'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261

''' Short description: ''' For the Mediterranean Sea - the CNR diurnal sub-skin Sea Surface Temperature (SST) product provides daily gap-free (L4) maps of hourly mean sub-skin SST at 1/16° (0.0625°) horizontal resolution over the CMEMS Mediterranean Sea (MED) domain, by combining infrared satellite and model data (Marullo et al., 2014). The implementation of this product takes advantage of the consolidated operational SST processing chains that provide daily mean SST fields over the same basin (Buongiorno Nardelli et al., 2013). The sub-skin temperature is the temperature at the base of the thermal skin layer and it is equivalent to the foundation SST at night, but during daytime it can be significantly different under favorable (clear sky and low wind) diurnal warming conditions. The sub-skin SST L4 product is created by combining geostationary satellite observations aquired from SEVIRI and model data (used as first-guess) aquired from the CMEMS MED Monitoring Forecasting Center (MFC). This approach takes advantage of geostationary satellite observations as the input signal source to produce hourly gap-free SST fields using model analyses as first-guess. The resulting SST anomaly field (satellite-model) is free, or nearly free, of any diurnal cycle, thus allowing to interpolate SST anomalies using satellite data acquired at different times of the day (Marullo et al., 2014). [https://help.marine.copernicus.eu/en/articles/4444611-how-to-cite-or-reference-copernicus-marine-products-and-services How to cite] '''DOI (product) :''' https://doi.org/10.48670/moi-00170

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces Level-4 product includes monthly averaged datasets of the diffuse attenuation coefficient of light at 490 nm (Kd490) for multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI observations (at 300m resolution). Kd490 is the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates the water column. It is directly related to the presence of absorbing and scattering matter in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. For the multi-sensor dataset, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by the GOS. The QAA allows the inversion of the radiative transfer equations to compute the Inherent Optical Properties. Level-4 product includes monthly averages along with the standard deviation and the number of observations in the period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Time averages are computed on the delayed-time data. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names :''' *dataset-oc-med-opt-multi-l4-kd490_1km_monthly-rt-v02 *dataset-oc-med-opt-olci-l4-kd490_300m_monthly-rt '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00117

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Level-4 product including the daily interpolated chlorophyll field with no data voids starting from the multi-sensor (MODIS-Aqua, NOAA-20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI), the monthly averaged chlorophyll concentration for the multi-sensor and climatological fields, all at 1 km resolution. Chlorophyll field are obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. The interpolated gap-free Level-4 Chl concentration is estimated by means of a modified version of the DINEOF algorithm by GOS (Volpe et al., 2018). DINEOF is an iterative procedure in which EOF are used to reconstruct the entire field domain. As first guess, it uses the SeaWiFS-derived daily climatological values at missing pixels and satellite observations at valid pixels. Monthly Level-4 dataset is the time averages of the L3 fields and includes the standard deviation and the number of observations in the monthly period of integration. SeaWiFS daily climatology provides reference for the calculation of Quality Indices (QI) for Chl observations. '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll) are estimated via state-of-the-art algorithms for better product quality. Level-4 includes both monthly time averages and the daily-interpolated fields. Time averages are computed on the delayed-time data. The interpolated product starts from the L3 products at 1 km resolution. At the first iteration, DINEOF procedure uses, as first guess for each of the missing pixels the relative daily climatological pixel. A procedure to smooth out spurious spatial gradients is applied to the daily merged image (observation and climatology). From the second iteration, the procedure uses, as input for the next one, the field obtained by the EOF calculation, using only a number of modes: that is, at the second round, only the first two modes, at the third only the first three, and so on. At each iteration, the same smoothing procedure is applied between EOF output and initial observations. The procedure stops when the variance explained by the current EOF mode exceeds that of noise. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). For the climatology Rrs data are derived from the latest SeaWiFS NASA reprocessing (R2018.0) and converted to chlorophyll concentrations with the same algorithm as the one used for other L4 and/or L3 products. '''Description of observation methods/instruments:''' Ocean color technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean color which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of both the cal/val and a more in depth view of the method is given in QUID-009-038to045-071-073-078-079-095-096.pdf over Copernicus web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l4-chl_1km_monthly-rep-v02 *dataset-oc-med-chl-multi-l4-interp_1km_daily-rep *dataset-oc-med-chl-seawifs-l4-chl_1km_daily-climatology-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant. '''DOI (product) :''' https://doi.org/10.48670/moi-00114

'''Short description:''' The Reprocessed (REP) Mediterranean (MED) dataset provides a stable and consistent long-term Sea Surface Temperature (SST) time series over the Mediterranean Sea (and the adjacent North Atlantic box) developed for climate applications. This product consists of daily (nighttime), merged multi-sensor (L3S), satellite-based estimates of the foundation SST (namely, the temperature free, or nearly-free, of any diurnal cycle) at 0.05° resolution grid covering the period from 1st January 1981 to present (approximately one month before real time). The MED-REP-L3S product is built from a consistent reprocessing of the collated level-3 (merged single-sensor, L3C) climate data record (CDR) v.3.0, provided by the ESA Climate Change Initiative (CCI) and covering the period up to 2021, and its interim extension (ICDR) that allows the regular temporal extension for 2022 onwards. '''DOI (product) :''' https://doi.org/10.48670/moi-00314

