'''DEFINITION''' Ocean acidification is quantified by decreases in pH, which is a measure of acidity: a decrease in pH value means an increase in acidity, that is, acidification. The observed decrease in ocean pH resulting from increasing concentrations of CO2 is an important indicator of global change. The estimate of global mean pH builds on a reconstruction methodology, * Obtain values for alkalinity based on the so called “locally interpolated alkalinity regression (LIAR)” method after Carter et al., 2016; 2018. * Build on surface ocean partial pressure of carbon dioxide (CMEMS product: MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) obtained from an ensemble of Feed-Forward Neural Networks (Chau et al. 2022) which exploit sampling data gathered in the Surface Ocean CO2 Atlas (SOCAT) (https://www.socat.info/) * Derive a gridded field of ocean surface pH based on the van Heuven et al., (2011) CO2 system calculations using reconstructed pCO2 (MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) and alkalinity. The global mean average of pH at yearly time steps is then calculated from the gridded ocean surface pH field. It is expressed in pH unit on total hydrogen ion scale. In the figure, the amplitude of the uncertainty (1σ ) of yearly mean surface sea water pH varies at a range of (0.0023, 0.0029) pH unit (see Quality Information Document for more details). The trend and uncertainty estimates amount to -0.0017±0.0004e-1 pH units per year. The indicator is derived from in situ observations of CO2 fugacity (SOCAT data base, www.socat.info, Bakker et al., 2016). These observations are still sparse in space and time. Monitoring pH at higher space and time resolutions, as well as in coastal regions will require a denser network of observations and preferably direct pH measurements. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020). '''CONTEXT''' The decrease in surface ocean pH is a direct consequence of the uptake by the ocean of carbon dioxide. It is referred to as ocean acidification. The International Panel on Climate Change (IPCC) Workshop on Impacts of Ocean Acidification on Marine Biology and Ecosystems (2011) defined Ocean Acidification as “a reduction in the pH of the ocean over an extended period, typically decades or longer, which is caused primarily by uptake of carbon dioxide from the atmosphere, but can also be caused by other chemical additions or subtractions from the ocean”. The pH of contemporary surface ocean waters is already 0.1 lower than at pre-industrial times and an additional decrease by 0.33 pH units is projected over the 21st century in response to the high concentration pathway RCP8.5 (Bopp et al., 2013). Ocean acidification will put marine ecosystems at risk (e.g. Orr et al., 2005; Gehlen et al., 2011; Kroeker et al., 2013). The monitoring of surface ocean pH has become a focus of many international scientific initiatives (http://goa-on.org/) and constitutes one target for SDG14 (https://sustainabledevelopment.un.org/sdg14). '''CMEMS KEY FINDINGS''' Since the year 1985, global ocean surface pH is decreasing at a rate of -0.0017±0.019 decade-1 '''DOI (product):''' https://doi.org/10.48670/moi-00224

'''Short Description''' The biogeochemical analysis and forecasts for the Mediterranean Sea at 1/24° of horizontal resolution (ca. 4 km) are produced by means of the MedBFM4 model system. MedBFM4, which is run by OGS (IT), consists of the coupling of the multi-stream atmosphere radiative model OASIM, the multi-stream in-water radiative and tracer transport model OGSTM_BIOPTIMOD v4.6, and the biogeochemical flux model BFM v5.3. Additionally, MedBFM4 features the 3D variational data assimilation scheme 3DVAR-BIO v4.1 with the assimilation of surface chlorophyll (CMEMS-OCTAC NRT product) and of vertical profiles of chlorophyll, nitrate and oxygen (BGC-Argo floats provided by CORIOLIS DAC). The biogeochemical MedBFM system, which is forced by the NEMO-OceanVar model (MEDSEA_ANALYSIS_FORECAST_PHY_006_013), produces one day of hindcast and ten days of forecast (every day) and seven days of analysis (weekly on Tuesday). Salon, S.; Cossarini, G.; Bolzon, G.; Feudale, L.; Lazzari, P.; Teruzzi, A.; Solidoro, C., and Crise, A. (2019) Novel metrics based on Biogeochemical Argo data to improve the model uncertainty evaluation of the CMEMS Mediterranean marine ecosystem forecasts. Ocean Science, 15, pp.997–1022. DOI: https://doi.org/10.5194/os-15-997-2019 ''DOI (Product)'': https://doi.org/10.48670/mds-00358

