'''DEFINITION:''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) provided by the ESA Ocean Colour Climate Change Initiative (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT:''' Phytoplankton – and chlorophyll concentration as their proxy – respond rapidly to changes in their physical environment. In the North Atlantic region these changes present a distinct seasonality and are mostly determined by light and nutrient availability (González Taboada et al., 2014). By comparing annual mean values to a climatology, we effectively remove the seasonal signal at each grid point, while retaining information on potential events during the year (Gregg and Rousseaux, 2014). In particular, North Atlantic anomalies can then be correlated with oscillations in the Northern Hemisphere Temperature (Raitsos et al., 2014). Chlorophyll anomalies also provide information on the status of the North Atlantic oligotrophic gyre, where evidence of rapid gyre expansion has been found for the 1997-2012 period (Polovina et al. 2008, Aiken et al., 2017, Sathyendranath et al., 2018b). '''CMEMS KEY FINDINGS:''' The average chlorophyll anomaly in the North Atlantic is -0.02 log10(mg m-3), with a maximum value of 1.0 log10(mg m-3) and a minimum value of -1.0 log10(mg m-3). That is to say that, in average, the annual 2019 mean value is slightly lower (96%) than the 1997-2014 climatological value. A moderate increase in chlorophyll concentration was observed in 2019 over the Bay of Biscay and regions close to Iceland and Greenland, such as the Irminger Basin and the Denmark Strait. In particular, the annual average values for those areas are around 160% of the 1997-2014 average (anomalies > 0.2 log10(mg m-3)). While the significant negative anomalies reported for 2016-2017 (Sathyendranath et al., 2018c) in the area west of the Ireland and Scotland coasts continued to manifest, the Irish and North Seas returned to their normative regime during 2019, with anomalies close to zero. A change in the anomaly sign (positive to negative) was also detected for the West European Basin, with annual values as low as 60% of the 1997-2014 average. This reduction in chlorophyll might be matched with negative anomalies in sea level during the period, indicating a dominance of upwelling factors over stratification.

''' Short description: ''' For the Mediterranean Sea - the CNR diurnal sub-skin Sea Surface Temperature (SST) product provides daily gap-free (L4) maps of hourly mean sub-skin SST at 1/16° (0.0625°) horizontal resolution over the CMEMS Mediterranean Sea (MED) domain, by combining infrared satellite and model data (Marullo et al., 2014). The implementation of this product takes advantage of the consolidated operational SST processing chains that provide daily mean SST fields over the same basin (Buongiorno Nardelli et al., 2013). The sub-skin temperature is the temperature at the base of the thermal skin layer and it is equivalent to the foundation SST at night, but during daytime it can be significantly different under favorable (clear sky and low wind) diurnal warming conditions. The sub-skin SST L4 product is created by combining geostationary satellite observations aquired from SEVIRI and model data (used as first-guess) aquired from the CMEMS MED Monitoring Forecasting Center (MFC). This approach takes advantage of geostationary satellite observations as the input signal source to produce hourly gap-free SST fields using model analyses as first-guess. The resulting SST anomaly field (satellite-model) is free, or nearly free, of any diurnal cycle, thus allowing to interpolate SST anomalies using satellite data acquired at different times of the day (Marullo et al., 2014). [https://help.marine.copernicus.eu/en/articles/4444611-how-to-cite-or-reference-copernicus-marine-products-and-services How to cite] '''DOI (product) :''' https://doi.org/10.48670/moi-00170

'''Short description:''' For the '''Mediterranean Sea''' Ocean '''Satellite Observations''', the Italian National Research Council (CNR – Rome, Italy), is providing '''Bio-Geo_Chemical (BGC)''' regional datasets: * '''''plankton''''' with the phytoplankton chlorophyll concentration (CHL) evaluated via region-specific algorithms (Case 1 waters: Volpe et al., 2019, with new coefficients; Case 2 waters, Berthon and Zibordi, 2004), and the interpolated '''gap-free''' Chl concentration (to provide a ""cloud free"" product) estimated by means of a modified version of the DINEOF algorithm (Volpe et al., 2018) * '''''transparency''''' with the diffuse attenuation coefficient of light at 490 nm (KD490) (for '''""multi'''"" observations achieved via region-specific algorithm, Volpe et al., 2019) * '''''pp''''' with the Integrated Primary Production (PP). '''Upstreams''': SeaWiFS, MODIS, MERIS, VIIRS-SNPP & JPSS1, OLCI-S3A & S3B for the '''""multi""''' products, and OLCI-S3A & S3B for the '''""olci""''' products '''Temporal resolutions''': monthly and daily (for '''""gap-free""''' and '''""pp""''' data) '''Spatial resolutions''': 1 km for '''""multi""''' (4 km for '''""pp""''') and 300 meters for '''""olci""''' To find this product in the catalogue, use the search keyword '''""OCEANCOLOUR_MED_BGC_L4_NRT""'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00298

