'''This product has been archived''' '''DEFINITION''' Estimates of Ocean Heat Content (OHC) are obtained from integrated differences of the measured temperature and a climatology along a vertical profile in the ocean (von Schuckmann et al., 2018). The regional OHC values are then averaged from 60°S-60°N aiming i) to obtain the mean OHC as expressed in Joules per meter square (J/m2) to monitor the large-scale variability and change. ii) to monitor the amount of energy in the form of heat stored in the ocean (i.e. the change of OHC in time), expressed in Watt per square meter (W/m2). Ocean heat content is one of the six Global Climate Indicators recommended by the World Meterological Organisation for Sustainable Development Goal 13 implementation (WMO, 2017). '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the ocean shapes our perspectives for the future (von Schuckmann et al., 2020). Variations in OHC can induce changes in ocean stratification, currents, sea ice and ice shelfs (IPCC, 2019; 2021); they set time scales and dominate Earth system adjustments to climate variability and change (Hansen et al., 2011); they are a key player in ocean-atmosphere interactions and sea level change (WCRP, 2018) and they can impact marine ecosystems and human livelihoods (IPCC, 2019). '''CMEMS KEY FINDINGS''' Since the year 2005, the upper (0-700m) near-global (60°S-60°N) ocean warms at a rate of 0.6 ± 0.1 W/m2. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00234

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global ocean, the ESA Ocean Colour CCI surface Chlorophyll (mg m-3, 4 km resolution) using the OC-CCI recommended chlorophyll algorithm is made available in CMEMS format. L3 products are daily files, while the L4 are monthly composites. ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. A detailed description of calibration & validation is given in the relevant QUID, associated validation reports and quality documentation. '''Processing information:''' ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. The entire CCI data set is consistent and processing is done in one go. Both OC CCI and the REP product are versioned. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Quality / Accuracy / Calibration information:''' Detailed description of cal/val is given in the relevant QUID, associated validation reports and quality documentation. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''DOI (product) :''' https://doi.org/10.48670/moi-00101

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' The time series are derived from the regional chlorophyll reprocessed (REP) product as distributed by CMEMS. This dataset, derived from multi-sensor (SeaStar-SeaWiFS, AQUA-MODIS, NOAA20-VIIRS, NPP-VIIRS, Envisat-MERIS and Sentinel3A-OLCI) Rrs spectra produced by CNR using an in-house processing chain, is obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 (off-shore) waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 (coastal) waters, Berthon and Zibordi, 2004). The processing chain and the techniques used for algorithms merging are detailed in Colella et al. (2021). Monthly regional mean values are calculated by performing the average of 2D monthly mean (weighted by pixel area) over the region of interest. The deseasonalized time series is obtained by applying the X-11 seasonal adjustment methodology on the original time series as described in Colella et al. (2016), and then the Mann-Kendall test (Mann, 1945; Kendall, 1975) and Sens’s method (Sen, 1968) are subsequently applied to obtain the magnitude of trend. '''CONTEXT''' Phytoplankton and chlorophyll concentration as a proxy for phytoplankton respond rapidly to changes in environmental conditions, such as light, temperature, nutrients and mixing (Colella et al. 2016). The character of the response depends on the nature of the change drivers, and ranges from seasonal cycles to decadal oscillations (Basterretxea et al. 2018). Therefore, it is of critical importance to monitor chlorophyll concentration at multiple temporal and spatial scales, in order to be able to separate potential long-term climate signals from natural variability in the short term. In particular, phytoplankton in the Mediterranean Sea is known to respond to climate variability associated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al. 2018, Colella et al. 2016). '''CMEMS KEY FINDINGS''' In the Mediterranean Sea, the trend average for the 1997-2020 period is slightly negative (-0.580.62% per year). Due to the change in processing techniques and chlorophyll retrieval, this trend estimate cannot be compared directly to those previously reported. The observations time series (in grey) shows minima values have been quite constant until 2015 and then there is a little decrease up to 2020, when an absolute minimum occurs with values lower than 0.04 mg m-3. Throughout the time series, maxima are variable year by year (with absolute maximum in 2015, >0.14 mg m-3), showing an evident reduction since 2016. In the last years of the series, the decrease of chlorophyll concentrations is also observed in the deseasonalized timeseries (in green) with a marked step in 2020. This attenuation of chlorophyll values in the last years results in an overall negative trend for the Mediterranean Sea. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00259

