EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification, contaminants and litter. The chosen parameters are relevant for the Marine Strategy Framework Directive (MSFD), in particular for descriptors 5, 8, 9 and 10. The dataset contains standardized, harmonized and validated data collections from beach litter (monitoring and other sources). Datasets concerning beach and seafloor litter data are loaded in a central database after a semi-automated validation phase. Once loaded, a data assessment is performed in order to check data consistency and potential errors are corrected thanks to a feedback loop with data originators. For beach litter, the harmonized datasets contain all unrestricted EMODnet Chemistry data on beach litter, including monitoring data, data from cleaning surveys and data from research. A relevant part of the monitoring data has been considered for assessment purposes by the European institutions and therefore is tagged as MSFD_monitoring. EMODnet beach litter data and databases are hosted and maintained by 'Istituto Nazionale di Oceanografia e di Geofisica Sperimentale, Division of Oceanography (OGS/NODC)' from Italy. Data are formatted following Guidelines and forms for gathering marine litter data, which can be found at: https://doi.org/10.6092/15c0d34c-a01a-4091-91ac-7c4f561ab508 The updated vocabularies of admitted values are available at: https://nodc.ogs.it/marinelitter/vocab The harmonized datasets can be downloaded as EMODnet Beach litter data format Version 7.0, which is a spreadsheet file composed of 4 sheets: beach metadata, survey metadata, animals and litter. Local_CDI field in the survey metadata sheet allows to retrieve the original data.

This visualization product displays the cigarette related items abundance of marine macro-litter (> 2.5cm) per beach per year from Marine Strategy Framework Directive (MSFD) monitoring surveys without UNEP-MARLIN data. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of beach litter have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols and reference lists used on a European scale. Preliminary processings were necessary to harmonize all the data: - Exclusion of OSPAR 1000 protocol: in order to follow the approach of OSPAR that it is not including these data anymore in the monitoring; - Selection of MSFD surveys only (exclusion of other monitoring, cleaning and research operations); - Exclusion of beaches without coordinates; - Selection of cigarette related items only. The list of selected items is attached to this metadata. This list was created using EU Marine Beach Litter Baselines, the European Threshold Value for Macro Litter on Coastlines and the Joint list of litter categories for marine macro-litter monitoring from JRC (these three documents are attached to this metadata); - Selection of surveys referring to the UNEP-MARLIN list: the UNEP-MARLIN protocol differs from the other types of monitoring in that cigarette butts are surveyed in a 10m square. To avoid comparing abundances from very different protocols, the choice has been made to distinguish in two maps the cigarette related items results associated with the UNEP-MARLIN list from the others; - Normalization of survey lengths to 100m & 1 survey / year: in some case, the survey length was not exactly 100m, so in order to be able to compare the abundance of litter from different beaches a normalization is applied using this formula: Number of cigarette related items of the survey (normalized by 100 m) = Number of cigarette related items of the survey x (100 / survey length) Then, this normalized number of cigarette related items is summed to obtain the total normalized number of cigarette related items for each survey. Finally, the median abundance of cigarette related items for each beach and year is calculated from these normalized abundances of cigarette related items per survey. Sometimes the survey length was null or equal to 0. Assuming that the MSFD protocol has been applied, the length has been set at 100m in these cases. Percentiles 50, 75, 95 & 99 have been calculated taking into account cigarette related items from MSFD monitoring data (excluding UNEP-MARLIN protocol) for all years. More information is available in the attached documents. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area.

