, inside the margin of the standard deviation, in the English Channel, the Skagerrak Strait and the southern and central North Sea except in the station 6200046 with a positive anomaly of 0.8m and a slight negative anomaly (-0.1/-0.5m) inside the margin of the std in the NorthWest of the British Isles and the northern North Sea. '''DOI (product):''' https://doi.org/10.48670/moi-00270

This product displays for Hexachlorobenzene, median values of the last 6 available years that have been measured per matrix and are present in EMODnet regional contaminants aggregated datasets, v2022. The median values ranges are derived from the following percentiles: 0-25%, 25-75%, 75-90%, >90%. Only "good data" are used, namely data with Quality Flag=1, 2, 6, Q (SeaDataNet Quality Flag schema). For water, only surface values are used (0-15 m), for sediment and biota data at all depths are used.

This visualization product displays beaches locations where the Marine Strategy Framework Directive (MSFD) monitoring protocol has been applied to collate data on macrolitter (> 2.5 cm). Reference lists associated with these protocols have been indicated with different colors in the map. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of beach litter have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols and reference lists used on a European scale. Preliminary processing were necessary to harmonize all the data: - Exclusion of OSPAR 1000 protocol: in order to follow the approach of OSPAR that it is not including these data anymore in the monitoring; - Selection of MSFD surveys only (exclusion of other monitoring, cleaning and research operations); - Exclusion of beaches without coordinates; - Some categories & some litter types like organic litter, small fragments (paraffin and wax; items > 2.5cm) and pollutants have been removed. The list of selected items is attached to this metadata. This list was created using EU Marine Beach Litter Baselines and EU Threshold Value for Macro Litter on Coastlines from JRC (these two documents are attached to this metadata). More information is available in the attached documents. Warning: the absence of data on the map doesn't necessarily mean that they don't exist, but that no information has been entered in the Marine Litter Database for this area.

This visualization product displays the location of all the surveys present in the EMODnet marine litter database (MLDB). The different fishing gears used are represented by different colors. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of seafloor litter collected by international fish-trawl surveys have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols (OSPAR and MEDITS protocols) and reference lists used on a European scale. Moreover, within the same protocol, different gear types are deployed during fishing bottom trawl surveys. Unlike other EMODnet seafloor litter products, all trawls surveyed since 2006 are included in this map even if the wingspread and/or the distance are unknown. Only surveys with an unknown number of items were excluded from this product. More information on data processing and calculation are detailed in the document attached. Warning: the absence of data on the map doesn't necessarily mean that they don't exist, but that no information has been entered in the Marine Litter Database for this area.

Moving 6-year analysis of Water body chlorophyll-a in the Mediterranean Sea for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 6-year centered average of the season. 6-years periods span from 1990-1995 until 2016-2021. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Units: mg/m3. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.9, using GEBCO 30sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.125 degrees (around 13.5km and 10.9km accordingly). The vertical resolution is 20 depth levels: [0.,5.,10.,20.,30.,50.,75.,100.,125.,150.,200.,250.,300.,400.,500.,600.,700.,800.,900.,1000.]. The horizontal correlation length is 200km. The vertical correlation length (in meters) was set twices the vertical resolution: [10.,10.,20.,20.,40.,50.,50.,50.,50.,100.,100.,100.,200.,200.,200.,200.,200.,200.,200.,200.]. Duplicates check was performed using the following criteria for space and time: dlon=0.001deg., dlat=0.001deg., ddepth=1m, dtime=1hour, dvalue=0.1. The error variance (epsilon2) was set equal to 1 for profiles and 10 for time series to reduce the influence of close data near the coasts. An anamorphosis transformation was applied to the data (function DIVAnd.Anam.loglin) to avoid unrealistic negative values: threshold value=200. A background analysis field was used for all years (1990-2021) with correlation length equal to 600km and error variance (epsilon2) equal to 20. Quality control of the observations was applied using the interpolated field (QCMETHOD=3). Residuals (differences between the observations and the analysis (interpolated linearly to the location of the observations) were calculated. Observations with residuals outside the minimum and maximum values of the 99% quantile were discarded from the analysis. Originators of Italian data sets-List of contributors: - Brunetti Fabio (OGS) - Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 - Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 - Cataletto Bruno (OGS) - Cinzia Comici Cinzia (OGS) - Civitarese Giuseppe (OGS) - DeVittor Cinzia (OGS) - Giani Michele (OGS) - Kovacevic Vedrana (OGS) - Mosetti Renzo (OGS) - Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 - Celio Massimo (ARPA FVG) - Malaguti Antonella (ENEA) - Fonda Umani Serena (UNITS) - Bignami Francesco (ISAC/CNR) - Boldrini Alfredo (ISMAR/CNR) - Marini Mauro (ISMAR/CNR) - Miserocchi Stefano (ISMAR/CNR) - Zaccone Renata (IAMC/CNR) - Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D.,Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d'Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011.