We assembled a dataset of 14C-based productivity measurements to understand the critical variables required for accurate assessment of daily depth-integrated phytoplankton carbon fixation (PP(PPeu)u) from measurements of sea surface pigment concentrations (Csat)(Csat). From this dataset, we developed a light-dependent, depth-resolved model for carbon fixation (VGPM) that partitions environmental factors affecting primary production into those that influence the relative vertical distribution of primary production (Pz)z) and those that control the optimal assimilation efficiency of the productivity profile (P(PBopt). The VGPM accounted for 79% of the observed variability in Pz and 86% of the variability in PPeu by using measured values of PBopt. Our results indicate that the accuracy of productivity algorithms in estimating PPeu is dependent primarily upon the ability to accurately represent variability in Pbopt. We developed a temperature-dependent Pbopt model that was used in conjunction with monthly climatological images of Csat sea surface temperature, and cloud-corrected estimates of surface irradiance to calculate a global annual phytoplankton carbon fixation (PPannu) rate of 43.5 Pg C yr‒1. The geographical distribution of PPannu was distinctly different than results from previous models. Our results illustrate the importance of focusing Pbopt model development on temporal and spatial, rather than the vertical, variability.

The Copernicus Marine Service (or Copernicus Marine Environment Monitoring Service) is the marine component of the Copernicus Programme of the European Union. It provides free, regular and systematic authoritative information on the state of the Blue (physical), White (sea ice) and Green (biogeochemical) ocean, on a global and regional scale. It is funded by the European Commission (EC) and implemented by Mercator Ocean International. It is designed to serve EU policies and International legal Commitments related to Ocean Governance, to cater for the needs of society at large for global ocean knowledge and to boost the Blue Economy across all maritime sectors by providing free-of-charge state-of-the-art ocean data and information. It provides key inputs that support major EU and international policies and initiatives and can contribute to: combating pollution, marine protection, maritime safety and routing, sustainable use of ocean resources, developing marine energy resources, blue growth, climate monitoring, weather forecasting, and more. It also aims to increase awareness amongst the general public by providing European and global citizens with information about ocean-related issues.

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the North Atlantic and Arctic oceans, the ESA Ocean Colour CCI Remote Sensing Reflectance (merged, bias-corrected Rrs) data are used to compute surface Chlorophyll (mg m-3, 1 km resolution) using the regional OC5CCI chlorophyll algorithm. The Rrs are generated by merging the data from SeaWiFS, MODIS-Aqua, MERIS, VIIRS and OLCI-3A sensors and realigning the spectra to that of the MERIS sensor. The algorithm used is OC5CCI - a variation of OC5 (Gohin et al., 2002) developed by IFREMER in collaboration with PML. As part of this development, an OC5CCI look up table was generated specifically for application over OC-CCI merged daily remote sensing reflectances. The resulting OC5CCI algorithm was tested and selected through an extensive calibration exercise that analysed the quantitative performance against in situ data for several algorithms in these specific regions. Processing information: PML's Remote Sensing Group has the capability to automatically receive, archive, process and map global data from multiple polar-orbiting sensors in both near-real time and delayed time. OLCI products are downloaded at level-1 from CODA, the Copernicus Hub and/or via EUMETCAST. These products are remapped at nominal 300m and 1 Km spatial resolution using cylindrical equirectangular projection. Description of observation methods/instruments: Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in situ measurements, an estimate of chlorophyll content can be derived. '''Processing information:''' ESA OC-CCI Rrs raw data are provided by Plymouth Marine Laboratory, currently at 4km resolution globally. These are processed to produce chlorophyll concentration using the same in-house software as in the operational processing. The entire CCI data set is consistent and processing is done in one go. Both OC CCI and the REP product are versioned. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (70deg), large spacecraft zenith angle (56deg), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 560 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). For the regional products, a variant of the OC-CCI chain is run to produce high resolution data at the 1km resolution necessary. A detailed description of the ESA OC-CCI processing system can be found in OC-CCI (2014e). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Quality / Accuracy / Calibration information:''' Detailed description of cal/val is given in the relevant QUID, associated validation reports and quality documentation. '''DOI (product) :''' https://doi.org/10.48670/moi-00073

