EMODnet Chemistry aims to provide access to marine chemistry datasets and derived data products concerning eutrophication, acidity and contaminants. The importance of the selected substances and other parameters relates to the Marine Strategy Framework Directive (MSFD). This aggregated dataset contains all unrestricted EMODnet Chemistry data on eutrophication and acidity, and covers the Northeast Atlantic Ocean (40W). Data were aggregated and quality controlled by 'IFREMER / IDM / SISMER - Scientific Information Systems for the SEA' in France. ITS-90 water temperature and water body salinity variables have also been included ('as are') to complete the eutrophication and acidity data. If you use these variables for calculations, please refer to SeaDataNet for the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets . Regional datasets concerning eutrophication and acidity are automatically harvested, and the resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all sea regions ( https://doi.org/10.13120/8xm0-5m67 ). Parameter names are based on P35 vocabulary, which relates to EMODnet Chemistry aggregated parameter names and is available at: https://vocab.nerc.ac.uk/search_nvs/P35/ . When not present in original data, water body nitrate plus nitrite was calculated by summing all nitrate and nitrite parameters. The same procedure was applied for water body dissolved inorganic nitrogen (DIN), which was calculated by summing all nitrate, nitrite, and ammonium parameters. Concentrations per unit mass were converted to a unit volume using a constant density of 1.025 kg/L. The aggregated dataset can also be downloaded as an ODV collection and spreadsheet, which is composed of a metadata header followed by tab separated values. This spreadsheet can be imported to ODV Software for visualisation (more information can be found at: https://www.seadatanet.org/Software/ODV ).

This visualization product displays the size of litter in percent per net per year from specific protocols different from research and monitoring protocols. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Before 2021, there was no coordinated effort at the regional or European scale for micro-litter. Given this situation, EMODnet Chemistry proposed to adopt the data gathering and data management approach as generally applied for marine data, i.e., populating metadata and data in the CDI Data Discovery and Access service using dedicated SeaDataNet data transport formats. EMODnet Chemistry is currently the official EU collector of micro-litter data from Marine Strategy Framework Directive (MSFD) National Monitoring activities (descriptor 10). A series of specific standard vocabularies or standard terms related to micro-litter have been added to SeaDataNet NVS (NERC Vocabulary Server) Common Vocabularies to describe the micro-litter. European micro-litter data are collected by the National Oceanographic Data Centres (NODCs). Micro-litter map products are generated from NODCs data after a test of the aggregated collection including data and data format checks and data harmonization. A filter is applied to represent only micro-litter sampled according to a very specific protocol such as the Volvo Ocean Race (VOR) or Oceaneye. To calculate percentages for each size, formula applied is: Size (%) = (∑number of particles of each size)*100 / (∑number of particles of all size) When the number of micro-litters was not filled or was equal to zero, it was not possible to calculate the percentage. Standard vocabularies for micro-litter size classes are taken from Seadatanet's H03 library (https://vocab.seadatanet.org/v_bodc_vocab_v2/search.asp?lib=H03 ). Different protocols with different degrees of precision were used to classify the sampled micro-litters. Consequently, on the map, the distribution of micro-litter in the size classes depends on the protocol applied during the survey. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the National Oceanographic Data Centre (NODC) for this area.

This visualization product displays the spatial distribution of the sampling effort over the six-years' period 2017-2022 from research and monitoring protocols. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Before 2021, there was no coordinated effort at the regional or European scale for micro-litter. Given this situation, EMODnet Chemistry proposed to adopt the data gathering and data management approach as generally applied for marine data, i.e., populating metadata and data in the CDI Data Discovery and Access service using dedicated SeaDataNet data transport formats. EMODnet Chemistry is currently the official EU collector of micro-litter data from Marine Strategy Framework Directive (MSFD) National Monitoring activities (descriptor 10). A series of specific standard vocabularies or standard terms related to micro-litter have been added to SeaDataNet NVS (NERC Vocabulary Server) Common Vocabularies to describe the micro-litter. European micro-litter data are collected by the National Oceanographic Data Centres (NODCs). Micro-litter map products are generated from NODCs data after a test of the aggregated collection including data and data format checks and data harmonization. A filter is applied to represent only micro-litter samplings carried out according to research and monitoring protocols as MSFD monitoring. The spatial distribution was then determined by calculating the number of times each cell was sampled during the period 2017-2022. The corresponding total distance (kms) sampled in each cell is also provided in the attribute table. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the National Oceanographic Data Centre (NODC) for this area.

Seasonal climatology of Water body dissolved oxygen concentration for Loire river for the period 1950-2024 and for the following seasons: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Observation data span from 1950 to 2024. Depth levels (m): [0.0, 2.0, 4.0, 6.0, 8.0, 10.0, 15.0, 20.0, 25.0, 30.0, 35.0, 40.0, 45.0, 50.0, 60.0, 70.0, 80.0, 90.0, 100.0, 110.0, 120.0, 130.0]. Data sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: the computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.12, using GEBCO 15 sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps is 0.01 degrees. Horizontal correlation length is defined seasonally (in meters): 150000 (winter), 100000 (spring), 70000 (summer), 115000 (autumn). Vertical correlation length was optimized and vertically filtered and a seasonally-averaged profile was used (DIVAnd.fitvertlen). Signal-to-noise ratio was fixed to 1 for vertical profiles and 0.1 for time series to account for the redundancy in the time series observations. A logarithmic transformation (DIVAnd.loglin) was applied to the data prior to the analysis. Background field: the vertically-filtered data mean profile is substracted from the data. Detrending of data: no, advection constraint applied: no. Units: umol/l.

