Rapport final ONF

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, acidity and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). ITS-90 water temperature and Water body salinity variables have been also included (as-is) to complete the Eutrophication and Acidity data. If you use these variables for calculations, please refer to SeaDataNet for having the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets . This aggregated dataset contains all unrestricted EMODnet Chemistry data on Eutrophication and Acidity (14 parameters with quality flag indicators), and covers the Mediterranean Sea with 67271 CDI records (60876 Vertical profiles and 6395 Time series). Vertical profiles temporal range is from 1911-08-17 to 2017-10-25. Time series temporal range is from 1974-06-04 to 2015-12-22. Data were aggregated and quality controlled by 'Hellenic Centre for Marine Research, Hellenic National Oceanographic Data Centre (HCMR/HNODC)' from Greece. Regional datasets concerning eutrophication and acidity are automatically harvested and resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all Sea Regions ( https://doi.org/10.6092/9f75ad8a-ca32-4a72-bf69-167119b2cc12). When not present in original data, Water body nitrate plus nitrite was calculated by summing up the Nitrates and Nitrites. Same procedure was applied for Water body dissolved inorganic nitrogen (DIN) which was calculated by summing up the Nitrates, Nitrites and Ammonium. Parameter names are based on P35, EMODnet Chemistry aggregated parameter names vocabulary, which is available at: https://www.bodc.ac.uk/resources/vocabularies/vocabulary_search/P35/. Detailed documentation is available at: https://doi.org/10.6092/ec8207ef-ed81-4ee5-bf48-e26ff16bf02e The aggregated dataset can be downloaded as ODV spreadsheet, which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' The time series are derived from the regional chlorophyll reprocessed (REP) product as distributed by CMEMS. This dataset, derived from multi-sensor (SeaStar-SeaWiFS, AQUA-MODIS, NOAA20-VIIRS, NPP-VIIRS, Envisat-MERIS and Sentinel3A-OLCI) Rrs spectra produced by CNR using an in-house processing chain, is obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 (off-shore) waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 (coastal) waters, Berthon and Zibordi, 2004). The processing chain and the techniques used for algorithms merging are detailed in Colella et al. (2021). Monthly regional mean values are calculated by performing the average of 2D monthly mean (weighted by pixel area) over the region of interest. The deseasonalized time series is obtained by applying the X-11 seasonal adjustment methodology on the original time series as described in Colella et al. (2016), and then the Mann-Kendall test (Mann, 1945; Kendall, 1975) and Sens’s method (Sen, 1968) are subsequently applied to obtain the magnitude of trend. '''CONTEXT''' Phytoplankton and chlorophyll concentration as a proxy for phytoplankton respond rapidly to changes in environmental conditions, such as light, temperature, nutrients and mixing (Colella et al. 2016). The character of the response depends on the nature of the change drivers, and ranges from seasonal cycles to decadal oscillations (Basterretxea et al. 2018). Therefore, it is of critical importance to monitor chlorophyll concentration at multiple temporal and spatial scales, in order to be able to separate potential long-term climate signals from natural variability in the short term. In particular, phytoplankton in the Mediterranean Sea is known to respond to climate variability associated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al. 2018, Colella et al. 2016). '''CMEMS KEY FINDINGS''' In the Mediterranean Sea, the trend average for the 1997-2020 period is slightly negative (-0.580.62% per year). Due to the change in processing techniques and chlorophyll retrieval, this trend estimate cannot be compared directly to those previously reported. The observations time series (in grey) shows minima values have been quite constant until 2015 and then there is a little decrease up to 2020, when an absolute minimum occurs with values lower than 0.04 mg m-3. Throughout the time series, maxima are variable year by year (with absolute maximum in 2015, >0.14 mg m-3), showing an evident reduction since 2016. In the last years of the series, the decrease of chlorophyll concentrations is also observed in the deseasonalized timeseries (in green) with a marked step in 2020. This attenuation of chlorophyll values in the last years results in an overall negative trend for the Mediterranean Sea. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00259