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' The time series are derived from the regional chlorophyll reprocessed (REP) products as distributed by CMEMS which, in turn, result from the application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) provided by the ESA Ocean Colour Climate Change Initiative (ESA OC-CCI, Sathyendranath et al. 2019; Jackson 2020). Daily regional mean values are calculated by performing the average (weighted by pixel area) over the region of interest. A fixed annual cycle is extracted from the original signal, using the Census-I method as described in Vantrepotte et al. (2009). The deasonalised time series is derived by subtracting the mean seasonal cycle from the original time series, and then fitted to a linear regression to, finally, obtain the linear trend. '''CONTEXT''' Phytoplankton – and chlorophyll concentration as a proxy for phytoplankton – respond rapidly to changes in environmental conditions, such as temperature, light and nutrients availability, and mixing. The response in the North Atlantic ranges from cyclical to decadal oscillations (Henson et al., 2009); it is therefore of critical importance to monitor chlorophyll concentration at multiple temporal and spatial scales, in order to be able to separate potential long-term climate signals from natural variability in the short term. In particular, phytoplankton in the North Atlantic are known to respond to climate variability associated with the North Atlantic Oscillation (NAO), with the initiation of the spring bloom showing a nominal correlation with sea surface temperature and the NAO index (Zhai et al., 2013). '''CMEMS KEY FINDINGS''' While the overall trend average for the 1997-2020 period in the North Atlantic Ocean is slightly positive (0.92 ± 0.13 % per year), an underlying low frequency harmonic signal can be seen in the deseasonalised data. The annual average for the region in 2020 is 0.31 mg m-3. Though no appreciable changes in the timing of the spring and autumn blooms have been observed during 2020, these reached higher chlorophyll values than the average for the time series. In particular, the spring bloom maximum in 2020, circa 0.80 mg m-3, showed an increase in chlorophyll concentration from the observations during the 2016-2019 spring blooms. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00194

'''Short description''' The biogeochemical hindcast for global ocean is produced at Mercator-Ocean (Toulouse. France). It provides 3D biogeochemical fields since year 1993 at 1/4 degree and on 75 vertical levels. It uses PISCES biogeochemical model (available on the NEMO[https://www.nemo-ocean.eu/] modelling platform). No data assimilation in this product. * Latest NEMO version (v3.6_STABLE) * Forcings: FREEGLORYS2V4[https://www.mercator-ocean.fr/en/solutions-expertise/how-to-access-the-mercator-ocean-services/let-s-define-your-needs/] ocean physics produced at Mercator-Ocean and ERA-Interim[https://www.ecmwf.int/en/forecasts/datasets/archive-datasets/reanalysis-datasets/era-interim] atmosphere produced at ECMWF at a daily frequency * Outputs: Daily (chlorophyll. nitrate. phosphate. silicate. dissolved oxygen. primary production) and monthly (chlorophyll. nitrate. phosphate. silicate. dissolved oxygen. primary production. iron. phytoplankton in carbon) 3D mean fields interpolated on a standard regular grid in NetCDF format. The simulation is performed once and for all. * Initial conditions: World Ocean Atlas 2013 for nitrate. phosphate. silicate and dissolved oxygen. GLODAPv2 for DIC and Alkalinity. and climatological model outputs for Iron and DOC * Quality/Accuracy/Calibration information: See the related QuID[http://catalogue.marine.copernicus.eu/documents/QUID/CMEMS-GLO-QUID-001-029.pdf] '''DOI (product):''' https://doi.org/10.48670/moi-00019

'''Short description:''' This product consists of 3D fields of Particulate Organic Carbon (POC), Particulate Backscattering coefficient (bbp) and Chlorophyll-a concentration (Chla) at depth. The reprocessed product is provided at 0.25°x0.25° horizontal resolution, over 36 levels from the surface to 1000 m depth. A neural network method estimates both the vertical distribution of Chla concentration and of particulate backscattering coefficient (bbp), a bio-optical proxy for POC, from merged surface ocean color satellite measurements with hydrological properties and additional relevant drivers. '''DOI (product):''' https://doi.org/10.48670/moi-00046 '''Product Citation:''' Please refer to our Technical FAQ for citing products: http://marine.copernicus.eu/faq/cite-cmems-products-cmems-credit/?idpage=169.

