'''DEFINITION:''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) provided by the ESA Ocean Colour Climate Change Initiative (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT:''' Phytoplankton – and chlorophyll concentration as their proxy – respond rapidly to changes in their physical environment. In the North Atlantic region these changes present a distinct seasonality and are mostly determined by light and nutrient availability (González Taboada et al., 2014). By comparing annual mean values to a climatology, we effectively remove the seasonal signal at each grid point, while retaining information on potential events during the year (Gregg and Rousseaux, 2014). In particular, North Atlantic anomalies can then be correlated with oscillations in the Northern Hemisphere Temperature (Raitsos et al., 2014). Chlorophyll anomalies also provide information on the status of the North Atlantic oligotrophic gyre, where evidence of rapid gyre expansion has been found for the 1997-2012 period (Polovina et al. 2008, Aiken et al., 2017, Sathyendranath et al., 2018b). '''CMEMS KEY FINDINGS:''' The average chlorophyll anomaly in the North Atlantic is -0.02 log10(mg m-3), with a maximum value of 1.0 log10(mg m-3) and a minimum value of -1.0 log10(mg m-3). That is to say that, in average, the annual 2019 mean value is slightly lower (96%) than the 1997-2014 climatological value. A moderate increase in chlorophyll concentration was observed in 2019 over the Bay of Biscay and regions close to Iceland and Greenland, such as the Irminger Basin and the Denmark Strait. In particular, the annual average values for those areas are around 160% of the 1997-2014 average (anomalies > 0.2 log10(mg m-3)). While the significant negative anomalies reported for 2016-2017 (Sathyendranath et al., 2018c) in the area west of the Ireland and Scotland coasts continued to manifest, the Irish and North Seas returned to their normative regime during 2019, with anomalies close to zero. A change in the anomaly sign (positive to negative) was also detected for the West European Basin, with annual values as low as 60% of the 1997-2014 average. This reduction in chlorophyll might be matched with negative anomalies in sea level during the period, indicating a dominance of upwelling factors over stratification.

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261

'''This product has been archived'''                For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' Experimental altimeter satellite along-track sea surface heights anomalies (SLA) computed with respect to a twenty-year [1993, 2012] mean with a 5Hz (~1.3km) sampling. All the missions are homogenized with respect to a reference mission (see QUID document or http://duacs.cls.fr [http://duacs.cls.fr] pages for processing details). The product gives additional variables (e.g. Mean Dynamic Topography, Dynamic Atmosphic Correction, Ocean Tides, Long Wavelength Errors, Internal tide, …) that can be used to change the physical content for specific needs This product was generated as experimental products in a CNES R&D context. It was processed by the DUACS multimission altimeter data processing system. '''DOI (product) :''' https://doi.org/10.48670/moi-00137

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes surface chlorophyll concentration (mg m-3) derived from multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, and Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI (at high resolution, 300m) Rrs spectra. Chlorophyll datasets are obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum at pixel-by-pixel level with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case 1 and Case 2 information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. This product identifies the average chlorophyll content of the surface layer as defined by the first optical depth (roughly one fifth of the euphotic depth). For multi-sensor observations, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. The current day data temporal consistency is evaluated as Quality Index (QI): QI=(CurrentDataPixel-ClimatologyDataPixel)/STDDataPixel where QI is the difference between current data and the relevant climatological field as a signed multiple of climatological standard deviations (STDDataPixel). '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour, which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l3-chl_1km_daily-rt-v02 *dataset-oc-med-chl-olci-l3-chl_300m_daily-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00111

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean- The L3 multi-sensor (supercollated) product is built from bias-corrected L3 mono-sensor (collated) products at the resolution 0.02 degrees. If the native collated resolution is N and N < 0.02 the change (degradation) of resolution is done by averaging the best quality data. If N > 0.02 the collated data are associated to the nearest neighbour without interpolation nor artificial increase of the resolution. A synthesis of the bias-corrected L3 mono-sensor (collated) files remapped at resolution R is done through a selection of data based on the following hierarchy: AVHRR_METOP_B, VIIRS_NPP, SLSTRA, SEVIRI, AVHRRL-19, MODIS_A, MODIS_T, AMSR2. This hierarchy can be changed in time depending on the health of each sensor. '''DOI (product) :''' https://doi.org/10.48670/moi-00163

'''Short description:''' For the Mediterranean Sea - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are processed homogeneously starting from the L2OCN products. '''DOI (product) :''' https://doi.org/10.48670/mds-00342