'''DEFINITION''' The OMI_EXTREME_WAVE_NORTHWESTSHELF_swh_mean_and_anomaly_obs indicator is based on the computation of the 99th and the 1st percentiles from in situ data (observations). It is computed for the variable significant wave height (swh) measured by in situ buoys. The use of percentiles instead of annual maximum and minimum values, makes this extremes study less affected by individual data measurement errors. The percentiles are temporally averaged, and the spatial evolution is displayed, jointly with the anomaly in the target year. This study of extreme variability was first applied to sea level variable (Pérez Gómez et al 2016) and then extended to other essential variables, sea surface temperature and significant wave height (Pérez Gómez et al 2018). '''CONTEXT''' Projections on Climate Change foresee a future with a greater frequency of extreme sea states (Stott, 2016; Mitchell, 2006). The damages caused by severe wave storms can be considerable not only in infrastructure and buildings but also in the natural habitat, crops and ecosystems affected by erosion and flooding aggravated by the extreme wave heights. In addition, wave storms strongly hamper the maritime activities, especially in harbours. These extreme phenomena drive complex hydrodynamic processes, whose understanding is paramount for proper infrastructure management, design and maintenance (Goda, 2010). In recent years, there have been several studies searching possible trends in wave conditions focusing on both mean and extreme values of significant wave height using a multi-source approach with model reanalysis information with high variability in the time coverage, satellite altimeter records covering the last 30 years and in situ buoy measured data since the 1980s decade but with sparse information and gaps in the time series (e.g. Dodet et al., 2020; Timmermans et al., 2020; Young & Ribal, 2019). These studies highlight a remarkable interannual, seasonal and spatial variability of wave conditions and suggest that the possible observed trends are not clearly associated with anthropogenic forcing (Hochet et al. 2021, 2023). In the North Atlantic, the mean wave height shows some weak trends not very statistically significant. Young & Ribal (2019) found a mostly positive weak trend in the European Coasts while Timmermans et al. (2020) showed a weak negative trend in high latitudes, including the North Sea and even more intense in the Norwegian Sea. For extreme values, some authors have found a clearer positive trend in high percentiles (90th-99th) (Young et al., 2011; Young & Ribal, 2019). '''COPERNICUS MARINE SERVICE KEY FINDINGS''' The mean 99th percentiles showed in the area present a wide range from 2.5 meters in the English Channel with 0.3m of standard deviation (std), 3-5m in the southern and central North Sea with 0.3-0.6m of std, 4 meters in the Skagerrak Strait with 0.6m of std, 6-7m in the northern North Sea with 0.4-0.5m of std to 8 meters in the NorthWest of the British Isles with 0.8-1.0m of std. Results for this year show either low positive or negative anomalies between -0.3m and +0.4m, inside the margin of the standard deviation, in the English Channel, the Skagerrak Strait and the southern and central North Sea except in the station 6200046 with a positive anomaly of 0.8m and a slight negative anomaly (-0.1/-0.5m) inside the margin of the std in the NorthWest of the British Isles and the northern North Sea. '''DOI (product):''' https://doi.org/10.48670/moi-00270

'''Short description:''' For the '''Mediterranean Sea''' Ocean '''Satellite Observations''', the Italian National Research Council (CNR – Rome, Italy), is providing multi-years '''Bio-Geo_Chemical (BGC)''' regional datasets: * '''''plankton''''' with the phytoplankton chlorophyll concentration (CHL) evaluated via region-specific algorithms (Case 1 waters: Volpe et al., 2019, with new coefficients; Case 2 waters, Berthon and Zibordi, 2004), and the interpolated '''gap-free''' Chl concentration (to provide a "cloud free" product) estimated by means of a modified version of the DINEOF algorithm (Volpe et al., 2018); moreover, daily climatology for chlorophyll concentration is provided. * '''''pp''''' with the Integrated Primary Production (PP). '''Upstreams''': SeaWiFS, MODIS, MERIS, VIIRS-SNPP & JPSS1, OLCI-S3A & S3B for the '''"multi"''' products, and OLCI-S3A & S3B for the '''"olci"''' products '''Temporal resolutions''': monthly and daily (for '''"gap-free"''' and climatology data) '''Spatial resolution''': 1 km for '''"multi"''' and 300 meters for '''"olci"''' To find this product in the catalogue, use the search keyword '''"OCEANCOLOUR_MED_BGC_L4_MY"'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00300