'''DEFINITION''' This product includes the Mediterranean Sea satellite chlorophyll trend map based on regional chlorophyll reprocessed (MY) product as distributed by CMEMS OC-TAC (OCEANCOLOUR_MED_BGC_L3_NRT_009_141). This dataset, derived from multi-sensor (SeaStar-SeaWiFS, AQUA-MODIS, NOAA20-VIIRS, NPP-VIIRS, Envisat-MERIS and Sentinel3-OLCI) (at 1 km resolution) Rrs spectra produced by CNR using an in-house processing chain, is obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 (off-shore) waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 (coastal) waters, Berthon and Zibordi, 2004). The processing chain and the techniques used for algorithms merging are detailed in Colella et al. (2023). The trend map is obtained by applying Colella et al. (2016) methodology, where the Mann-Kendall test (Mann, 1945; Kendall, 1975) and Sens’s method (Sen, 1968) are applied on deseasonalized monthly time series, as obtained from the X-11 technique (see e. g. Pezzulli et al. 2005), to estimate, trend magnitude and its significance. The trend is expressed in % per year that represents the relative changes (i.e., percentage) corresponding to the dimensional trend [mg m-3 y-1] with respect to the reference climatology (1997-2014). Only significant trends (p < 0.05) are included. This OMI has been introduced since the 2nd issue of Ocean State Report in 2017. '''CONTEXT''' Phytoplankton are key actors in the carbon cycle and, as such, recognised as an Essential Climate Variable (ECV). Chlorophyll concentration - as a proxy for phytoplankton - respond rapidly to changes in environmental conditions, such as light, temperature, nutrients and mixing (Colella et al. 2016). The character of the response depends on the nature of the change drivers, and ranges from seasonal cycles to decadal oscillations (Basterretxea et al. 2018). The Mediterranean Sea is an oligotrophic basin, where chlorophyll concentration decreases following a specific gradient from West to East (Colella et al. 2016). The highest concentrations are observed in coastal areas and at the river mouths, where the anthropogenic pressure and nutrient loads impact on the eutrophication regimes (Colella et al. 2016). The the use of long-term time series of consistent, well-calibrated, climate-quality data record is crucial for detecting eutrophication. Furthermore, chlorophyll analysis also demands the use of robust statistical temporal decomposition techniques, in order to separate the long-term signal from the seasonal component of the time series. '''KEY FINDINGS''' The chlorophyll trend in the Mediterranean Sea for the 1997–2024 period confirms the findings of the previous release, with predominantly negative values observed across most of the basin. On average, the region shows a trend of approximately -0.77% per year, slightly more negative than the overall trend reported previously. As in earlier assessments, weak positive trends persist in specific areas such as the northern Aegean Sea and the Sicily Channel. Compared to the 1997–2023 period, new positive trends are now evident in the Gulf of Lion. In contrast to the findings of Salgado-Hernanz et al. (2019), which were based on satellite observations from 1998 to 2014, this analysis does not reveal a distinct difference between the western and eastern Mediterranean basins. Notably, the Ligurian Sea now exhibits a negative trend, diverging from the positive trends identified by Colella et al. (2016) for the 1998–2009 period and by Salgado-Hernanz et al. (2019) for 1998–2014. Similarly, the waters of the Northern Adriatic Sea show weak positive trends, differing from the strong negative trend previously reported by Colella et al. (2016), and also representing a shift from the positive values observed by Salgado-Hernanz et al. (2019). '''DOI (product):''' https://doi.org/10.48670/moi-00260

'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318

'''Short description:''' For the '''Mediterranean Sea''' Ocean '''Satellite Observations''', the Italian National Research Council (CNR – Rome, Italy), is providing multi-years '''Bio-Geo_Chemical (BGC)''' regional datasets: * '''''plankton''''' with the phytoplankton chlorophyll concentration (CHL) evaluated via region-specific algorithms (Case 1 waters: Volpe et al., 2019, with new coefficients; Case 2 waters, Berthon and Zibordi, 2004), and the interpolated '''gap-free''' Chl concentration (to provide a "cloud free" product) estimated by means of a modified version of the DINEOF algorithm (Volpe et al., 2018); moreover, daily climatology for chlorophyll concentration is provided. * '''''pp''''' with the Integrated Primary Production (PP). '''Upstreams''': SeaWiFS, MODIS, MERIS, VIIRS-SNPP & JPSS1, OLCI-S3A & S3B for the '''"multi"''' products, and OLCI-S3A & S3B for the '''"olci"''' products '''Temporal resolutions''': monthly and daily (for '''"gap-free"''' and climatology data) '''Spatial resolution''': 1 km for '''"multi"''' and 300 meters for '''"olci"''' To find this product in the catalogue, use the search keyword '''"OCEANCOLOUR_MED_BGC_L4_MY"'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00300

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261

'''Short description:''' For the Mediterranean Sea - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Near Real-Time Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are updated several times daily to provide the best product timeliness. '''DOI (product) :''' https://doi.org/10.48670/mds-00334

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS REP Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2020 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' Some coastal and shelf waters, especially between 30 and 400N showed active oligotrophication flags for 2020, with some scattered offshore locations within the same latitudinal belt also showing oligotrophication. Eutrophication index is positive only for a small number of coastal locations just north of 40oN, and south of 30oN. In general, the indicator map showed very few areas with active eutrophication flags for 2019 and for 2020. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''Short description:''' The Reprocessed (REP) Mediterranean (MED) dataset provides a stable and consistent long-term Sea Surface Temperature (SST) time series over the Mediterranean Sea (and the adjacent North Atlantic box) developed for climate applications. This product consists of daily (nighttime), merged multi-sensor (L3S), satellite-based estimates of the foundation SST (namely, the temperature free, or nearly-free, of any diurnal cycle) at 0.05° resolution grid covering the period from 1st January 1981 to present (approximately one month before real time). The MED-REP-L3S product is built from a consistent reprocessing of the collated level-3 (merged single-sensor, L3C) climate data record (CDR) v.3.0, provided by the ESA Climate Change Initiative (CCI) and covering the period up to 2021, and its interim extension (ICDR) that allows the regular temporal extension for 2022 onwards. '''DOI (product) :''' https://doi.org/10.48670/moi-00314