'''Short description:''' The Reprocessed (REP) Mediterranean (MED) dataset provides a stable and consistent long-term Sea Surface Temperature (SST) time series over the Mediterranean Sea (and the adjacent North Atlantic box) developed for climate applications. This product consists of daily (nighttime), merged multi-sensor (L3S), satellite-based estimates of the foundation SST (namely, the temperature free, or nearly-free, of any diurnal cycle) at 0.05° resolution grid covering the period from 1st January 1981 to present (approximately one month before real time). The MED-REP-L3S product is built from a consistent reprocessing of the collated level-3 (merged single-sensor, L3C) climate data record (CDR) v.3.0, provided by the ESA Climate Change Initiative (CCI) and covering the period up to 2021, and its interim extension (ICDR) that allows the regular temporal extension for 2022 onwards. '''DOI (product) :''' https://doi.org/10.48670/moi-00314

'''DEFINITION''' The time series are derived from the regional chlorophyll reprocessed (MY) product as distributed by CMEMS (OCEANCOLOUR_MED_BGC_L3_NRT_009_141). This dataset, derived from multi-sensor (SeaStar-SeaWiFS, AQUA-MODIS, NOAA20-VIIRS, NPP-VIIRS, Envisat-MERIS and Sentinel3-OLCI) Rrs spectra produced by CNR using an in-house processing chain, is obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 (off-shore) waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 (coastal) waters, Berthon and Zibordi, 2004). The processing chain and the techniques used for algorithms merging are detailed in Colella et al. (2023). Monthly regional mean values are calculated by performing the average of 2D monthly mean (weighted by pixel area) over the region of interest. The deseasonalized time series is obtained by applying the X-11 seasonal adjustment methodology on the original time series as described in Colella et al. (2016), and then the Mann-Kendall test (Mann, 1945; Kendall, 1975) and Sens’s method (Sen, 1968) are subsequently applied to obtain the magnitude of trend. This OMI has been introduced since the 2nd issue of Ocean State Report in 2017. '''CONTEXT''' Phytoplankton and chlorophyll concentration as a proxy for phytoplankton respond rapidly to changes in environmental conditions, such as light, temperature, nutrients and mixing (Colella et al. 2016). The character of the response depends on the nature of the change drivers, and ranges from seasonal cycles to decadal oscillations (Basterretxea et al. 2018). Therefore, it is of critical importance to monitor chlorophyll concentration at multiple temporal and spatial scales, in order to be able to separate potential long-term climate signals from natural variability in the short term. In particular, phytoplankton in the Mediterranean Sea is known to respond to climate variability associated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al. 2018, Colella et al. 2016). '''KEY FINDINGS''' In the Mediterranean Sea, the average chlorophyll trend for the 1997–2024 period is slightly negative, at -0.77 ± 0.59% per year, reinforcing the findings of the previous releases. This result contrasts with the analysis by Sathyendranath et al. (2018), which reported increasing chlorophyll concentrations across all European seas. From around 2010–2011 onward, excluding the 2018–2019 period, a noticeable decline in chlorophyll levels is evident in the deseasonalized time series (green line) and in the observed maxima (grey line), particularly from 2015. This sustained decline over the past decade contributes to the overall negative trend observed in the Mediterranean Sea. '''DOI (product):''' https://doi.org/10.48670/moi-00259

'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR) in Rome distributes reprocessed surface chlorophyll concentration (Chl) and phytoplankton functional types (PFT). Input Rrs multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI) spectra at the state-of-the-art algorithms for multi-sensor merging. Single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged. Reprocessed (multi-year) products are consistent and homogeneous in terms of format, algorithms and processing software. Chl is obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Volpe et al., 2019) and AD4 (Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average spectrum from in situ measurements. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where Case II spectra are selected with a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between observed and reference spectra and using it as weight for the final value. The PFT provides estimates of Chl concentration of 9 phytoplankton groups: Micro, Nano, Pico, Diato, Dino, Crypto, Hapto, Green and Prokar. Micro consists of Diato and Dino, Nano includes Crypto and Hapto and Pico is referred to Green and Prokar with the adjustment of Brewin et al. (2010) in the ultra-oligotrophic water for Pico and Nano. These classes are estimated via empirical regional functions, correlating Chl concentration with each in-situ PFT fraction computed by a regional diagnostic pigment analysis (Di Cicco et al. 2017). '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll and kd490) are estimated via state-of-the-art algorithms for better product quality. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' * dataset-oc-med-chl-multi-l3-chl_1km_daily-rep-v02 * dataset-oc-med-pft-multi-l3-pft_1km_daily-rep-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00112