This dataset contains all satellite altimeter wave heights above 9 m, from the following satellite missions: ERS-1, ERS-2, Topex-Poseidon (Topex only), Envisat, SARAL, Jason-1, Jason-2, Jason-3, Sentinel-3A, Sentinel-3B, Sentinel-6A, Cryosat-2, CFOSAT, SWOT. Storm event identification used the DetectHsStorm package developed by M. De Carlo and F. Ardhuin (  https://github.com/ardhuin/) . This data can be combined with modeled storm tracks (see F. Ardhuin, M. De Carlo, Storm tracks based on wave heights from LOPS WAVEWATCH III hindcast and ERA5 reanalysis, years 1991-2024, SEANOE (2025). doi: 10.17882/105148 )

This visualization product displays the location of all the surveys present in the EMODnet marine litter database (MLDB). The different fishing gears used are represented by different colors. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of seafloor litter collected by international fish-trawl surveys have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols (OSPAR and MEDITS protocols) and reference lists used on a European scale. Moreover, within the same protocol, different gear types are deployed during bottom trawl surveys. Unlike other EMODnet seafloor litter products, all trawls surveyed since 2006 are included in this map even if the wingspread and/or the distance are unknown. Only surveys with an unknown number of items were excluded from this product. More information on data processing and calculation are detailed in the attached document. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area.

In recent years, large datasets of in situ marine carbonate system parameters (partial pressure of CO2 (pCO2), total alkalinity, dissolved inorganic carbon and pH) have been collated. These carbonate system datasets have highly variable data density in both space and time, especially in the case of pCO2, which is routinely measured at high frequency using underway measuring systems. This variation in data density can create biases when the data are used, for example for algorithm assessment, favouring datasets or regions with high data density. A common way to overcome data density issues is to bin the data into cells of equal latitude and longitude extent. This leads to bins with spatial areas that are latitude and projection dependent (eg become smaller and more elongated as the poles are approached). Additionally, as bin boundaries are defined without reference to the spatial distribution of the data or to geographical features, data clusters may be divided sub-optimally (eg a bin covering a region with a strong gradient). To overcome these problems and to provide a tool for matching in situ data with satellite, model and climatological data, which often have very different spatiotemporal scales both from the in situ data and from each other, a methodology has been created to group in situ data into ‘regions of interest’, spatiotemporal cylinders consisting of circles on the Earth’s surface extending over a period of time. These regions of interest are optimally adjusted to contain as many in situ measurements as possible. All in situ measurements of the same parameter contained in a region of interest are collated, including estimated uncertainties and regional summary statistics. The same grouping is done for each of the other datasets, producing a dataset of matchups. About 35 million in situ datapoints were then matched with data from five satellite sources and five model and re-analysis datasets to produce a global matchup dataset of carbonate system data, consisting of 287,000 regions of interest spanning 54 years from 1957 to 2023. Each region of interest is 50 km in diameter and 5 days in duration, improving the spatial and temporal resolution of the previous version (v3.4). The list of sources added in this dataset includes: - sea surface temperature and sea ice concentration from Copernicus Climate Service Multi-satellite L4 (http://dx.doi.org/10.5285/62c0f97b1eac4e0197a674870afe1ee6) - sea surface salinity from the Copernicus Marine service Multi Observation Global Ocean Sea Surface Salinity and Sea Surface Density (https://doi.org/10.48670/moi-00051) - Surface ocean sea-air CO2 fluxes and total alkalinity from ETH Zurich OceanSODA-ETHZ-v2 gridded dataset (https://doi.org/10.5281/zenodo.11206366) - salinity and mixed layer depth from SODA v3.4.2 reanalysis (https://doi.org/10.1175/JCLI-D-18-0149.1) - chlorophyll-A from ESA Ocean Colour CCI v6 (doi:10.3390/s19194285) - wind at 10 m and mean sea level pressure from ERA5 reanalysis - nitrate, silicate, phosphate, oxygen, temperature and salinity from World Ocean Atlas 2018 - sea level anomaly from Global Ocean Gridded L4 Sea Surface Heights And Derived Variables Multi-Year dataset by Copernicus Marine Service Information (https://doi.org/10.48670/moi-00148) - sea surface salinity from ESA Salinity CCI L4 v3.2.1 (https://dx.doi.org/10.5285/5920a2c77e3c45339477acd31ce62c3c) - sea surface salinity from JPL SMAP Level 3 CAP Sea Surface Salinity (https://doi.org/10.5067/SMP40-3SPCS) - temperature and salinity from Coriolis Observation Re-Analysis CORA5.2 by Copernicus Marine Service (https://doi.org/10.17882/46219) - subskin sea surface temperature from NOAA OISST SST (http://doi.org/10.5067/GHAAO-4BC01) - sea surface salinity from the Arctic salinity dataset (https://doi.org/10.20350/digitalCSIC/9065) the Barcelona Expert Center (http://bec.icm.csic.es/) - pH and spCO2 from Copernicus Marine Service Surface Ocean Carbon Dataset (https://doi.org/10.48670/moi-00047) An example application, the reparameterisation of a global total alkalinity algorithm, is shown. This matchup dataset can be updated as and when in situ and other datasets are updated, and similar datasets at finer spatiotemporal scale can be constructed, for example to enable regional studies. This dataset was funded by ESA OceanHealth / Ocean Acidification project which aims at developing the use of satellite Earth Observation for studying and monitoring marine carbonate chemistry.