'''DEFINITION''' Variations of the Mediterranean Outflow Water at 1000 m depth are monitored through area-averaged salinity anomalies in specifically defined boxes. The salinity data are extracted from several CMEMS products and averaged in the corresponding monitoring domain: * IBI-MYP: IBI_MULTIYEAR_PHY_005_002 * IBI-NRT: IBI_ANALYSISFORECAST_PHYS_005_001 * GLO-MYP: GLOBAL_REANALYSIS_PHY_001_030 * CORA: INSITU_GLO_TS_REP_OBSERVATIONS_013_002_b * ARMOR: MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012 The anomalies of salinity have been computed relative to the monthly climatology obtained from IBI-MYP. Outcomes from diverse products are combined to deliver a unique multi-product result. Multi-year products (IBI-MYP, GLO,MYP, CORA, and ARMOR) are used to show an ensemble mean and the standard deviation of members in the covered period. The IBI-NRT short-range product is not included in the ensemble, but used to provide the deterministic analysis of salinity anomalies in the most recent year. '''CONTEXT''' The Mediterranean Outflow Water is a saline and warm water mass generated from the mixing processes of the North Atlantic Central Water and the Mediterranean waters overflowing the Gibraltar sill (Daniault et al., 1994). The resulting water mass is accumulated in an area west of the Iberian Peninsula (Daniault et al., 1994) and spreads into the North Atlantic following advective pathways (Holliday et al. 2003; Lozier and Stewart 2008, de Pascual-Collar et al., 2019). The importance of the heat and salt transport promoted by the Mediterranean Outflow Water flow has implications beyond the boundaries of the Iberia-Biscay-Ireland domain (Reid 1979, Paillet et al. 1998, van Aken 2000). For example, (i) it contributes substantially to the salinity of the Norwegian Current (Reid 1979), (ii) the mixing processes with the Labrador Sea Water promotes a salt transport into the inner North Atlantic (Talley and MacCartney, 1982; van Aken, 2000), and (iii) the deep anti-cyclonic Meddies developed in the African slope is a cause of the large-scale westward penetration of Mediterranean salt (Iorga and Lozier, 1999). Several studies have demonstrated that the core of Mediterranean Outflow Water is affected by inter-annual variability. This variability is mainly caused by a shift of the MOW dominant northward-westward pathways (Bozec et al. 2011), it is correlated with the North Atlantic Oscillation (Bozec et al. 2011) and leads to the displacement of the boundaries of the water core (de Pascual-Collar et al., 2019). The variability of the advective pathways of MOW is an oceanographic process that conditions the destination of the Mediterranean salt transport in the North Atlantic. Therefore, monitoring the Mediterranean Outflow Water variability becomes decisive to have a proper understanding of the climate system and its evolution (e.g. Bozec et al. 2011, Pascual-Collar et al. 2019). The CMEMS IBI-OMI_WMHE_mow product is aimed to monitor the inter-annual variability of the Mediterranean Outflow Water in the North Atlantic. The objective is the establishment of a long-term monitoring program to observe the variability and trends of the Mediterranean water mass in the IBI regional seas. To do that, the salinity anomaly is monitored in key areas selected to represent the main reservoir and the three main advective spreading pathways. More details and a full scientific evaluation can be found in the CMEMS Ocean State report Pascual et al., 2018 and de Pascual-Collar et al. 2019. '''CMEMS KEY FINDINGS''' The absence of long-term trends in the monitoring domain Reservoir (b) suggests the steadiness of water mass properties involved on the formation of Mediterranean Outflow Water. Results obtained in monitoring box North (c) present an alternance of periods with positive and negative anomalies. The last negative period started in 2016 reaching up to the present. Such negative events are linked to the decrease of the northward pathway of Mediterranean Outflow Water (Bozec et al., 2011), which appears to return to steady conditions in 2020 and 2021. Results for box West (d) reveal a cycle of negative (2015-2017) and positive (2017 up to the present) anomalies. The positive anomalies of salinity in this region are correlated with an increase of the westward transport of salinity into the inner North Atlantic (de Pascual-Collar et al., 2019), which appear to be maintained for years 2020-2021. Results in monitoring boxes North and West are consistent with independent studies (Bozec et al., 2011; and de Pascual-Collar et al., 2019), suggesting a westward displacement of Mediterranean Outflow Water and the consequent contraction of the northern boundary. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00258

