'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS REP Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2020 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' Some coastal and shelf waters, especially between 30 and 400N showed active oligotrophication flags for 2020, with some scattered offshore locations within the same latitudinal belt also showing oligotrophication. Eutrophication index is positive only for a small number of coastal locations just north of 40oN, and south of 30oN. In general, the indicator map showed very few areas with active eutrophication flags for 2019 and for 2020. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean- The L3 multi-sensor (supercollated) product is built from bias-corrected L3 mono-sensor (collated) products at the resolution 0.02 degrees. If the native collated resolution is N and N < 0.02 the change (degradation) of resolution is done by averaging the best quality data. If N > 0.02 the collated data are associated to the nearest neighbour without interpolation nor artificial increase of the resolution. A synthesis of the bias-corrected L3 mono-sensor (collated) files remapped at resolution R is done through a selection of data based on the following hierarchy: AVHRR_METOP_B, VIIRS_NPP, SLSTRA, SEVIRI, AVHRRL-19, MODIS_A, MODIS_T, AMSR2. This hierarchy can be changed in time depending on the health of each sensor. '''DOI (product) :''' https://doi.org/10.48670/moi-00163

'''Short description:''' This product provides daily (nighttime), gap-free (Level-4, L4) maps of foundation Sea Surface Temperature (SST) - that is, the SST free from diurnal warming - over the Mediterranean Sea, at high (HR, 1/16°) and ultra-high (UHR, 1/100°) spatial resolutions, covering the period from 2008 to present. Each map represents nighttime SST values (centered at 00:00 UTC) and is produced by the Italian National Research Council – Institute of Marine Sciences (CNR-ISMAR). L4 maps are generated by selecting only the highest-quality SST observations from upstream Level-2 (L2) data acquired within a short local nighttime window, in order to minimize cloud contamination and avoid the effects of the diurnal cycle. The main L2 sources currently ingested include SLSTR from Sentinel-3A and -3B, VIIRS from NOAA-21, NOAA-20, and Suomi-NPP, AVHRR from Metop-B and -C, and SEVIRI. A two-step algorithm allows to interpolate SST data at high and ultra-high spatial resolution, applying statistical techniques (Buongiorno Nardelli et al., 2013; Buongiorno Nardelli et al., 2015). Additionally, from 2024 onwards, an improved first-guess field has been used in the generation of the MED UHR L4 data, enhancing the product's spatial resolution of SST features and the accuracy of SST gradients via machine learning techniques (Fanelli et al., 2024). '''DOI (product) :''' https://doi.org/10.48670/moi-00172

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally distributes Remote Sensing Reflectances (Rrs) and diffuse attenuation coefficient of light at 490 nm (kd490) data. These datasets derived from Rrs multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI) spectra at the state-of-the-art algorithms for multi-sensor merging. Single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. Reprocessed (multi-year) products are consistent and homogeneous in terms of format, algorithms and processing software. Rrs is defined as the ratio of upwelling radiance and downwelling irradiance at any wavelength (412, 443, 490, 555, and 670 nm). Kd490 is defined as the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates within the water column. It is directly related to the presence of scattering particles in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. Kd490 is achieved via Mediterranean regional algorithm developed by GOS on the basis of MedBiOp in situ dataset (Volpe et al., 2019). The current day data temporal consistency is evaluated as Quality Index (QI): QI=(CurrentDataPixel-ClimatologyDataPixel)/STDDataPixel where QI is the difference between current data and the relevant climatological field as a signed multiple of climatological standard deviations (STDDataPixel). Inherent Optical Properties (aph443, adg443 and bbp443 at 443nm) are derived via QAAv6 model. '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll and kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' * dataset-oc-med-opt-multi-l3-rrs412_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs490_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs510_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs555_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs670_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-kd490_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-bbp443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-adg443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-aph443_1km_daily-rep-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00116

'''Short description:''' The Reprocessed (REP) Mediterranean (MED) dataset provides a stable and consistent long-term Sea Surface Temperature (SST) time series over the Mediterranean Sea (and the adjacent North Atlantic box) developed for climate applications. This product consists of daily (nighttime), optimally interpolated (L4), satellite-based estimates of the foundation SST (namely, the temperature free, or nearly-free, of any diurnal cycle) at 0.05° resolution grid covering the period from 1st January 1981 to present (approximately one month before real time). The MED-REP-L4 product is built from a consistent reprocessing of the collated level-3 (merged single-sensor, L3C) climate data record (CDR) v.3.0, provided by the ESA Climate Change Initiative (CCI) and covering the period up to 2021, and its interim extension (ICDR) that allows the regular temporal extension for 2022 onwards. '''DOI (product) :''' https://doi.org/10.48670/moi-00173

'''Short description:''' For the '''Mediterranean Sea''' Ocean '''Satellite Observations''', the Italian National Research Council (CNR – Rome, Italy), is providing multi-years '''Bio-Geo_Chemical (BGC)''' regional datasets: * '''''plankton''''' with the phytoplankton chlorophyll concentration (CHL) evaluated via region-specific algorithms (Case 1 waters: Volpe et al., 2019, with new coefficients; Case 2 waters, Berthon and Zibordi, 2004), and the interpolated '''gap-free''' Chl concentration (to provide a "cloud free" product) estimated by means of a modified version of the DINEOF algorithm (Volpe et al., 2018); moreover, daily climatology for chlorophyll concentration is provided. * '''''pp''''' with the Integrated Primary Production (PP). '''Upstreams''': SeaWiFS, MODIS, MERIS, VIIRS-SNPP & JPSS1, OLCI-S3A & S3B for the '''"multi"''' products, and OLCI-S3A & S3B for the '''"olci"''' products '''Temporal resolutions''': monthly and daily (for '''"gap-free"''' and climatology data) '''Spatial resolution''': 1 km for '''"multi"''' and 300 meters for '''"olci"''' To find this product in the catalogue, use the search keyword '''"OCEANCOLOUR_MED_BGC_L4_MY"'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00300

'''Short description:''' The Mean Dynamic Topography MDT-CMEMS_2020_MED is an estimate of the mean over the 1993-2012 period of the sea surface height above geoid for the Mediterranean Sea. This is consistent with the reference time period also used in the SSALTO DUACS products '''DOI (product) :''' https://doi.org/10.48670/moi-00151

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces Level-4 product includes monthly averaged datasets of the diffuse attenuation coefficient of light at 490 nm (Kd490) for multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI observations (at 300m resolution). Kd490 is the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates the water column. It is directly related to the presence of absorbing and scattering matter in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. For the multi-sensor dataset, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by the GOS. The QAA allows the inversion of the radiative transfer equations to compute the Inherent Optical Properties. Level-4 product includes monthly averages along with the standard deviation and the number of observations in the period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Time averages are computed on the delayed-time data. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names :''' *dataset-oc-med-opt-multi-l4-kd490_1km_monthly-rt-v02 *dataset-oc-med-opt-olci-l4-kd490_300m_monthly-rt '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00117

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean - Sea Surface Temperature Mono-Sensor L3 Observations. One SST file per 24h per area and per sensor (bias corrected) closest to the original resolution: SLSTR-A, AMSR2, SEVIRI, AVHRR_METOP_B, AVHRR18_G, AVHRR_19L, MODIS_A, MODIS_T, VIIRS_NPP. One SST file per file window per area and per sensor (bias corrected) closest to the original resolution , while still manageable in terms volume over the processed area. '''Description of observation methods/instruments:''' The METOP_B derived SSTs are not bias corrected because METOP_B is used as the reference sensor for the correction method. '''DOI (product) :''' https://doi.org/10.48670/moi-00162

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261