An observation network was initiated in 2021 in the framework of the CocoriCO2 project to monitore carbonate parameters along the French coastal systems. Six sites were selected along the French Atlantic and Mediterranean coastlines based on their importance in terms of shellfish production and the presence of high- and low-frequency monitoring activities. At each site, autonomous pH sensors were deployed both inside and outside shellfish production areas, next to high-frequency CTD (conductivity-temperature-depth) probes operated through two operating monitoring networks (SNO COAST-HF and Ifremer ECOSCOPA). pH sensors were set to an acquisition rate of 15 min and discrete seawater samples were collected biweekly in order to control the quality of pH data (laboratory spectrophotometric measurements) as well as to measure total alkalinity and dissolved inorganic carbon concentrations for full characterization of the carbonate system. While this network has been up and running for more than two years, the acquired dataset has already revealed important differences in terms of pH variations between monitored sites related to the influence of diverse processes (freshwater inputs, tides, temperature, biological processes).    

Since 2004, the Service facility SNAPO-CO2 (Service National d’Analyse des Paramètres Océaniques du CO2) housed by the LOCEAN laboratory (Paris, France) has been in charge for the analysis of Total Alkalinity (AT) and Total dissolved inorganic carbon (CT) of seawater samples on a series of cruises or ships of opportunity conducted in different regions in the frame of French projects. More than 44000 observations are synthetized in this work. Sampling was performed either from CTD-Rosette casts (Niskin bottles) or collected from the ship’s seawater supply (intake at about 5m depth). After completion of each cruise, discrete samples were returned back at LOCEAN laboratory and stored in a dark room at 4 °C before analysis generally within 2-3 months after sampling (sometimes within a week).  AT and CT were analyzed simultaneously by potentiometric titration using a closed cell (Edmond, 1970). Certified Reference Materials (CRMs) provided by Pr. A. Dickson (Scripps Institution of Oceanography, San Diego, USA) were used to calibrate the measurements. The same instrumentation was used for underway measurements during OISO cruises (https://doi.org/10.18142/228) and OISO AT-CT data for 1998-2018 in the South Indian Ocean added in this synthesis. The synthesis is organized in two files (one for Global ocean and the Coastal Zones, one for the Mediterranean Sea) with the same format: Cruise name, Ship name, day, month, year, hour, minute, second, latitude, longitude, depth, AT (µmol/kg), Flag-AT, CT (µmol/kg), Flag-CT, Temperature (°C), Flag-Temp, Salinity (PSU), Flag-Salinity, nsample/cruise, nsample on file, sampling method.