EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (24 parameters), and covers the Mediterranean Sea with 4517 CDI records divided per matrices: 520 biota profiles, 560 water profiles, 3437 sediment (26 Vertical profiles and 3411 Time series). In the water dataset, the vertical profiles temporal range is from 1974-09-12 to 2015-09-14. In sediment dataset, vertical profiles temporal range is from 2010-08-02 to 2014-09-28 and time series temporal range is from 1981-06-27 to 2018-08-02. In biota time series temporal range is from 1979-03-29 to 2017-03-15. Data were aggregated and quality controlled by ‘Hellenic Centre for Marine Research, Hellenic National Oceanographic Data Centre (HCMR/HNODC)’ from Greece. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names” ,but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 24 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

Water body dissolved oxygen concentration - Monthly Climatology for the European Seas for the period 1960-2020 on the domain from longitude -45.0 to 70.0 degrees East and latitude 24.0 to 83.0 degrees North. Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.2, using GEBCO 30sec topography for the spatial connectivity of water masses. Horizontal correlation length and vertical correlation length vary spatially depending on the topography and domain. Depth range: 0.0, 5.0, 10.0, 15.0, 20.0, 25.0, 30.0, 35.0, 40.0, 45.0, 50.0, 55.0, 60.0, 65.0, 70.0, 75.0, 80.0, 85.0, 90.0, 95.0, 100.0, 125.0, 150.0, 175.0, 200.0, 225.0, 250.0, 275.0, 300.0, 325.0, 350.0, 375.0, 400.0, 425.0, 450.0, 475.0, 500.0, 550.0, 600.0, 650.0, 700.0, 750.0, 800.0, 850.0, 900.0, 950.0, 1000.0, 1050.0, 1100.0, 1150.0, 1200.0, 1250.0, 1300.0, 1350.0, 1400.0, 1450.0, 1500.0, 1550.0, 1600.0, 1650.0, 1700.0, 1750.0, 1800.0, 1850.0, 1900.0, 1950.0, 2000.0, 2100.0, 2200.0, 2300.0, 2400.0, 2500.0, 2600.0, 2700.0, 2800.0, 2900.0, 3000.0, 3100.0, 3200.0, 3300.0, 3400.0, 3500.0, 3600.0, 3700.0, 3800.0, 3900.0, 4000.0, 4100.0, 4200.0, 4300.0, 4400.0, 4500.0, 4600.0, 4700.0, 4800.0, 4900.0, 5000.0, 5100.0, 5200.0, 5300.0, 5400.0, 5500.0 m. Units: umol/l. The horizontal resolution of the produced DIVAnd analysis is 0.25 degrees.

The SDC_GLO_CLIM_N2 product contains seasonally averaged Brunt-Vaisala squared frequency profiles using the density profiles computed in SeadataCloud Global Ocean Climatology - Density Climatology. The Density Climatology product uses the Profiling Floats (PFL) data from World Ocean database 18 for the time period 2003 to 2017 with a Nonlinear Quality procedure applied on it. Computed BVF profiles are averaged seasonally into 5x5 degree boxes for Atlantic and Pacific Oceans. For data access, please register at http://www.marine-id.org/.

Water body chlorophyll-a - Monthly Climatology for the European Seas for the period 1960-2020 on the domain from longitude -45.0 to 70.0 degrees East and latitude 24.0 to 83.0 degrees North. Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.2, using GEBCO 30sec topography for the spatial connectivity of water masses. Horizontal correlation length and vertical correlation length vary spatially depending on the topography and domain. Depth range: 0.0, 5.0, 10.0, 15.0, 20.0, 25.0, 30.0, 35.0, 40.0, 45.0, 50.0, 55.0, 60.0, 65.0, 70.0, 75.0, 80.0, 85.0, 90.0, 95.0, 100.0, 125.0, 150.0, 175.0, 200.0, 225.0, 250.0, 275.0, 300.0, 325.0, 350.0, 375.0, 400.0, 425.0, 450.0, 475.0, 500.0, 550.0, 600.0, 650.0, 700.0, 750.0, 800.0, 850.0, 900.0, 950.0, 1000.0, 1050.0, 1100.0, 1150.0, 1200.0, 1250.0, 1300.0, 1350.0, 1400.0, 1450.0, 1500.0, 1550.0, 1600.0, 1650.0, 1700.0, 1750.0, 1800.0, 1850.0, 1900.0, 1950.0, 2000.0, 2100.0, 2200.0, 2300.0, 2400.0, 2500.0, 2600.0, 2700.0, 2800.0, 2900.0, 3000.0, 3100.0, 3200.0, 3300.0, 3400.0, 3500.0, 3600.0, 3700.0, 3800.0, 3900.0, 4000.0, 4100.0, 4200.0, 4300.0, 4400.0, 4500.0, 4600.0, 4700.0, 4800.0, 4900.0, 5000.0, 5100.0, 5200.0, 5300.0, 5400.0, 5500.0 m. Units: mg/m3. The horizontal resolution of the produced DIVAnd analysis is 0.25 degrees.

