'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces Level-4 product includes monthly averaged datasets of the diffuse attenuation coefficient of light at 490 nm (Kd490) for multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI observations (at 300m resolution). Kd490 is the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates the water column. It is directly related to the presence of absorbing and scattering matter in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. For the multi-sensor dataset, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by the GOS. The QAA allows the inversion of the radiative transfer equations to compute the Inherent Optical Properties. Level-4 product includes monthly averages along with the standard deviation and the number of observations in the period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Time averages are computed on the delayed-time data. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names :''' *dataset-oc-med-opt-multi-l4-kd490_1km_monthly-rt-v02 *dataset-oc-med-opt-olci-l4-kd490_300m_monthly-rt '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00117

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Level-4 product including the daily interpolated chlorophyll field with no data voids starting from the multi-sensor (MODIS-Aqua, NOAA-20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI), the monthly averaged chlorophyll concentration for the multi-sensor and climatological fields, all at 1 km resolution. Chlorophyll field are obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. The interpolated gap-free Level-4 Chl concentration is estimated by means of a modified version of the DINEOF algorithm by GOS (Volpe et al., 2018). DINEOF is an iterative procedure in which EOF are used to reconstruct the entire field domain. As first guess, it uses the SeaWiFS-derived daily climatological values at missing pixels and satellite observations at valid pixels. Monthly Level-4 dataset is the time averages of the L3 fields and includes the standard deviation and the number of observations in the monthly period of integration. SeaWiFS daily climatology provides reference for the calculation of Quality Indices (QI) for Chl observations. '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll) are estimated via state-of-the-art algorithms for better product quality. Level-4 includes both monthly time averages and the daily-interpolated fields. Time averages are computed on the delayed-time data. The interpolated product starts from the L3 products at 1 km resolution. At the first iteration, DINEOF procedure uses, as first guess for each of the missing pixels the relative daily climatological pixel. A procedure to smooth out spurious spatial gradients is applied to the daily merged image (observation and climatology). From the second iteration, the procedure uses, as input for the next one, the field obtained by the EOF calculation, using only a number of modes: that is, at the second round, only the first two modes, at the third only the first three, and so on. At each iteration, the same smoothing procedure is applied between EOF output and initial observations. The procedure stops when the variance explained by the current EOF mode exceeds that of noise. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). For the climatology Rrs data are derived from the latest SeaWiFS NASA reprocessing (R2018.0) and converted to chlorophyll concentrations with the same algorithm as the one used for other L4 and/or L3 products. '''Description of observation methods/instruments:''' Ocean color technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean color which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of both the cal/val and a more in depth view of the method is given in QUID-009-038to045-071-073-078-079-095-096.pdf over Copernicus web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l4-chl_1km_monthly-rep-v02 *dataset-oc-med-chl-multi-l4-interp_1km_daily-rep *dataset-oc-med-chl-seawifs-l4-chl_1km_daily-climatology-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant. '''DOI (product) :''' https://doi.org/10.48670/moi-00114

'''DEFINITION''' The time series are derived from the regional chlorophyll reprocessed (MY) product as distributed by CMEMS. This dataset, derived from multi-sensor (SeaStar-SeaWiFS, AQUA-MODIS, NOAA20-VIIRS, NPP-VIIRS, Envisat-MERIS and Sentinel3-OLCI) Rrs spectra produced by CNR using an in-house processing chain, is obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 (off-shore) waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 (coastal) waters, Berthon and Zibordi, 2004). The processing chain and the techniques used for algorithms merging are detailed in Colella et al. (2023). Monthly regional mean values are calculated by performing the average of 2D monthly mean (weighted by pixel area) over the region of interest. The deseasonalized time series is obtained by applying the X-11 seasonal adjustment methodology on the original time series as described in Colella et al. (2016), and then the Mann-Kendall test (Mann, 1945; Kendall, 1975) and Sens’s method (Sen, 1968) are subsequently applied to obtain the magnitude of trend. '''CONTEXT''' Phytoplankton and chlorophyll concentration as a proxy for phytoplankton respond rapidly to changes in environmental conditions, such as light, temperature, nutrients and mixing (Colella et al. 2016). The character of the response depends on the nature of the change drivers, and ranges from seasonal cycles to decadal oscillations (Basterretxea et al. 2018). Therefore, it is of critical importance to monitor chlorophyll concentration at multiple temporal and spatial scales, in order to be able to separate potential long-term climate signals from natural variability in the short term. In particular, phytoplankton in the Mediterranean Sea is known to respond to climate variability associated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al. 2018, Colella et al. 2016). '''CMEMS KEY FINDINGS''' In the Mediterranean Sea, the trend average for the 1997-2022 period is slightly negative (-0.69±0.69% per year) confirm the results obtained from previous release (1997-2021). This result is in contrast with the analysis of Sathyendranath et al. (2018) that reveals an increasing trend in chlorophyll concentration in all the European Seas. Starting from 2010-2011, except for 2018-2019, the decrease of chlorophyll concentrations is quite evident in the deseasonalized timeseries (in green), and in the maxima of the observations (grey line), starting from 2015. This attenuation of chlorophyll values of the last decade, results in an overall negative trend for the Mediterranean Sea. '''Figure caption''' Mediterranean Sea time series and trend (1997-2022) of satellite chlorophyll, based on CMEMS product OCEANCOLOUR_MED_BGC_L4_MY_009_144. The monthly regional average (weighted by pixel area) time series is shown in grey, with the deseasonalized time series in green and the trend in blue. '''DOI (product):''' https://doi.org/10.48670/moi-00259