'''DEFINITION''' The time series are derived from the regional chlorophyll reprocessed (REP) products as distributed by CMEMS which, in turn, result from the application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) provided by the ESA Ocean Colour Climate Change Initiative (ESA OC-CCI, Sathyendranath et al. 2019; Jackson 2020). Daily regional mean values are calculated by performing the average (weighted by pixel area) over the region of interest. A fixed annual cycle is extracted from the original signal, using the Census-I method as described in Vantrepotte et al. (2009). The deseasonalised time series is derived by subtracting the mean seasonal cycle from the original time series, and then fitted to a linear regression to, finally, obtain the linear trend. '''CONTEXT''' Phytoplankton – and chlorophyll concentration as a proxy for phytoplankton – respond rapidly to changes in environmental conditions, such as temperature, light and nutrients availability, and mixing. The response in the North Atlantic ranges from cyclical to decadal oscillations (Henson et al., 2009); it is therefore of critical importance to monitor chlorophyll concentration at multiple temporal and spatial scales, in order to be able to separate potential long-term climate signals from natural variability in the short term. In particular, phytoplankton in the North Atlantic are known to respond to climate variability associated with the North Atlantic Oscillation (NAO), with the initiation of the spring bloom showing a nominal correlation with sea surface temperature and the NAO index (Zhai et al., 2013). '''CMEMS KEY FINDINGS''' While the overall trend average for the 1997-2021 period in the North Atlantic Ocean is slightly positive (0.16 ± 0.12 % per year), an underlying low frequency harmonic signal can be seen in the deseasonalised data. The annual average for the region in 2021 is 0.25 mg m-3. Though no appreciable changes in the timing of the spring and autumn blooms have been observed during 2021, a lower peak chlorophyll concentration is observed in the timeseries extension. This decrease in peak concentration with respect to the previous year is contributing to the reduction trend. '''DOI (product):''' https://doi.org/10.48670/moi-00194

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description :''' For the '''Global''' Ocean '''Satellite Observations''', ACRI-ST company (Sophia Antipolis, France) is providing '''Chlorophyll-a''' and '''Optics''' products [1997 - present] based on the '''Copernicus-GlobColour''' processor. * '''Chlorophyll and Bio''' products refer to Chlorophyll-a, Primary Production (PP) and Phytoplankton Functional types (PFT). Products are based on a multi sensors/algorithms approach to provide to end-users the best estimate. Two dailies Chlorophyll-a products are distributed: ** one limited to the daily observations (called L3), ** the other based on a space-time interpolation: the '''"Cloud Free"''' (called L4). * '''Optics''' products refer to Reflectance (RRS), Suspended Matter (SPM), Particulate Backscattering (BBP), Secchi Transparency Depth (ZSD), Diffuse Attenuation (KD490) and Absorption Coef. (ADG/CDM). * The spatial resolution is 4 km. For Chlorophyll, a 1 km over the Atlantic (46°W-13°E , 20°N-66°N) is also available for the '''Cloud Free''' product, plus a 300m Global coastal product (OLCI S3A & S3B merged). *Products (Daily, Monthly and Climatology) are based on the merging of the sensors SeaWiFS, MODIS, MERIS, VIIRS-SNPP&JPSS1, OLCI-S3A&S3B. Additional products using only OLCI upstreams are also delivered. * Recent products are organized in datasets called NRT (Near Real Time) and long time-series in datasets called REP/MY (Multi-Years). The NRT products are provided one day after satellite acquisition and updated a few days after in Delayed Time (DT) to provide a better quality. An uncertainty is given at pixel level for all products. To find the '''Copernicus-GlobColour''' products in the catalogue, use the search keyword '''"GlobColour"'''. See [http://catalogue.marine.copernicus.eu/documents/QUID/CMEMS-OC-QUID-009-030-032-033-037-081-082-083-085-086-098.pdf QUID document] for a detailed description and assessment. '''DOI (product) :''' https://doi.org/10.48670/moi-00100