Seasonal Climatology of Chlorophyll-a for Loire River for the period 1976-2020 and for the following seasons: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December Observational data span from 1976 to 2020. Depth levels (m): -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -25.0, -20.0, -15.0, -10.0, -8.0, -6.0, -4.0, -2.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: The computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps grids is 0.01 degrees. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Signal to noise ratio was fixed to 1 for vertical profiles and to 0.1 for time series to account for the redundancy in the time series observations. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. . Detrending of data: no, Advection constraint applied: no. Units: mg/m^3.

Seasonal Climatology of Dissolved Oxygen concentration for Loire River for the period 1963-2020 and for the following seasons: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December Observational data span from 1963 to 2020. Depth levels (m): -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -25.0, -20.0, -15.0, -10.0, -8.0, -6.0, -4.0, -2.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: The computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps grids is 0.01 degrees. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Signal to noise ratio was fixed to 1 for vertical profiles and to 0.1 for time series to account for the redundancy in the time series observations. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. . Detrending of data: no, Advection constraint applied: no. Units: umol/l.

Moving 6-year analysis of Water body phosphate in the NorthEast Atlantic for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 6-year centred average of each season. 6-year periods span from 1950/1955 until 2016/2021. Observation data span from 1950 to 2021. Depth levels (IODE standard depths): [0.0, 5.0, 10.0, 20.0, 30.0, 40.0, 50.0, 75.0, 100.0, 125.0, 150.0, 200.0, 250.0, 300.0, 400.0, 500.0, 600.0, 700.0, 800.0, 900.0, 1000.0, 1100.0, 1200.0, 1300.0, 1400.0, 1500.0, 1750.0, 2000.0]. Data sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Descrption of DIVAnd analysis: the computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30 sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps is 0.1 degrees. Horizontal correlation length varies from 250km in open sea regions to 50km at the coast. Vertical correlation length is defined as twice the vertical resolution. Signal-to-noise ratio was fixed to 1 for vertical profiles and 0.1 for time series to account for the redundancy in the time series observations. A logarithmic transformation (DIVAnd.Anam.loglin) was applied to the data prior to the analysis to avoid unrealistic negative values. Background field: a vertically-filtered profile of the seasonal data mean value (including all years) is substracted from the data. Detrending of data: no, advection constraint applied: no. Units: umol/l.

Seasonal climatology of Water body silicate for Loire river for the period 1950-2021 and for the following seasons: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Observation data span from 1950 to 2021. Depth levels (m): [0.0, 2.0, 4.0, 6.0, 8.0, 10.0, 15.0, 20.0, 25.0, 30.0, 35.0, 40.0, 45.0, 50.0, 60.0, 70.0, 80.0, 90.0, 100.0, 110.0, 120.0, 130.0]. Data sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: the computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 15 sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps is 0.01 degrees. Horizontal correlation length is defined seasonally (in meters): 133000 (winter), 180000 (spring), 150000 (summer), 210000 (autumn). Vertical correlation length was optimized and vertically filtered and a seasonally-averaged profile was used (DIVAnd.fitvertlen). Signal-to-noise ratio was fixed to 1 for vertical profiles and 0.1 for time series to account for the redundancy in the time series observations. A logarithmic transformation (DIVAnd.Anam.loglin) was applied to the data prior to the analysis to avoid unrealistic negative values. Background field: the vertically-filtered data mean profile is substracted from the data. Detrending of data: no, advection constraint applied: no. Units: umol/l.

Moving 6-year analysis of Water body dissolved inorganic nitrogen in the NorthEast Atlantic for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 6-year centred average of each season. 6-year periods span from 1971/1976 until 2016/2021. Observation data span from 1971 to 2021. Depth levels (IODE standard depths): [0.0, 5.0, 10.0, 20.0, 30.0, 40.0, 50.0, 75.0, 100.0, 125.0, 150.0, 200.0, 250.0, 300.0, 400.0, 500.0, 600.0, 700.0, 800.0, 900.0, 1000.0, 1100.0, 1200.0, 1300.0, 1400.0, 1500.0, 1750.0, 2000.0]. Data sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Descrption of DIVAnd analysis: the computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30 sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps is 0.1 degrees. Horizontal correlation length varies from 400km in open sea regions to 50km at the coast. Vertical correlation length is defined as twice the vertical resolution. Signal-to-noise ratio was fixed to 1 for vertical profiles and 0.1 for time series to account for the redundancy in the time series observations. A logarithmic transformation (DIVAnd.Anam.loglin) was applied to the data prior to the analysis to avoid unrealistic negative values. Background field: a vertically-filtered profile of the seasonal data mean value (including all years) is substracted from the data. Detrending of data: no, advection constraint applied: no. Units: umol/l.

Seasonal climatology of Water body dissolved oxygen concentration for Loire river for the period 1950-2021 and for the following seasons: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Observation data span from 1950 to 2021. Depth levels (m): [0.0, 2.0, 4.0, 6.0, 8.0, 10.0, 15.0, 20.0, 25.0, 30.0, 35.0, 40.0, 45.0, 50.0, 60.0, 70.0, 80.0, 90.0, 100.0, 110.0, 120.0, 130.0]. Data sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: the computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 15 sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps is 0.01 degrees. Horizontal correlation length is defined seasonally (in meters): 150000 (winter), 100000 (spring), 70000 (summer), 115000 (autumn). Vertical correlation length was optimized and vertically filtered and a seasonally-averaged profile was used (DIVAnd.fitvertlen). Signal-to-noise ratio was fixed to 1 for vertical profiles and 0.1 for time series to account for the redundancy in the time series observations. A logarithmic transformation (DIVAnd.Anam.loglin) was applied to the data prior to the analysis to avoid unrealistic negative values. Background field: the vertically-filtered data mean profile is substracted from the data. Detrending of data: no, advection constraint applied: no. Units: umol/l.

Moving 6-year analysis and visualization of DIN in the North Sea. Four seasons (December-February, March-May, June-August, September-November). Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVAnd (Data-Interpolating Variational Analysis) tool, version 2.7.9. results were subjected to the minfield option in DIVAnd to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. The depth dimension allows visualizing the gridded field at various depths.

Moving 6-year analysis and visualization of Water body phosphate in the North Sea. Four seasons (December-February, March-May, June-August, September-November). Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVAnd (Data-Interpolating Variational Analysis) tool, version 2.7.9. results were subjected to the minfield option in DIVAnd to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. The depth dimension allows visualizing the gridded field at various depths.

This product displays the stations where fluoranthene has been measured and the values present in EMODnet Chemistry infrastructure are always below the limit of detection or quantification (LOD/LOQ), i.e quality values found in EMODnet validated dataset can be equal to 6 or Q. It is necessary to take into account that LOD/LOQ can change with time. These products aggregate data by station, producing only one final value for each station (above, below or above/below). EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

Seasonal Climatology of Dissolved Inorganic Nitrogen (DIN) for Loire River for the period 1990-2019 and for the following seasons: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December Observational data span from 1990 to 2019. Depth levels (m): -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -25.0, -20.0, -15.0, -10.0, -8.0, -6.0, -4.0, -2.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: The computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps grids is 0.01 degrees. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Signal to noise ratio was fixed to 1 for vertical profiles and to 0.1 for time series to account for the redundancy in the time series observations. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. . Detrending of data: no, Advection constraint applied: no. Units: umol/l.