This visualization product displays the size of litter in percent per net per year from research and monitoring protocols. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Before 2021, there was no coordinated effort at the regional or European scale for micro-litter. Given this situation, EMODnet Chemistry proposed to adopt the data gathering and data management approach as generally applied for marine data, i.e., populating metadata and data in the CDI Data Discovery and Access service using dedicated SeaDataNet data transport formats. EMODnet Chemistry is currently the official EU collector of micro-litter data from Marine Strategy Framework Directive (MSFD) National Monitoring activities (descriptor 10). A series of specific standard vocabularies or standard terms related to micro-litter have been added to SeaDataNet NVS (NERC Vocabulary Server) Common Vocabularies to describe the micro-litter. European micro-litter data are collected by the National Oceanographic Data Centres (NODCs). Micro-litter map products are generated from NODCs data after a test of the aggregated collection including data and data format checks and data harmonization. A filter is applied to represent only micro-litter sampled according to research and monitoring protocols as MSFD monitoring. To calculate percentages for each size, formula applied is: Size (%) = (∑number of particles of each size)*100 / (∑number of particles of all size) When the number of microlitters was not filled or was equal to zero, it was not possible to calculate the percentage. Standard vocabularies for microliter sizes are taken from Seadatanet's H03 library (https://vocab.seadatanet.org/v_bodc_vocab_v2/search.asp?lib=H03 ). Different protocols with different degrees of precision were used to classify the sampled micro-litters. Consequently, on the map, the distribution of micro-litter in the size classes depends on the protocol applied during the survey. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the National Oceanographic Data Centre (NODC) for this area.

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data on potential hazardous substances, despite the fact that some data might not be related to pollution (e.g. collected by deep corer). Temperature, salinity and additional parameters are included when available. It covers the Mediterranean Sea. Data were harmonised and validated by the ‘Hellenic Centre for Marine Research, Hellenic National Oceanographic Data Centre (HCMR/HNODC)’ in Greece. The dataset contains water, sediment and biota profiles and timeseries. The temporal coverage is 1974–2022 for water measurements, 1971–2023 for sediment measurements and 1979-2023 for biota measurements. Regional datasets concerning contaminants are automatically harvested and the resulting collections are harmonised and validated using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.6092/8b52e8d7-dc92-4305-9337-7634a5cae3f4 ). Parameter names are based on P01 vocabulary, which relates to BODC Parameter Usage Vocabulary and is available at: https://vocab.nerc.ac.uk/search_nvs/P01/ . The harmonised dataset can be downloaded as as an ODV spreadsheet, which is composed of a metadata header followed by tab separated values. This spreadsheet can be imported into ODV Software for visualisation (more information can be found at: https://www.seadatanet.org/Software/ODV ). In addition, the same dataset is offered also as a txt file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms into subcomponents (substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications (e.g. LibreOffice Calc).