This visualization product displays the cigarette related items abundance of marine macro-litter (> 2.5cm) per beach per year from non-MSFD monitoring surveys, research & cleaning operations without UNEP-MARLIN data. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of beach litter have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols and reference lists used on a European scale. Preliminary processings were necessary to harmonize all the data: - Exclusion of OSPAR 1000 protocol: in order to follow the approach of OSPAR that it is not including these data anymore in the monitoring; - Selection of surveys from non-MSFD monitoring, cleaning and research operations; - Exclusion of beaches without coordinates; - Selection of plastic bags related items only. The list of selected items is attached to this metadata. This list was created using EU Marine Beach Litter Baselines, the European Threshold Value for Macro Litter on Coastlines and the Joint list of litter categories for marine macro-litter monitoring from JRC (these three documents are attached to this metadata); - Exclusion of surveys without associated length; - Normalization of survey lengths to 100m & 1 survey / year: in some case, the survey length was not 100m, so in order to be able to compare the abundance of litter from different beaches a normalization is applied using this formula: Number of plastic bags related items of the survey (normalized by 100 m) = Number of plastic bags related items of the survey x (100 / survey length) Then, this normalized number of plastic bags related items is summed to obtain the total normalized number of plastic bags related items for each survey. Finally, the median abundance of plastic bags related items for each beach and year is calculated from these normalized abundances of plastic bags related items per survey. Percentiles 50, 75, 95 & 99 have been calculated taking into account plastic bags related items from other sources data for all years. More information is available in the attached documents. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area.

Moving 6-year analysis of Water body dissolved inorganic nitrogen (DIN) in the Mediterranean Sea for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 6-year centered average of the season. 6-years periods span from 1990-1995 until 2018-2023. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.12, using GEBCO 30sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.125 degrees (around 13.5km and 10.9km accordingly). The vertical resolution is 21 depth levels: [0.,5.,10.,20.,30.,50.,75.,100.,125.,150.,200.,250.,300.,400.,500.,600.,700.,800.,900.,1000.,1100.]. The horizontal correlation length is 200km. The vertical correlation length (in meters) was set twices the vertical resolution: [10.,10.,20.,20.,40.,50.,50.,50.,50.,100.,100.,100.,200.,200.,200.,200.,200.,200.,200.,200.,200.]. Duplicates check was performed using the following criteria for space and time: dlon=0.001deg., dlat=0.001deg., ddepth=1m, dtime=1hour, dvalue=0.1. The error variance (epsilon2) was set equal to 1 for profiles and 10 for time series to reduce the influence of close data near the coasts. An anamorphosis transformation was applied to the data (function DIVAnd.Anam.loglin) to avoid unrealistic negative values: threshold value=200. A background analysis field was used for all years (1990-2023) with correlation length equal to 600km and error variance (epsilon2) equal to 20. Quality control of the observations was applied using the interpolated field (QCMETHOD=3). Residuals (differences between the observations and the analysis (interpolated linearly to the location of the observations) were calculated. Observations with residuals outside the minimum and maximum values of the 99% quantile were discarded from the analysis. Originators of Italian data sets-List of contributors: - Brunetti Fabio (OGS) - Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 - Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 - Cataletto Bruno (OGS) - Cinzia Comici Cinzia (OGS) - Civitarese Giuseppe (OGS) - DeVittor Cinzia (OGS) - Giani Michele (OGS) - Kovacevic Vedrana (OGS) - Mosetti Renzo (OGS) - Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 - Celio Massimo (ARPA FVG) - Malaguti Antonella (ENEA) - Fonda Umani Serena (UNITS) - Bignami Francesco (ISAC/CNR) - Boldrini Alfredo (ISMAR/CNR) - Marini Mauro (ISMAR/CNR) - Miserocchi Stefano (ISMAR/CNR) - Zaccone Renata (IAMC/CNR) - Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D.,Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d'Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011.

Moving 6-year analysis of Water body chlorophyll-a in the NorthEast Atlantic for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 6-year centred average of each season. 6-year periods span from 1971/1976 until 2019/2024. Observation data span from 1971 to 2024. High-frequency observation trails were filtered to a 3h temporal resolution. Depth levels (IODE standard depths): [0.0, 5.0, 10.0, 20.0, 30.0, 40.0, 50.0, 75.0, 100.0, 125.0, 150.0, 200.0, 250.0, 300.0]. Data sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: the computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.12, using GEBCO 30 sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps is 0.1 degrees. Horizontal correlation length varies from 200km in open sea regions to 50km at the coast. Vertical correlation length is defined as twice the vertical resolution. Signal-to-noise ratio was fixed to 1 for vertical profiles and 0.1 for time series to account for the redundancy in the time series observations. A logarithmic transformation (DIVAnd.loglin) was applied to the data prior to the analysis. Background field: a vertically-filtered profile of the seasonal data mean value (including all years) is substracted from the data. Detrending of data: no, advection constraint applied: no. Units: mg/m3.

