'''Short description:''' Le modèle biogéochimique ECO-MARS3D sur la façade Manche Atlantique (PREVIMER_B1-ECOMARS3D-MANGA4000) est un modèle 3D de résolution spatiale 4km qui fournit les concentrations de nutriments et de plancton toutes les heures sur 30 niveaux (fenêtre de prévision à 4 jours). '''Paramètres calculés :''' Les paramètres calculés sont les suivants : * SAL : sea_water_salinity * TEMP : sea_water_temperature * suspended_inorganic_particulate_matter : mass_concentration_of_suspended_matter_in_sea_water * nanopicoplankton_nitrogen : mole_concentration_of_nanoplankton_expressed_as_nitrogen_in_sea_water * diatom_nitrogen : mole_concentration_of_diatoms_expressed_as_nitrogen_in_sea_water * dinoflagellate_nitrogen : mole_concentration_of_dinoflagellates_expressed_as_nitrogen_in_sea_water * microzooplankton_nitrogen : mole_concentration_of_microzooplankton_expressed_as_nitrogen_in_sea_water * mesozooplankton_nitrogen : mole_concentration_of_mesozooplankton_expressed_as_nitrogen_in_sea_water * colonial_phaeocystis_nitrogen : mole_concentration_of_colonial_phaeocystis_expressed_as_nitrogen_in_sea_water * phaeocystis_mucus : concentration_of_phaeocystis_mucus_expressed_as_mass_in_sea_water * ammonium : mole_concentration_of_ammonium_in_sea_water * nitrate : mole_concentration_of_nitrate_in_sea_water * dissolved_silicate : mole_concentration_of_silicate_in_sea_water * dissolved_phosphate : mole_concentration_of_phosphate_in_sea_water * dissolved_oxygen : dissolved_oxygen_in_water_column * cumulative_nanoflagellate_carbon_production : cumulative_nanoflagellate_production_expressed_as_carbon_in_sea_water * cumulative_diatom_carbon_production : cumulative_diatom_production_expressed_as_carbon_in_sea_water * cumulative_dinoflagellate_carbon_production : cumulative_dinoflagellate_production_expressed_as_carbon_in_sea_water * cumulative_phaeocystis_carbon_production : cumulative_phaeocystis_production_expressed_as_carbon_in_sea_water * organic_nitrogen_benth : mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_benthos Les paramètres diagnostiques calculés sont les suivants : * XE : sea_surface_height_above_geoid * maximum_de_diat : maximum_diatom_mass_concentration_in_sea_water * maximum_de_dino : maximum_dinoflagellate_mass_concentration_in_sea_water * maximum_de_nano : maximum_nanoflagellate_mass_concentration_in_sea_water * grad_vert_salinite : maximum_vertical_gradient_of_sea_water_salinity * grad_vert_temp : maximum_vertical_gradient_of_sea_water_temperature * extinction_lumineuse : light_extinction_in_sea_water * prod_diat : cumulated_production_of_diatoms_in_sea_water_column_expressed_in_carbon * prod_dino : cumulated_production_of_dinoflagellates_in_sea_water_column_expressed_in_carbon * prod_nano : cumulated_production_of_nanoflagellates_in_sea_water_column_expressed_in_carbon * chlorophylle_a : chlorophyll_mass_concentration_in_sea_water * prod_cumul_chloro : cumulated_total_production_in_sea_water_column_expressed_in_carbon * maximum_de_phaeocystis : maximum_phaeocystis_mass_concentration_in_sea_water * prod_phaeocystis : cumulated_production_of_phaeocystis_in_sea_water_column_expressed_in_carbon * oxygen_saturation : oxygen_saturation * ammoniumGIRON_tracer_sign: mole_concentration_of_ammonium_in_sea_waterGIRON_tracer_sign * ammoniumGIRON_tracer_age: mole_concentration_of_ammonium_in_sea_waterGIRON_tracer_age * nitrateGIRON_tracer_sign: mole_concentration_of_nitrate_in_sea_waterGIRON_tracer_sign * nitrateGIRON_tracer_age: mole_concentration_of_nitrate_in_sea_waterGIRON_tracer_age * nanopicoplankton_nitrogenGIRON_tracer_sign: mole_concentration_of_nanoplankton_expressed_as_nitrogen_in_sea_waterGIRON_tracer_sign * nanopicoplankton_nitrogenGIRON_tracer_age: mole_concentration_of_nanoplankton_expressed_as_nitrogen_in_sea_waterGIRON_tracer_age * diatom_nitrogenGIRON_tracer_sign: mole_concentration_of_diatoms_expressed_as_nitrogen_in_sea_waterGIRON_tracer_sign * diatom_nitrogenGIRON_tracer_age: mole_concentration_of_diatoms_expressed_as_nitrogen_in_sea_waterGIRON_tracer_age * dinoflagellate_nitrogenGIRON_tracer_sign: mole_concentration_of_dinoflagellates_expressed_as_nitrogen_in_sea_waterGIRON_tracer_sign * dinoflagellate_nitrogenGIRON_tracer_age: mole_concentration_of_dinoflagellates_expressed_as_nitrogen_in_sea_waterGIRON_tracer_age * microzooplankton_nitrogenGIRON_tracer_sign: mole_concentration_of_microzooplankton_expressed_as_nitrogen_in_sea_waterGIRON_tracer_sign * microzooplankton_nitrogenGIRON_tracer_age: mole_concentration_of_microzooplankton_expressed_as_nitrogen_in_sea_waterGIRON_tracer_age * mesozooplankton_nitrogenGIRON_tracer_sign: mole_concentration_of_mesozooplankton_expressed_as_nitrogen_in_sea_waterGIRON_tracer_sign * mesozooplankton_nitrogenGIRON_tracer_age: mole_concentration_of_mesozooplankton_expressed_as_nitrogen_in_sea_waterGIRON_tracer_age * detrital_nitrogenGIRON_tracer_sign: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_sea_waterGIRON_tracer_sign * detrital_nitrogenGIRON_tracer_age: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_sea_waterGIRON_tracer_age * colonial_phaeocystis_nitrogenGIRON_tracer_sign: mole_concentration_of_colonial_phaeocystis_expressed_as_nitrogen_in_sea_waterGIRON_tracer_sign * colonial_phaeocystis_nitrogenGIRON_tracer_age: mole_concentration_of_colonial_phaeocystis_expressed_as_nitrogen_in_sea_waterGIRON_tracer_age * phaeocystis_cells_nitrogenGIRON_tracer_sign: mole_concentration_of_phaeocystis_cells_expressed_as_nitrogen_in_sea_waterGIRON_tracer_sign * phaeocystis_cells_nitrogenGIRON_tracer_age: mole_concentration_of_phaeocystis_cells_expressed_as_nitrogen_in_sea_waterGIRON_tracer_age * organic_nitrogen_benthGIRON_tracer_sign: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_benthosGIRON_tracer_sign * organic_nitrogen_benthGIRON_tracer_age: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_benthosGIRON_tracer_age * phytoplankton_sign_N_GIRON: nitrogen_fraction_in_phytoplankton_from_source_GIRON * phytoplankton_age_N_GIRON: age_of_nitrogen_fraction_in_phytoplankton_from_source_GIRON * ammoniumLOIRE_tracer_sign: mole_concentration_of_ammonium_in_sea_waterLOIRE_tracer_sign * ammoniumLOIRE_tracer_age: mole_concentration_of_ammonium_in_sea_waterLOIRE_tracer_age * nitrateLOIRE_tracer_sign: mole_concentration_of_nitrate_in_sea_waterLOIRE_tracer_sign * nitrateLOIRE_tracer_age: mole_concentration_of_nitrate_in_sea_waterLOIRE_tracer_age * nanopicoplankton_nitrogenLOIRE_tracer_sign: mole_concentration_of_nanoplankton_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_sign * nanopicoplankton_nitrogenLOIRE_tracer_age: mole_concentration_of_nanoplankton_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_age * diatom_nitrogenLOIRE_tracer_sign: mole_concentration_of_diatoms_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_sign * diatom_nitrogenLOIRE_tracer_age: mole_concentration_of_diatoms_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_age * dinoflagellate_nitrogenLOIRE_tracer_sign: mole_concentration_of_dinoflagellates_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_sign * dinoflagellate_nitrogenLOIRE_tracer_age: mole_concentration_of_dinoflagellates_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_age * microzooplankton_nitrogenLOIRE_tracer_sign: mole_concentration_of_microzooplankton_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_sign * microzooplankton_nitrogenLOIRE_tracer_age: mole_concentration_of_microzooplankton_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_age * mesozooplankton_nitrogenLOIRE_tracer_sign: mole_concentration_of_mesozooplankton_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_sign * mesozooplankton_nitrogenLOIRE_tracer_age: mole_concentration_of_mesozooplankton_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_age * detrital_nitrogenLOIRE_tracer_sign: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_sign * detrital_nitrogenLOIRE_tracer_age: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_age * colonial_phaeocystis_nitrogenLOIRE_tracer_sign: mole_concentration_of_colonial_phaeocystis_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_sign * colonial_phaeocystis_nitrogenLOIRE_tracer_age: mole_concentration_of_colonial_phaeocystis_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_age * phaeocystis_cells_nitrogenLOIRE_tracer_sign: mole_concentration_of_phaeocystis_cells_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_sign * phaeocystis_cells_nitrogenLOIRE_tracer_age: mole_concentration_of_phaeocystis_cells_expressed_as_nitrogen_in_sea_waterLOIRE_tracer_age * organic_nitrogen_benthLOIRE_tracer_sign: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_benthosLOIRE_tracer_sign * organic_nitrogen_benthLOIRE_tracer_age: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_benthosLOIRE_tracer_age * phytoplankton_sign_N_LOIRE: nitrogen_fraction_in_phytoplankton_from_source_LOIRE * phytoplankton_age_N_LOIRE: age_of_nitrogen_fraction_in_phytoplankton_from_source_LOIRE * ammoniumSEINE_tracer_sign: mole_concentration_of_ammonium_in_sea_waterSEINE_tracer_sign * ammoniumSEINE_tracer_age: mole_concentration_of_ammonium_in_sea_waterSEINE_tracer_age * nitrateSEINE_tracer_sign: mole_concentration_of_nitrate_in_sea_waterSEINE_tracer_sign * nitrateSEINE_tracer_age: mole_concentration_of_nitrate_in_sea_waterSEINE_tracer_age * nanopicoplankton_nitrogenSEINE_tracer_sign: mole_concentration_of_nanoplankton_expressed_as_nitrogen_in_sea_waterSEINE_tracer_sign * nanopicoplankton_nitrogenSEINE_tracer_age: mole_concentration_of_nanoplankton_expressed_as_nitrogen_in_sea_waterSEINE_tracer_age * diatom_nitrogenSEINE_tracer_sign: mole_concentration_of_diatoms_expressed_as_nitrogen_in_sea_waterSEINE_tracer_sign * diatom_nitrogenSEINE_tracer_age: mole_concentration_of_diatoms_expressed_as_nitrogen_in_sea_waterSEINE_tracer_age * dinoflagellate_nitrogenSEINE_tracer_sign: mole_concentration_of_dinoflagellates_expressed_as_nitrogen_in_sea_waterSEINE_tracer_sign * dinoflagellate_nitrogenSEINE_tracer_age: mole_concentration_of_dinoflagellates_expressed_as_nitrogen_in_sea_waterSEINE_tracer_age * microzooplankton_nitrogenSEINE_tracer_sign: mole_concentration_of_microzooplankton_expressed_as_nitrogen_in_sea_waterSEINE_tracer_sign * microzooplankton_nitrogenSEINE_tracer_age: mole_concentration_of_microzooplankton_expressed_as_nitrogen_in_sea_waterSEINE_tracer_age * mesozooplankton_nitrogenSEINE_tracer_sign: mole_concentration_of_mesozooplankton_expressed_as_nitrogen_in_sea_waterSEINE_tracer_sign * mesozooplankton_nitrogenSEINE_tracer_age: mole_concentration_of_mesozooplankton_expressed_as_nitrogen_in_sea_waterSEINE_tracer_age * detrital_nitrogenSEINE_tracer_sign: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_sea_waterSEINE_tracer_sign * detrital_nitrogenSEINE_tracer_age: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_sea_waterSEINE_tracer_age * colonial_phaeocystis_nitrogenSEINE_tracer_sign: mole_concentration_of_colonial_phaeocystis_expressed_as_nitrogen_in_sea_waterSEINE_tracer_sign * colonial_phaeocystis_nitrogenSEINE_tracer_age: mole_concentration_of_colonial_phaeocystis_expressed_as_nitrogen_in_sea_waterSEINE_tracer_age * phaeocystis_cells_nitrogenSEINE_tracer_sign: mole_concentration_of_phaeocystis_cells_expressed_as_nitrogen_in_sea_waterSEINE_tracer_sign * phaeocystis_cells_nitrogenSEINE_tracer_age: mole_concentration_of_phaeocystis_cells_expressed_as_nitrogen_in_sea_waterSEINE_tracer_age * organic_nitrogen_benthSEINE_tracer_sign: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_benthosSEINE_tracer_sign * organic_nitrogen_benthSEINE_tracer_age: mole_concentration_of_organic_detritus_expressed_as_nitrogen_in_benthosSEINE_tracer_age * phytoplankton_sign_N_SEINE: nitrogen_fraction_in_phytoplankton_from_source_SEINE * phytoplankton_age_N_SEINE: age_of_nitrogen_fraction_in_phytoplankton_from_source_SEINE