Tronçons linéaires de voies de l'Aquitaine romaine - projet Aquitaviae

'''This product has been archived'''                For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' The indicator of the Kuroshio extension phase variations is based on the standardized high frequency altimeter Eddy Kinetic Energy (EKE) averaged in the area 142-149°E and 32-37°N and computed from the DUACS (https://duacs.cls.fr) delayed-time (reprocessed version DT-2021, CMEMS SEALEVEL_GLO_PHY_L4_MY_008_047) and near real-time (CMEMS SEALEVEL_GLO_PHY_L4_NRT_OBSERVATIONS_008_046) altimeter sea level gridded products. The change in the reprocessed version (previously DT-2018) and the extension of the mean value of the EKE (now 27 years, previously 20 years) induce some slight changes not impacting the general variability of the Kuroshio extension (correlation coefficient of 0.988 for the total period, 0.994 for the delayed time period only). '''CONTEXT''' The long-term mean and trends alone do not give a complete view of the likely changes in position of unstable western boundary current extensions (Kelly et al., 2010). The Kuroshio Extension is an eastward-flowing current in the subtropical western North Pacific after the Kuroshio separates from the coast of Japan at 35°N, 140°E. Being the extension of a wind-driven western boundary current, the Kuroshio Extension is characterized by a strong variability and is rich in large-amplitude meanders and energetic eddies (Niiler et al., 2003; Qiu, 2003, 2002). The Kuroshio Extension region has the largest sea surface height variability on sub-annual and decadal time scales in the extratropical North Pacific Ocean (Jayne et al., 2009; Qiu and Chen, 2010, 2005). Prediction and monitoring of the path of the Kuroshio are of huge importance for local economies as the position of the Kuroshio extension strongly determines the regions where phytoplankton and hence fish are located. '''CMEMS KEY FINDINGS''' The different states of the Kuroshio extension phase have been presented and validated by Bessières et al. (2013) and further reported by Drévillon et al. (2018) in the Copernicus Ocean State Report #2. Two rather different states of the Kuroshio extension are observed: an ‘elongated state’ (also called ‘strong state’) corresponding to a narrow strong steady jet, and a ‘contracted state’ (also called ‘weak state’) in which the jet is weaker and more unsteady, spreading on a wider latitudinal band. When the Kuroshio Extension jet is in a contracted (elongated) state, the upstream Kuroshio Extension path tends to become more (less) variable and regional eddy kinetic energy level tends to be higher (lower). In between these two opposite phases, the Kuroshio extension jet has many intermediate states of transition and presents either progressively weakening or strengthening trends. In 2018, the indicator reveals an elongated state followed by a weakening neutral phase since then. '''DOI (product):''' https://doi.org/10.48670/moi-00222