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean - Sea Surface Temperature Mono-Sensor L3 Observations. One SST file per 24h per area and per sensor (bias corrected) closest to the original resolution: SLSTR-A, AMSR2, SEVIRI, AVHRR_METOP_B, AVHRR18_G, AVHRR_19L, MODIS_A, MODIS_T, VIIRS_NPP. One SST file per file window per area and per sensor (bias corrected) closest to the original resolution , while still manageable in terms volume over the processed area. '''Description of observation methods/instruments:''' The METOP_B derived SSTs are not bias corrected because METOP_B is used as the reference sensor for the correction method. '''DOI (product) :''' https://doi.org/10.48670/moi-00162

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Level-4 product including the daily interpolated chlorophyll field with no data voids starting from the multi-sensor (MODIS-Aqua, NOAA-20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and the monthly averaged chlorophyll concentration for the multi-sensor (at 1 km resolution) and Sentinel-OLCI Level-3 (at 300m resolution). Chlorophyll field are obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. The interpolated gap-free Level-4 Chl concentration is estimated by means of a modified version of the DINEOF algorithm by GOS (Volpe et al., 2018). DINEOF is an iterative procedure in which EOF are used to reconstruct the entire field domain. As first guess, it uses the SeaWiFS-derived daily climatological values at missing pixels and satellite observations at valid pixels. The other Level-4 dataset is the time averages of the L3 fields and includes the standard deviation and the number of observations in the monthly period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Level-4 includes both monthly time averages and the daily-interpolated fields. Time averages are computed on the delayed-time data. The interpolated product starts from the L3 products at 1 km resolution. At the first iteration, DINEOF procedure uses, as first guess for each of the missing pixels the relative daily climatological pixel. A procedure to smooth out spurious spatial gradients is applied to the daily merged image (observation and climatology). From the second iteration, the procedure uses, as input for the next one, the field obtained by the EOF calculation, using only a number of modes: that is, at the second round, only the first two modes, at the third only the first three, and so on. At each iteration, the same smoothing procedure is applied between EOF output and initial observations. The procedure stops when the variance explained by the current EOF mode exceeds that of noise. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the pre+D2sence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l4-chl_1km_monthly-rt-v02 *dataset-oc-med-chl-multi-l4-interp_1km_daily-rt-v02 *dataset-oc-med-chl-olci-l4-chl_300m_monthly-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00113

'''Short description:''' Near Real-Time mono-mission satellite-based 2D full wave spectral product. These very complete products enable to characterise spectrally the direction, wave length and multiple sea Sates along CFOSAT track (in boxes of 70km/90km left and right from the nadir pointing). The data format are 2D directionnal matrices. They also include integrated parameters (Hs, direction, wavelength) from the spectrum with and without partitions. '''DOI (product) :''' https://doi.org/10.48670/mds-00382

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean, the L4 multi-sensor daily satellite product is a 2km horizontal resolution subskin sea surface temperature analysis. This SST analysis is run by Meteo France CMS and is built using the European Ocean L3S products originating from bias-corrected European Ocean L3C mono-sensor products at 0.02 degrees resolution. This analysis uses the analysis of the previous day at the same time as first guess field. '''DOI (product) :''' https://doi.org/10.48670/moi-00161

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR) in Rome distributes reprocessed surface chlorophyll concentration (Chl) and phytoplankton functional types (PFT). Input Rrs multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI) spectra at the state-of-the-art algorithms for multi-sensor merging. Single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged. Reprocessed (multi-year) products are consistent and homogeneous in terms of format, algorithms and processing software. Chl is obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Volpe et al., 2019) and AD4 (Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average spectrum from in situ measurements. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where Case II spectra are selected with a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between observed and reference spectra and using it as weight for the final value. The PFT provides estimates of Chl concentration of 9 phytoplankton groups: Micro, Nano, Pico, Diato, Dino, Crypto, Hapto, Green and Prokar. Micro consists of Diato and Dino, Nano includes Crypto and Hapto and Pico is referred to Green and Prokar with the adjustment of Brewin et al. (2010) in the ultra-oligotrophic water for Pico and Nano. These classes are estimated via empirical regional functions, correlating Chl concentration with each in-situ PFT fraction computed by a regional diagnostic pigment analysis (Di Cicco et al. 2017). '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll and kd490) are estimated via state-of-the-art algorithms for better product quality. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' * dataset-oc-med-chl-multi-l3-chl_1km_daily-rep-v02 * dataset-oc-med-pft-multi-l3-pft_1km_daily-rep-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00112