Moving 10-years analysis of pH at Mediterranean Sea for each season : - winter (January-March), - spring (April-June), - summer (July-September), - autumn (October-December). Every year of the time dimension corresponds to the 10-year centered average of each season. Decades span from 1959-1968 until 2005-2014. Observational data span from 1930 to 2014. Depth range (IODE standard depths): -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0, -30.0, -20.0, -10.0, -5.0, -0.0. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. Profiles were interpolated at standard depths using weighted parabolic interpolation algorithm (Reiniger and Ross, 1968). GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5. DIVA settings: A constant value for signal-to-noise ratio was used equal to 1. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Originators of Italian data sets-List of contributors: o Brunetti Fabio (OGS) o Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 o Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 o Cataletto Bruno (OGS) o Cinzia Comici Cinzia (OGS) o Civitarese Giuseppe (OGS) o DeVittor Cinzia (OGS) o Giani Michele (OGS) o Kovacevic Vedrana (OGS) o Mosetti Renzo (OGS) o Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 o Celio Massimo (ARPA FVG) o Malaguti Antonella (ENEA) o Fonda Umani Serena (UNITS) o Bignami Francesco (ISAC/CNR) o Boldrini Alfredo (ISMAR/CNR) o Marini Mauro (ISMAR/CNR) o Miserocchi Stefano (ISMAR/CNR) o Zaccone Renata (IAMC/CNR) o Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D., Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d'Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011. Units: pH units

'''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS MY Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2021 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' The coastal and shelf waters, especially between 30 and 400N that showed active oligotrophication flags for 2020 have reduced in 2021 and a reversal to eutrophic flags can be seen in places. Again, the eutrophication index is positive only for a small number of coastal locations just north of 40oN in 2021, however south of 40oN there has been a significant increase in eutrophic flags, particularly around the Azores. In general, the 2021 indicator map showed an increase in oligotrophic areas in the Northern Atlantic and an increase in eutrophic areas in the Southern Atlantic. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''Short description:''' Altimeter satellite gridded Sea Level Anomalies (SLA) computed with respect to a twenty-year [1993, 2012] mean. The SLA is estimated by Optimal Interpolation, merging the L3 along-track measurement from the different altimeter missions available. Part of the processing is fitted to the European Sea area. (see QUID document or http://duacs.cls.fr [http://duacs.cls.fr] pages for processing details). The product gives additional variables (i.e. Absolute Dynamic Topography and geostrophic currents (absolute and anomalies)). It serves in delayed-time applications. This product is processed by the DUACS multimission altimeter data processing system. '''DOI (product):''' https://doi.org/10.48670/moi-00141

Metabolome of of the marine diatom Haslea ostrearia. Bacteria were isolated from Haslea ostrearia isolates cultivated in ES 1/3 medium in laboratory conditions over a 3-month period. These microalgal isolates were recovered from four sites on the French Atlantic coast: Bouin , La Barre-de-Monts (46.90 N; 2.11°W), Isle de Ré (46.22 N; 1.45°W), and La Tremblade (45.80 N; 1.15°W) . Data processing and statistical analysis of the metabolic profiles were performed on an LC/MS Metabolomics Discovery Workflow using Mass Profiler Professional Software and an Agilent 1290 Infinity II LC system coupled to an Agilent 6540 UHD Accurate-Mass QTOF hybrid mass spectrometer (Agilent Technologies, Waldbronn, Germany) equipped with a dual electrospray ionization (ESI) source. The full history (tools, parameters, input and output data files) is publicly available on http://dx.doi.org/10.12770/046e1e6a-864e-48a6-944b-d8613d67de0f