'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' Global Ocean- in-situ reprocessed Carbon observations. This product contains observations and gridded files from two up-to-date carbon and biogeochemistry community data products: Surface Ocean Carbon ATlas SOCATv2021 and GLobal Ocean Data Analysis Project GLODAPv2.2021. The SOCATv2021-OBS dataset contains >25 million observations of fugacity of CO2 of the surface global ocean from 1957 to early 2021. The quality control procedures are described in Bakker et al. (2016). These observations form the basis of the gridded products included in SOCATv2020-GRIDDED: monthly, yearly and decadal averages of fCO2 over a 1x1 degree grid over the global ocean, and a 0.25x0.25 degree, monthly average for the coastal ocean. GLODAPv2.2021-OBS contains >1 million observations from individual seawater samples of temperature, salinity, oxygen, nutrients, dissolved inorganic carbon, total alkalinity and pH from 1972 to 2019. These data were subjected to an extensive quality control and bias correction described in Olsen et al. (2020). GLODAPv2-GRIDDED contains global climatologies for temperature, salinity, oxygen, nitrate, phosphate, silicate, dissolved inorganic carbon, total alkalinity and pH over a 1x1 degree horizontal grid and 33 standard depths using the observations from the previous iteration of GLODAP, GLODAPv2. SOCAT and GLODAP are based on community, largely volunteer efforts, and the data providers will appreciate that those who use the data cite the corresponding articles (see References below) in order to support future sustainability of the data products. '''DOI (product) :''' https://doi.org/10.48670/moi-00035

ERA‐40 is a re‐analysis of meteorological observations from September 1957 to August 2002 produced by the European Centre for Medium‐Range Weather Forecasts (ECMWF)

In recent years, large datasets of in situ marine carbonate system parameters (partial pressure of CO2 (pCO2), total alkalinity, dissolved inorganic carbon and pH) have been collated. These carbonate system datasets have highly variable data density in both space and time, especially in the case of pCO2, which is routinely measured at high frequency using underway measuring systems. This variation in data density can create biases when the data are used, for example for algorithm assessment, favouring datasets or regions with high data density. A common way to overcome data density issues is to bin the data into cells of equal latitude and longitude extent. This leads to bins with spatial areas that are latitude and projection dependent (eg become smaller and more elongated as the poles are approached). Additionally, as bin boundaries are defined without reference to the spatial distribution of the data or to geographical features, data clusters may be divided sub-optimally (eg a bin covering a region with a strong gradient). To overcome these problems and to provide a tool for matching in situ data with satellite, model and climatological data, which often have very different spatiotemporal scales both from the in situ data and from each other, a methodology has been created to group in situ data into ‘regions of interest’, spatiotemporal cylinders consisting of circles on the Earth’s surface extending over a period of time. These regions of interest are optimally adjusted to contain as many in situ measurements as possible. All in situ measurements of the same parameter contained in a region of interest are collated, including estimated uncertainties and regional summary statistics. The same grouping is done for each of the other datasets, producing a dataset of matchups. About 35 million in situ datapoints were then matched with data from five satellite sources and five model and re-analysis datasets to produce a global matchup dataset of carbonate system data, consisting of 287,000 regions of interest spanning 54 years from 1957 to 2023. Each region of interest is 50 km in diameter and 5 days in duration, improving the spatial and temporal resolution of the previous version (v3.4). The list of sources added in this dataset includes: - sea surface temperature and sea ice concentration from Copernicus Climate Service Multi-satellite L4 (http://dx.doi.org/10.5285/62c0f97b1eac4e0197a674870afe1ee6) - sea surface salinity from the Copernicus Marine service Multi Observation Global Ocean Sea Surface Salinity and Sea Surface Density (https://doi.org/10.48670/moi-00051) - Surface ocean sea-air CO2 fluxes and total alkalinity from ETH Zurich OceanSODA-ETHZ-v2 gridded dataset (https://doi.org/10.5281/zenodo.11206366) - salinity and mixed layer depth from SODA v3.4.2 reanalysis (https://doi.org/10.1175/JCLI-D-18-0149.1) - chlorophyll-A from ESA Ocean Colour CCI v6 (doi:10.3390/s19194285) - wind at 10 m and mean sea level pressure from ERA5 reanalysis - nitrate, silicate, phosphate, oxygen, temperature and salinity from World Ocean Atlas 2018 - sea level anomaly from Global Ocean Gridded L4 Sea Surface Heights And Derived Variables Multi-Year dataset by Copernicus Marine Service Information (https://doi.org/10.48670/moi-00148) - sea surface salinity from ESA Salinity CCI L4 v3.2.1 (https://dx.doi.org/10.5285/5920a2c77e3c45339477acd31ce62c3c) - sea surface salinity from JPL SMAP Level 3 CAP Sea Surface Salinity (https://doi.org/10.5067/SMP40-3SPCS) - temperature and salinity from Coriolis Observation Re-Analysis CORA5.2 by Copernicus Marine Service (https://doi.org/10.17882/46219) - subskin sea surface temperature from NOAA OISST SST (http://doi.org/10.5067/GHAAO-4BC01) - sea surface salinity from the Arctic salinity dataset (https://doi.org/10.20350/digitalCSIC/9065) the Barcelona Expert Center (http://bec.icm.csic.es/) - pH and spCO2 from Copernicus Marine Service Surface Ocean Carbon Dataset (https://doi.org/10.48670/moi-00047) An example application, the reparameterisation of a global total alkalinity algorithm, is shown. This matchup dataset can be updated as and when in situ and other datasets are updated, and similar datasets at finer spatiotemporal scale can be constructed, for example to enable regional studies. This dataset was funded by ESA OceanHealth / Ocean Acidification project which aims at developing the use of satellite Earth Observation for studying and monitoring marine carbonate chemistry.