'''DEFINITION''' Heat transport across lines are obtained by integrating the heat fluxes along some selected sections and from top to bottom of the ocean. The values are computed from models’ daily output. The mean value over a reference period (1993-2014) and over the last full year are provided for the ensemble product and the individual reanalysis, as well as the standard deviation for the ensemble product over the reference period (1993-2014). The values are given in PetaWatt (PW). '''CONTEXT''' The ocean transports heat and mass by vertical overturning and horizontal circulation, and is one of the fundamental dynamic components of the Earth’s energy budget (IPCC, 2013). There are spatial asymmetries in the energy budget resulting from the Earth’s orientation to the sun and the meridional variation in absorbed radiation which support a transfer of energy from the tropics towards the poles. However, there are spatial variations in the loss of heat by the ocean through sensible and latent heat fluxes, as well as differences in ocean basin geometry and current systems. These complexities support a pattern of oceanic heat transport that is not strictly from lower to high latitudes. Moreover, it is not stationary and we are only beginning to unravel its variability. '''CMEMS KEY FINDINGS''' The mean transports estimated by the ensemble global reanalysis are comparable to estimates based on observations; the uncertainties on these integrated quantities are still large in all the available products. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00245

'''DEFINITION''' Ocean acidification is quantified by decreases in pH, which is a measure of acidity: a decrease in pH value means an increase in acidity, that is, acidification. The observed decrease in ocean pH resulting from increasing concentrations of CO2 is an important indicator of global change. The estimate of global mean pH builds on a reconstruction methodology, * Obtain values for alkalinity based on the so called “locally interpolated alkalinity regression (LIAR)” method after Carter et al., 2016; 2018. * Build on surface ocean partial pressure of carbon dioxide (CMEMS product: MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) obtained from an ensemble of Feed-Forward Neural Networks (Chau et al. 2022) which exploit sampling data gathered in the Surface Ocean CO2 Atlas (SOCAT) (https://www.socat.info/) * Derive a gridded field of ocean surface pH based on the van Heuven et al., (2011) CO2 system calculations using reconstructed pCO2 (MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) and alkalinity. The global mean average of pH at yearly time steps is then calculated from the gridded ocean surface pH field. It is expressed in pH unit on total hydrogen ion scale. In the figure, the amplitude of the uncertainty (1σ ) of yearly mean surface sea water pH varies at a range of (0.0023, 0.0029) pH unit (see Quality Information Document for more details). The trend and uncertainty estimates amount to -0.0017±0.0004e-1 pH units per year. The indicator is derived from in situ observations of CO2 fugacity (SOCAT data base, www.socat.info, Bakker et al., 2016). These observations are still sparse in space and time. Monitoring pH at higher space and time resolutions, as well as in coastal regions will require a denser network of observations and preferably direct pH measurements. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020). '''CONTEXT''' The decrease in surface ocean pH is a direct consequence of the uptake by the ocean of carbon dioxide. It is referred to as ocean acidification. The International Panel on Climate Change (IPCC) Workshop on Impacts of Ocean Acidification on Marine Biology and Ecosystems (2011) defined Ocean Acidification as “a reduction in the pH of the ocean over an extended period, typically decades or longer, which is caused primarily by uptake of carbon dioxide from the atmosphere, but can also be caused by other chemical additions or subtractions from the ocean”. The pH of contemporary surface ocean waters is already 0.1 lower than at pre-industrial times and an additional decrease by 0.33 pH units is projected over the 21st century in response to the high concentration pathway RCP8.5 (Bopp et al., 2013). Ocean acidification will put marine ecosystems at risk (e.g. Orr et al., 2005; Gehlen et al., 2011; Kroeker et al., 2013). The monitoring of surface ocean pH has become a focus of many international scientific initiatives (http://goa-on.org/) and constitutes one target for SDG14 (https://sustainabledevelopment.un.org/sdg14). '''CMEMS KEY FINDINGS''' Since the year 1985, global ocean surface pH is decreasing at a rate of -0.0017±0.019 decade-1 '''DOI (product):''' https://doi.org/10.48670/moi-00224

Map at 1 degree resolution of 10 year linear trend in sea water temperature at 3 levels: surface, 500m , bottom

Pentadal (5-year average) resolution time-series of bottom temperature for North Atlantic ocean area deeper than 1000m. Calculate the 5 year average bottom temperature at each point on the grid and then calculate the area weighted average.