'''Short description:''' For the '''Mediterranean Sea''' Ocean '''Satellite Observations''', the Italian National Research Council (CNR – Rome, Italy), is providing multi-years '''Bio-Geo_Chemical (BGC)''' regional datasets: * '''''plankton''''' with the phytoplankton chlorophyll concentration (CHL) evaluated via region-specific algorithms (Case 1 waters: Volpe et al., 2019, with new coefficients; Case 2 waters, Berthon and Zibordi, 2004), and the interpolated '''gap-free''' Chl concentration (to provide a "cloud free" product) estimated by means of a modified version of the DINEOF algorithm (Volpe et al., 2018); moreover, daily climatology for chlorophyll concentration is provided. * '''''pp''''' with the Integrated Primary Production (PP). '''Upstreams''': SeaWiFS, MODIS, MERIS, VIIRS-SNPP & JPSS1, OLCI-S3A & S3B for the '''"multi"''' products, and OLCI-S3A & S3B for the '''"olci"''' products '''Temporal resolutions''': monthly and daily (for '''"gap-free"''' and climatology data) '''Spatial resolution''': 1 km for '''"multi"''' and 300 meters for '''"olci"''' To find this product in the catalogue, use the search keyword '''"OCEANCOLOUR_MED_BGC_L4_MY"'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00300

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes surface chlorophyll concentration (mg m-3) derived from multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, and Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI (at high resolution, 300m) Rrs spectra. Chlorophyll datasets are obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum at pixel-by-pixel level with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case 1 and Case 2 information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. This product identifies the average chlorophyll content of the surface layer as defined by the first optical depth (roughly one fifth of the euphotic depth). For multi-sensor observations, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. The current day data temporal consistency is evaluated as Quality Index (QI): QI=(CurrentDataPixel-ClimatologyDataPixel)/STDDataPixel where QI is the difference between current data and the relevant climatological field as a signed multiple of climatological standard deviations (STDDataPixel). '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour, which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l3-chl_1km_daily-rt-v02 *dataset-oc-med-chl-olci-l3-chl_300m_daily-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00111

'''DEFINITION''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) produced by the Plymouth Marine Laboratory (PML) using the ESA Ocean Colour Climate Change Initiative processor (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT''' Phytoplankton and chlorophyll concentration as their proxy respond rapidly to changes in their physical environment. In the Mediterranean Sea, these changes are seasonal and are mostly determined by light and nutrient availability (Gregg and Rousseaux, 2014). By comparing annual mean values to the climatology, we effectively remove the seasonal signal at each grid point, while retaining information on peculiar events during the year. In particular, chlorophyll anomalies in the Mediterranean Sea can then be correlated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al 2018, Colella et al 2016). '''CMEMS KEY FINDINGS''' The 2019 average chlorophyll anomaly in the Mediterranean Sea is 1.02 mg m-3 (0.005 in log10 [mg m-3]), with a maximum value of 73 mg m-3 (1.86 log10 [mg m-3]) and a minimum value of 0.04 mg m-3 (-1.42 log10 [mg m-3]). The overall east west divided pattern reported in 2016, showing negative anomalies for the Western Mediterranean Sea and positive anomalies for the Levantine Sea (Sathyendranath et al., 2018b) is modified in 2019, with a widespread positive anomaly all over the eastern basin, which reaches the western one, up to the offshore water at the west of Sardinia. Negative anomaly values occur in the coastal areas of the basin and in some sectors of the Alboràn Sea. In the northwestern Mediterranean the values switch to be positive again in contrast to the negative values registered in 2017 anomaly. The North Adriatic Sea shows a negative anomaly offshore the Po river, but with weaker value with respect to the 2017 anomaly map.