Seawater samples (500 mL) were taken during the PIRATA FR-32 cruise to measure surface inorganic carbon and alkalinity. The analyses were realised by potentiometric titration using a closed-cell at the SNAPO-CO2, LOCEAN in Paris.

This product displays for Hexachlorobenzene, median values since 2012 that have been measured per matrix and are present in EMODnet regional contaminants aggregated datasets, v2024. The median values ranges are derived from the following percentiles: 0-25%, 25-75%, 75-90%, >90%. Only "good data" are used, namely data with Quality Flag=1, 2, 6, Q (SeaDataNet Quality Flag schema). For water, only surface values are used (0-15 m), for sediment and biota data at all depths are used.

This set of data documents the radiocarbon dates (n=19) obtained thanks to the accelerator mass spectrometry method (AMS) at the LMC14/ARTEMIS French national facility on the cores (Multicorer, Kullenberg) retrieved from the West-Gironde mud patch (WGMP) during the JERICObent-7 cruise (10-15 July 2019; NR Côtes de la Manche, https://doi.org/10.17600/18001022). The WGMP registers very high sedimentation rates since the last 600 years (≥ 0.3 cm/yr) and is thus of great interest for palaeoceanographic investigations. At present, this depocenter marks the mid-shelf of the temperate Bay of Biscay off major French rivers from the Aquitaine basin. The fine mud deposits of the WGMP are of 3 to 4 meters thick and lie on palimpsest levels rich in gravels and shells. They cover a V-shaped structure, oriented SW-NE, which is attributed to the incision(s) of a paleovalley in the Cenozoic substrate, mainly linked to the paleo-Gironde routing changes during past glacials/interglacials, and its potential past convergences with the paleo-rivers of the Antioche perthuis (Seudre, Charente paleovalleys?) at that times. Detailed information on each sample is presented with the 14C results obtained by the Artemis AMS facility at LMC14 laboratory (Dumoulin et al. 2017- https://doi.org/10.1017/RDC.2016.116, Beck et al. 2024- https://doi.org/10.1017/RDC.2023.23). Raw ages are indicated together with calibration calculations using the last two versions of the Calib software (http://calib.org/, Calib 7 and 8) to show the dispersion of ages linked to the updating of calibration curves (Marine13, Intcal13, Marine20, Intcal 20). The calibrated ages finally retained for publications (used in the related Seanoe document - https://doi.org/10.17882/104237 - and published in Eynaud et al., 2025 for the ST3c core, https://doi.org/10.1016/j.gloplacha.2025.105039) are those obtained with the last Calib 8.1 version. Raw 14C ages were calibrated and converted to calendar ages using the IntCal20 calibration curve with a reservoir age correction of 400 years deduced from Radionuclide analyses (137Cs and 210Pb) at the top of the studied cores (see Schmidt, 2025, https://www.seanoe.org/data/00968/107979/).