Moving 6-year analysis and visualization of Water body dissolved oxygen concentration in the North Sea. Four seasons (December-February, March-May, June-August, September-November). Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVAnd (Data-Interpolating Variational Analysis) tool, version 2.7.12. results were subjected to the minfield option in DIVAnd to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. The depth dimension allows visualizing the gridded field at various depths.

This dataset comprises energy density and proximal composition (water, ash, lipid and protein contents) for anchovy (Engraulis encrasicolus) and sardine (Sardina pilchardus) from the Bay of Biscay, the English Channel and the southern North Sea between 2014 and 2017. Fish were sampled throughout various seasons thanks to the PELGAS (May, Bay of Biscay), EVHOE (October-November, Bay of Biscay), CGFS and CAMANOC (September-October, English Channel) surveys conducted by IFREMER on the RV “Thalassa”, to the JUVENA (September-October, Bay of Biscay) survey conducted by AZTI, and from commercial landings within the European Data Collection Framework (DCF) during the CAPTAIN project (France Filière Pêche). During the surveys, pelagic (PELGAS and JUVENA) or demersal (EVHOE and CGFS) trawl hauls are undertaken to identify species and measure individual fish traits. Professional sampling was performed from pelagic trawl or purse-seine catches. From the various surveys, a sub-sampling of the trawls was performed to cover as much as possible the spatial extent of the surveys along the french coast. From the various selected trawls, a sub-sampling of 5 fish per size class (when possible) was performed to cover the size range of each species, based on the following size classes : sardine (1 : <15 cm ; 2 : 15-20 cm ; 3 : >20cm), anchovy (1 : <10cm ; 2 : 10-14 cm ; 3 : >14cm). Each fish was individually measured to the nearest tenth of a centimeter and weighted to the nearest tenth of a gram. These measurements were taken either at sea or later in the laboratory. The collected fish were frozen individually at -20°C before laboratory processing. In the laboratory, maturity stages were determined following ICES guidelines (ICES, 2008) based on macroscopic gonads observation and using a six-stage key as follows: stages 1 & 2 indicate immature and developing individuals, stages 3–5 indicate three steps of increasing gonad development and the spawning period (stage 3: partial pre-spawning; stage 4: spawning (hydrated); stage 5: partial post-spawning), and stage 6 features the final post-spawning period. Fish characterised by maturity stages 3, 4 or 5 were considered as being in an active reproductive period as opposed to fish in stages 1, 2 or 6. Fish were then ground and freeze-dried during at least 48 hours. Water content of the entire fish was determined from dry mass and wet mass ratio. Then, fish were ground again to obtain fine homogeneous dry powder for subsequent analysis. Energy density measurements were performed following the protocols of Gatti et al. (2018). Two subsamples of fish powder were placed in an adiabatic bomb calorimeter (IKA C-4000 adiabatic bomb calorimeter, IKA-WerkeGmbh & co. KG) for energy measurements. The energy density (ED, kJ.g-1 dry mass) was determined by measuring the heat released through the combustion of a small subsample, approximately 200 mg. If the coefficient of variation between the two measurements exceeded 3%, a third measurement was made. Finally, ED subsamples measurements were averaged and assigned to each individual fish. Energy density analyses were conducted on 503 individuals for anchovy and 976 individuals for sardine. Ash content was determined gravimetrically by combusting dried tissue in a muffle furnace at 550°C for six hours. Lipids and proteins were analysed by a certified laboratory (Labocea, Plouzané, France). Protein content was estimated using the Kjeldahl method. It consists in first determining the quantity of nitrogen contained in the sample, and to convert it into protein content using a conversion factor (6.25 here). Lipid content was determined by hydrolysis, using petroleum ether as an organic solvent. Carbohydrates represent less than 1% of fish mass and were thus neglected. Protein, lipid and ash content did not exactly sum to 1 in DW (anchovy: mean = 0.91, sd = 0.04; sardine: mean = 0.90, sd = 0.04). This discrepancy may arise from residual water, measurement uncertainties, or to a lesser extent the exclusion of carbohydrates. Body component contents have been normalised by dividing each component by the sum of lipids, proteins and ash content, to sum to one, enabling comparisons between fishes, assuming proportional errors across the components. A total of 116 and 104 proximate composition analyses were performed for anchovy and sardine, respectively.

Moving 6-year analysis and visualization of Water body phosphate in the North Sea. Four seasons (December-February, March-May, June-August, September-November). Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVAnd (Data-Interpolating Variational Analysis) tool, version 2.7.12. results were subjected to the minfield option in DIVAnd to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. The depth dimension allows visualizing the gridded field at various depths.