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces surface chlorophyll of the European region by merging the daily chlorophyll regional products over the Atlantic Ocean, the Baltic Sea, the Black Sea, and the Mediterranean Sea. Single chlorophyll daily images are the Case I – Case II products, which are produced accounting for bio-optical differences in these two water types. The mosaic is built using the following datasets: • dataset-oc-atl-chl-multi_cci-l3-chl_1km_daily-rt-v01 for the North Atlantic Ocean • dataset-oc-bal-chl-modis_a-l3-nn_1km_daily-rt-v01 for the Baltic Sea • dataset-oc-bs-chl-multi-l3-chl_1km_daily-rt-v02 for the Black Sea • dataset-oc-med-chl-multi-l3-chl_1km_daily-rt-v02 for the Mediterranean Sea. '''Processing information:''' All details about the processing can be found in relevant product description: *OCEANCOLOUR_ATL_CHL_L3_NRT_OBSERVATIONS_009_036 *OCEANCOLOUR_BAL_CHL_L3_NRT_OBSERVATIONS_009_049 *OCEANCOLOUR_BS_CHL_L3_NRT_OBSERVATIONS_009_044 *OCEANCOLOUR_MED_CHL_L3_NRT_OBSERVATIONS_009_040 '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-eur-chl-multi-l3-chl_1km_daily-rt-v02 '''DOI (product) :''' https://doi.org/10.48670/moi-00095

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS REP Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2020 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' Some coastal and shelf waters, especially between 30 and 400N showed active oligotrophication flags for 2020, with some scattered offshore locations within the same latitudinal belt also showing oligotrophication. Eutrophication index is positive only for a small number of coastal locations just north of 40oN, and south of 30oN. In general, the indicator map showed very few areas with active eutrophication flags for 2019 and for 2020. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR) in Rome distributes reprocessed surface chlorophyll concentration (Chl) and phytoplankton functional types (PFT). Input Rrs multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI) spectra at the state-of-the-art algorithms for multi-sensor merging. Single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged. Reprocessed (multi-year) products are consistent and homogeneous in terms of format, algorithms and processing software. Chl is obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Volpe et al., 2019) and AD4 (Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average spectrum from in situ measurements. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where Case II spectra are selected with a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between observed and reference spectra and using it as weight for the final value. The PFT provides estimates of Chl concentration of 9 phytoplankton groups: Micro, Nano, Pico, Diato, Dino, Crypto, Hapto, Green and Prokar. Micro consists of Diato and Dino, Nano includes Crypto and Hapto and Pico is referred to Green and Prokar with the adjustment of Brewin et al. (2010) in the ultra-oligotrophic water for Pico and Nano. These classes are estimated via empirical regional functions, correlating Chl concentration with each in-situ PFT fraction computed by a regional diagnostic pigment analysis (Di Cicco et al. 2017). '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll and kd490) are estimated via state-of-the-art algorithms for better product quality. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' * dataset-oc-med-chl-multi-l3-chl_1km_daily-rep-v02 * dataset-oc-med-pft-multi-l3-pft_1km_daily-rep-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00112

'''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS MY Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2021 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' The coastal and shelf waters, especially between 30 and 400N that showed active oligotrophication flags for 2020 have reduced in 2021 and a reversal to eutrophic flags can be seen in places. Again, the eutrophication index is positive only for a small number of coastal locations just north of 40oN in 2021, however south of 40oN there has been a significant increase in eutrophic flags, particularly around the Azores. In general, the 2021 indicator map showed an increase in oligotrophic areas in the Northern Atlantic and an increase in eutrophic areas in the Southern Atlantic. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. '''DOI (product):''' https://doi.org/10.48670/moi-00195