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean- The L3 multi-sensor (supercollated) product is built from bias-corrected L3 mono-sensor (collated) products at the resolution 0.02 degrees. If the native collated resolution is N and N < 0.02 the change (degradation) of resolution is done by averaging the best quality data. If N > 0.02 the collated data are associated to the nearest neighbour without interpolation nor artificial increase of the resolution. A synthesis of the bias-corrected L3 mono-sensor (collated) files remapped at resolution R is done through a selection of data based on the following hierarchy: AVHRR_METOP_B, VIIRS_NPP, SLSTRA, SEVIRI, AVHRRL-19, MODIS_A, MODIS_T, AMSR2. This hierarchy can be changed in time depending on the health of each sensor. '''DOI (product) :''' https://doi.org/10.48670/moi-00163

'''Short description:''' For the '''Global''' Ocean '''Satellite Observations''', Brockmann Consult (BC) is providing '''Bio-Geo_Chemical (BGC)''' products based on the ESA-CCI inputs. * Upstreams: SeaWiFS, MODIS, MERIS, VIIRS-SNPP, OLCI-S3A & OLCI-S3B for the '''""multi""''' products. * Variables: Chlorophyll-a ('''CHL'''). * Temporal resolutions: '''monthly'''. * Spatial resolutions: '''4 km''' (multi). * Recent products are organized in datasets called Near Real Time ('''NRT''') and long time-series (from 1997) in datasets called Multi-Years ('''MY'''). To find these products in the catalogue, use the search keyword '''""ESA-CCI""'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00283

'''This product has been archived''' '''DEFINITION''' Estimates of Ocean Heat Content (OHC) are obtained from integrated differences of the measured temperature and a climatology along a vertical profile in the ocean (von Schuckmann et al., 2018). The regional OHC values are then averaged from 60°S-60°N aiming i) to obtain the mean OHC as expressed in Joules per meter square (J/m2) to monitor the large-scale variability and change. ii) to monitor the amount of energy in the form of heat stored in the ocean (i.e. the change of OHC in time), expressed in Watt per square meter (W/m2). Ocean heat content is one of the six Global Climate Indicators recommended by the World Meterological Organisation for Sustainable Development Goal 13 implementation (WMO, 2017). '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the ocean shapes our perspectives for the future (von Schuckmann et al., 2020). Variations in OHC can induce changes in ocean stratification, currents, sea ice and ice shelfs (IPCC, 2019; 2021); they set time scales and dominate Earth system adjustments to climate variability and change (Hansen et al., 2011); they are a key player in ocean-atmosphere interactions and sea level change (WCRP, 2018) and they can impact marine ecosystems and human livelihoods (IPCC, 2019). '''CMEMS KEY FINDINGS''' Since the year 2005, the near-surface (0-300m) near-global (60°S-60°N) ocean warms at a rate of 0.4 ± 0.1 W/m2. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00233

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS REP Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2020 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' Some coastal and shelf waters, especially between 30 and 400N showed active oligotrophication flags for 2020, with some scattered offshore locations within the same latitudinal belt also showing oligotrophication. Eutrophication index is positive only for a small number of coastal locations just north of 40oN, and south of 30oN. In general, the indicator map showed very few areas with active eutrophication flags for 2019 and for 2020. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''DEFINITION''' Important note to users: These data are not to be used for navigation. The data is 100 m resolution and as high quality as possible. It has been produced with state-of-the-art technology and validated to the best of the producer’s ability and where sufficient high-quality data were available. These data could be useful for planning and modelling purposes. The user should independently assess the adequacy of any material, data and/or information of the product before relying upon it. Neither Mercator Ocean International/Copernicus Marine Service nor the data originators are liable for any negative consequences following direct or indirect use of the product information, services, data products and/or data. Product overview: This is a satellite derived bathymetry product covering the global coastal area (where data retrieval is possible), with 100 m resolution, based on Sentinel-2. This global coastal product has been developed based on 3 methodologies: Intertidal Satellite-Derived Bathymetry; Physics-based optical Satellite-Derived Bathymetry from RTE inversion; and Wave Kinematics Satellite-Derived Bathymetry from wave dispersion. There is one dataset for each of the methods (including a quality index based on uncertainty) and an additional one where the three datasets were merged (also includes a quality index). Using their expertise and special techniques the consortium tried to achieve an optimal balance between coverage and data quality. '''DOI (product):''' https://doi.org/10.48670/mds-00364

'''Short description:''' Arctic L4 sea ice concentration product based on a L3 sea ice concentration product retrieved from Sentinel-1 and RCM SAR imagery and GCOM-W AMSR2 microwave radiometer data using a deep learning algorithm (SEAICE_ARC_PHY_AUTO_L3_MYNRT_011_023), gap-filled with OSI SAF EUMETSAT sea ice concentration products and delivered on a 1 km grid. '''DOI (product) :''' https://doi.org/10.48670/mds-00344