'''DEFINITION''' The OMI_EXTREME_WAVE_IBI_swh_mean_and_anomaly_obs indicator is based on the computation of the 99th and the 1st percentiles from in situ data (observations). It is computed for the variable significant wave height (swh) measured by in situ buoys. The use of percentiles instead of annual maximum and minimum values, makes this extremes study less affected by individual data measurement errors. The percentiles are temporally averaged, and the spatial evolution is displayed, jointly with the anomaly in the target year. This study of extreme variability was first applied to sea level variable (Pérez Gómez et al 2016) and then extended to other essential variables, sea surface temperature and significant wave height (Pérez Gómez et al 2018). '''CONTEXT''' Projections on Climate Change foresee a future with a greater frequency of extreme sea states (Stott, 2016; Mitchell, 2006). The damages caused by severe wave storms can be considerable not only in infrastructure and buildings but also in the natural habitat, crops and ecosystems affected by erosion and flooding aggravated by the extreme wave heights. In addition, wave storms strongly hamper the maritime activities, especially in harbours. These extreme phenomena drive complex hydrodynamic processes, whose understanding is paramount for proper infrastructure management, design and maintenance (Goda, 2010). In recent years, there have been several studies searching possible trends in wave conditions focusing on both mean and extreme values of significant wave height using a multi-source approach with model reanalysis information with high variability in the time coverage, satellite altimeter records covering the last 30 years and in situ buoy measured data since the 1980s decade but with sparse information and gaps in the time series (e.g. Dodet et al., 2020; Timmermans et al., 2020; Young & Ribal, 2019). These studies highlight a remarkable interannual, seasonal and spatial variability of wave conditions and suggest that the possible observed trends are not clearly associated with anthropogenic forcing (Hochet et al. 2021, 2023). In the North Atlantic, the mean wave height shows some weak trends not very statistically significant. Young & Ribal (2019) found a mostly positive weak trend in the European Coasts while Timmermans et al. (2020) showed a weak negative trend in high latitudes, including the North Sea and even more intense in the Norwegian Sea. For extreme values, some authors have found a clearer positive trend in high percentiles (90th-99th) (Young, 2011; Young & Ribal, 2019). '''COPERNICUS MARINE SERVICE KEY FINDINGS''' The mean 99th percentiles showed in the area present a wide range from 2-3.5m in the Canary Island with 0.1-0.3 m of standard deviation (std), 3.5m in the Gulf of Cadiz with 0.5m of std, 3-6m in the English Channel and the Irish Sea with 0.5-0.6m of std, 4-7m in the Bay of Biscay with 0.4-0.9m of std to 8-10m in the West of the British Isles with 0.7-1.4m of std. Results for this year show slight negative anomalies in the Canary Island (-0.4/0.0m) and in the Gulf of Cadiz (-0.8m) barely out of the standard deviation range in both areas, slight positive or negative anomalies in the West of the British Isles (-0.6/+0.4m) and in the English Channel and the Irish Sea (-0.6/+0.3m) but inside the range of the standard deviation and a general positive anomaly in the Bay of Biscay reaching +1.0m but close to the limit of the standard deviation. '''DOI (product):''' https://doi.org/10.48670/moi-00250

'''Short description:''' This product consists of vertical profiles of the concentration of nutrients (nitrates, phosphates, and silicates) and carbonate system variables (total alkalinity, dissolved inorganic carbon, pH, and partial pressure of carbon dioxide), computed for each Argo float equipped with an oxygen sensor. The method called CANYON is based on a neural network trained using nutrient data (GLODAPv2 database) '''DOI (product) :''' https://doi.org/10.48670/moi-00048

'''Short description:''' For the NWS/IBI Ocean- Sea Surface Temperature L3 Observations . This product provides daily foundation sea surface temperature from multiple satellite sources. The data are intercalibrated. This product consists in a fusion of sea surface temperature observations from multiple satellite sensors, daily, over a 0.05° resolution grid. It includes observations by polar orbiting from the ESA CCI / C3S archive . The L3S SST data are produced selecting only the highest quality input data from input L2P/L3P images within a strict temporal window (local nightime), to avoid diurnal cycle and cloud contamination. The observations of each sensor are intercalibrated prior to merging using a bias correction based on a multi-sensor median reference correcting the large-scale cross-sensor biases. '''DOI (product) :''' https://doi.org/10.48670/moi-00311