This dataset contains some diagnostics of biology of a global ocean simulation coupling dynamics and biogeochemistry at ¼° over the year 2019. The simulation has been performed using the coupled circulation/ecosystem model NEMO/PISCES (https://www.nemo-ocean.eu/), which is here enhanced to perform an ensemble simulation with explicit simulation of modeling uncertainties in the physics and in the biogeochemistry. This dataset is one of the 40 members of the ensemble simulation. This study was part of the Horizon Europe project SEAMLESS (https://seamlessproject.org/Home.html), with the general objective of improving the analysis and forecast of ecosystem indicators.   See Popov et al. (https://os.copernicus.org/articles/20/155/2024/) for more details on the study.

This visualization product displays the spatial distribution of the sampling effort over the six-years' period 2017-2022. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of seafloor litter collected by international fish-trawl surveys have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols (OSPAR and MEDITS protocols) and reference lists used on a European scale. Moreover, within the same protocol, different gear types are deployed during bottom trawl surveys. The spatial distribution was determined by calculating the number of times each cell was sampled during the period 2017-2022. The corresponding total distance (kms) sampled in each cell is also provided in the attribute table. Information on data processing and calculation are detailed in the attached methodology document. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area. This work is based on the work presented in the following scientific article: O. Gerigny, M. Brun, M.C. Fabri, C. Tomasino, M. Le Moigne, A. Jadaud, F. Galgani, Seafloor litter from the continental shelf and canyons in French Mediterranean Water: Distribution, typologies and trends, Marine Pollution Bulletin, Volume 146, 2019, Pages 653-666, ISSN 0025-326X, https://doi.org/10.1016/j.marpolbul.2019.07.030.

Moving 6-year analysis of Water body dissolved inorganic nitrogen (DIN) in the Mediterranean Sea for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 6-year centered average of the season. 6-years periods span from 1990-1995 until 2018-2023. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.12, using GEBCO 30sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.125 degrees (around 13.5km and 10.9km accordingly). The vertical resolution is 21 depth levels: [0.,5.,10.,20.,30.,50.,75.,100.,125.,150.,200.,250.,300.,400.,500.,600.,700.,800.,900.,1000.,1100.]. The horizontal correlation length is 200km. The vertical correlation length (in meters) was set twices the vertical resolution: [10.,10.,20.,20.,40.,50.,50.,50.,50.,100.,100.,100.,200.,200.,200.,200.,200.,200.,200.,200.,200.]. Duplicates check was performed using the following criteria for space and time: dlon=0.001deg., dlat=0.001deg., ddepth=1m, dtime=1hour, dvalue=0.1. The error variance (epsilon2) was set equal to 1 for profiles and 10 for time series to reduce the influence of close data near the coasts. An anamorphosis transformation was applied to the data (function DIVAnd.Anam.loglin) to avoid unrealistic negative values: threshold value=200. A background analysis field was used for all years (1990-2023) with correlation length equal to 600km and error variance (epsilon2) equal to 20. Quality control of the observations was applied using the interpolated field (QCMETHOD=3). Residuals (differences between the observations and the analysis (interpolated linearly to the location of the observations) were calculated. Observations with residuals outside the minimum and maximum values of the 99% quantile were discarded from the analysis. Originators of Italian data sets-List of contributors: - Brunetti Fabio (OGS) - Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 - Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 - Cataletto Bruno (OGS) - Cinzia Comici Cinzia (OGS) - Civitarese Giuseppe (OGS) - DeVittor Cinzia (OGS) - Giani Michele (OGS) - Kovacevic Vedrana (OGS) - Mosetti Renzo (OGS) - Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 - Celio Massimo (ARPA FVG) - Malaguti Antonella (ENEA) - Fonda Umani Serena (UNITS) - Bignami Francesco (ISAC/CNR) - Boldrini Alfredo (ISMAR/CNR) - Marini Mauro (ISMAR/CNR) - Miserocchi Stefano (ISMAR/CNR) - Zaccone Renata (IAMC/CNR) - Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D.,Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d'Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011.