The SDC_GLO_CLIM_Dens product contains global monthly climatological estimates of in situ density using Temperature and Salinity from profiling floats contained in the World Ocean Data 18 (WOD18) database. The profiles were first quality controlled with a Nonlinear Quality control procedure. The climatology considers observations from surface to 2000 m for the time period 2003-2017. Density profiles are computed using UNESCO 1983 (EOS 80) equation from in situ temperature, salinity and pressure measurements by the PFL. Only profiles with both T,S values were used. The gridded fields are computed using DIVAnd (Data Interpolating Variational Analysis) version 2.3.1.

This product displays the stations where fluoranthene has been measured and the values present in EMODnet Chemistry infrastructure are always below the limit of detection or quantification (LOD/LOQ), i.e quality values found in EMODnet validated dataset can be equal to 6 or Q. It is necessary to take into account that LOD/LOQ can change with time. These products aggregate data by station, producing only one final value for each station (above, below or above/below). EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

Moving 6-year analysis of Water body dissolved inorganic nitrogen in the NorthEast Atlantic for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 6-year centred average of each season. 6-year periods span from 1971/1976 until 2019/2024. Observation data span from 1971 to 2024. Depth levels (IODE standard depths): [0.0, 5.0, 10.0, 20.0, 30.0, 40.0, 50.0, 75.0, 100.0, 125.0, 150.0, 200.0, 250.0, 300.0, 400.0, 500.0, 600.0, 700.0, 800.0, 900.0, 1000.0, 1100.0, 1200.0, 1300.0, 1400.0, 1500.0, 1750.0, 2000.0]. Data sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: the computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.12, using GEBCO 30 sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps is 0.1 degrees. Horizontal correlation length varies from 400km in open sea regions to 50km at the coast. Vertical correlation length is defined as twice the vertical resolution. Signal-to-noise ratio was fixed to 1 for vertical profiles and 0.1 for time series to account for the redundancy in the time series observations. A logarithmic transformation (DIVAnd.loglin) was applied to the data prior to the analysis. Background field: a vertically-filtered profile of the seasonal data mean value (including all years) is substracted from the data. Detrending of data: no, advection constraint applied: no. Units: umol/l.

The SDC_GLO_CLIM_O2_AOU product contains two different monthly climatology for dissolved Oxygen and Apparent Oxygen Utilization, SDC_GLO_CLIM_O2 and SDC_GLO_CLIM_AOU respectively from the World Ocean Data (WOD) database. Only basic quality control flags from the WOD are used. The first climatology, SDC_GLO_CLIM_O2, considers Dissolved Oxygen profiles casted together with temperature and salinity from CTD, Profiling Floats (PFL) and Ocean Station Data (OSD) for time duration 2003 to 2017. The second climatology, SDC_GLO_CLIM_AOU, apparent Oxygen utilization, is computed as a difference of dissolved oxygen and saturation O2 profiles. The gridded fields are computed using DIVAnd (Data Interpolating Variational Analysis) version 2.3.1.

Moving 6-year analysis of Water body chlorophyll-a in the NorthEast Atlantic for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 6-year centred average of each season. 6-year periods span from 1971/1976 until 2016/2021. Observation data span from 1971 to 2021. High-frequency observation trails were filtered to a 3h temporal resolution. Depth levels (IODE standard depths): [0.0, 5.0, 10.0, 20.0, 30.0, 40.0, 50.0, 75.0, 100.0, 125.0, 150.0, 200.0, 250.0, 300.0]. Data sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Descrption of DIVAnd analysis: the computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30 sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps is 0.1 degrees. Horizontal correlation length varies from 200km in open sea regions to 50km at the coast. Vertical correlation length is defined as twice the vertical resolution. Signal-to-noise ratio was fixed to 1 for vertical profiles and 0.1 for time series to account for the redundancy in the time series observations. A logarithmic transformation (DIVAnd.Anam.loglin) was applied to the data prior to the analysis to avoid unrealistic negative values. Background field: a vertically-filtered profile of the seasonal data mean value (including all years) is substracted from the data. Detrending of data: no, advection constraint applied: no. Units: mg/m3.

This product displays the stations present in EMODnet validated dataset where DDT levels have been measured in sediment. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0