'''Short description:''' Altimeter satellite along-track sea surface heights anomalies (SLA) computed with respect to a twenty-year [1993, 2012] mean with a 1Hz (~7km) sampling. It serves in delayed-time applications. This product is processed by the DUACS multimission altimeter data processing system. It processes data from all altimeter missions available (e.g. Sentinel-6A, Jason-3, Sentinel-3A, Sentinel-3B, Saral/AltiKa, Cryosat-2, Jason-1, Jason-2, Topex/Poseidon, ERS-1, ERS-2, Envisat, Geosat Follow-On, HY-2A, HY-2B, etc). The system exploits the most recent datasets available based on the enhanced GDR/NTC production. All the missions are homogenized with respect to a reference mission. Part of the processing is fitted to the European Sea area. (see QUID document or http://duacs.cls.fr [http://duacs.cls.fr] pages for processing details). The product gives additional variables (e.g. Mean Dynamic Topography, Dynamic Atmospheric Correction, Ocean Tides, Long Wavelength Errors) that can be used to change the physical content for specific needs (see PUM document for details) “’Associated products”’ A time invariant product https://resources.marine.copernicus.eu/product-detail/SEALEVEL_GLO_PHY_NOISE_L4_STATIC_008_033/INFORMATION describing the noise level of along-track measurements is available. It is associated to the sla_filtered variable. It is a gridded product. One file is provided for the global ocean and those values must be applied for Arctic and Europe products. For Mediterranean and Black seas, one value is given in the QUID document. '''DOI (product):''' https://doi.org/10.48670/moi-00139

'''Short description:''' For the Baltic Sea- The DMI Sea Surface Temperature L3S aims at providing daily multi-sensor supercollated data at 0.03deg. x 0.03deg. horizontal resolution, using satellite data from infra-red radiometers. Uses SST satellite products from these sensors: NOAA AVHRRs 7, 9, 11, 14, 16, 17, 18 , Envisat ATSR1, ATSR2 and AATSR. '''DOI (product) :''' https://doi.org/10.48670/moi-00154

'''Short Description:''' The ocean biogeochemistry reanalysis for the North-West European Shelf is produced using the European Regional Seas Ecosystem Model (ERSEM), coupled online to the forecasting ocean assimilation model at 7 km horizontal resolution, NEMO-NEMOVAR. ERSEM (Butenschön et al. 2016) is developed and maintained at Plymouth Marine Laboratory. NEMOVAR system was used to assimilate observations of sea surface chlorophyll concentration from ocean colour satellite data and all the physical variables described in [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=NWSHELF_MULTIYEAR_PHY_004_009 NWSHELF_MULTIYEAR_PHY_004_009]. Biogeochemical boundary conditions and river inputs used climatologies; nitrogen deposition at the surface used time-varying data. The description of the model and its configuration, including the products validation is provided in the [https://documentation.marine.copernicus.eu/QUID/CMEMS-NWS-QUID-004-011.pdf CMEMS-NWS-QUID-004-011]. Products are provided as monthly and daily 25-hour, de-tided, averages. The datasets available are concentration of chlorophyll, nitrate, phosphate, oxygen, phytoplankton biomass, net primary production, light attenuation coefficient, pH, surface partial pressure of CO2, concentration of diatoms expressed as chlorophyll, concentration of dinoflagellates expressed as chlorophyll, concentration of nanophytoplankton expressed as chlorophyll, concentration of picophytoplankton expressed as chlorophyll in sea water. All, as multi-level variables, are interpolated from the model 51 hybrid s-sigma terrain-following system to 24 standard geopotential depths (z-levels). Grid-points near to the model boundaries are masked. The product is updated biannually, providing a six-month extension of the time series. See [https://documentation.marine.copernicus.eu/PUM/CMEMS-NWS-PUM-004-009-011.pdf CMEMS-NWS-PUM-004-009_011] for details. '''Associated products:''' This model is coupled with a hydrodynamic model (NEMO) available as CMEMS product [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=NWSHELF_MULTIYEAR_PHY_004_009 NWSHELF_MULTIYEAR_PHY_004_009]. An analysis-forecast product is available from: [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=NWSHELF_MULTIYEAR_BGC_004_011 NWSHELF_MULTIYEAR_BGC_004_011]. '''DOI (product) :''' https://doi.org/10.48670/moi-00058