'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318

'''Short description:''' For the '''Global''' Ocean '''Satellite Observations''', Brockmann Consult (BC) is providing '''Bio-Geo_Chemical (BGC)''' products based on the ESA-CCI inputs. * Upstreams: SeaWiFS, MODIS, MERIS, VIIRS-SNPP, OLCI-S3A & OLCI-S3B for the '''""multi""''' products. * Variables: Chlorophyll-a ('''CHL'''). * Temporal resolutions: '''monthly'''. * Spatial resolutions: '''4 km''' (multi). * Recent products are organized in datasets called Near Real Time ('''NRT''') and long time-series (from 1997) in datasets called Multi-Years ('''MY'''). To find these products in the catalogue, use the search keyword '''""ESA-CCI""'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00283

'''DEFINITION''' The temporal evolution of thermosteric sea level in an ocean layer is obtained from an integration of temperature driven ocean density variations, which are subtracted from a reference climatology to obtain the fluctuations from an average field. The products used include three global reanalyses: GLORYS, C-GLORS, ORAS5 (GLOBAL_MULTIYEAR_PHY_ENS_001_031) and two in situ based reprocessed products: CORA5.2 (INSITU_GLO_PHY_TS_OA_MY_013_052) , ARMOR-3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Additionally, the time series based on the method of von Schuckmann and Le Traon (2011) has been added. The regional thermosteric sea level values are then averaged from 60°S-60°N aiming to monitor interannual to long term global sea level variations caused by temperature driven ocean volume changes through thermal expansion as expressed in meters (m). '''CONTEXT''' The global mean sea level is reflecting changes in the Earth’s climate system in response to natural and anthropogenic forcing factors such as ocean warming, land ice mass loss and changes in water storage in continental river basins. Thermosteric sea-level variations result from temperature related density changes in sea water associated with volume expansion and contraction (Storto et al., 2018). Global thermosteric sea level rise caused by ocean warming is known as one of the major drivers of contemporary global mean sea level rise (Cazenave et al., 2018; Oppenheimer et al., 2019). '''CMEMS KEY FINDINGS''' Since the year 2005 the upper (0-2000m) near-global (60°S-60°N) thermosteric sea level rises at a rate of 1.3±0.3 mm/year. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00240

'''This product has been archived''' '''DEFINITION''' Estimates of Ocean Heat Content (OHC) are obtained from integrated differences of the measured temperature and a climatology along a vertical profile in the ocean (von Schuckmann et al., 2018). The regional OHC values are then averaged from 60°S-60°N aiming i) to obtain the mean OHC as expressed in Joules per meter square (J/m2) to monitor the large-scale variability and change. ii) to monitor the amount of energy in the form of heat stored in the ocean (i.e. the change of OHC in time), expressed in Watt per square meter (W/m2). Ocean heat content is one of the six Global Climate Indicators recommended by the World Meterological Organisation for Sustainable Development Goal 13 implementation (WMO, 2017). '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the ocean shapes our perspectives for the future (von Schuckmann et al., 2020). Variations in OHC can induce changes in ocean stratification, currents, sea ice and ice shelfs (IPCC, 2019; 2021); they set time scales and dominate Earth system adjustments to climate variability and change (Hansen et al., 2011); they are a key player in ocean-atmosphere interactions and sea level change (WCRP, 2018) and they can impact marine ecosystems and human livelihoods (IPCC, 2019). '''CMEMS KEY FINDINGS''' Since the year 2005, the upper (0-700m) near-global (60°S-60°N) ocean warms at a rate of 0.6 ± 0.1 W/m2. Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00234

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Remote Sensing Reflectances (Rrs), and diffuse attenuation coefficient of light at 490 nm (kd490) for multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI observations (at 300m resolution). Exclusively for multi-sensor also the absorption of phytoplankton (aph443), Gelbstoff material (adg443), and the particulate backscattering (bbp443) coefficients at 443 nm are provided. Rrs is defined as the ratio of upwelling radiance and downwelling irradiance at any wavelength (412, 443, 490, 555, and 670 nm for multi-sensor, and 400, 412, 443, 490, 510, 560, 620, 665, 674, 681 and 709 nm for OLCI) and can also be expressed as the ratio of normalized water leaving Radiance (nLw) and the extra-terrestrial solar irradiance (F0). Kd490 is defined as the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column. It is related to the presence of scattering particles via the ratio between Rrs at 490 and 555 nm (490 and 560 nm for OLCI). For multi-sensor observations Kd490 is achieved via Mediterranean regional algorithm developed by GOS on the basis of MedBiOp in situ dataset (Volpe et al., 2019). The current day data temporal consistency is evaluated as Quality Index (QI): QI=(CurrentDataPixel-ClimatologyDataPixel)/STDDataPixel where QI is the difference between current data and the relevant climatological field as a signed multiple of climatological standard deviations (STDDataPixel). Inherent Optical Properties (aph443, adg443 and bbp443 at 443nm) are derived via QAAv6 model. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names :''' *dataset-oc-med-opt-multi-l3-rrs412_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-rrs443_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-rrs490_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-rrs510_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-rrs555_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-rrs670_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-kd490_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-bbp443_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-adg443_1km_daily-rt-v02 *dataset-oc-med-opt-multi-l3-aph443_1km_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs400_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs412_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs443_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs490_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs510_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs560_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs620_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs665_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs674_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs681_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-rrs709_300m_daily-rt-v02 *dataset-oc-med-opt-olci-l3-kd490_300m_daily-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00115

'''DEFINITION''' Volume transport across lines are obtained by integrating the volume fluxes along some selected sections and from top to bottom of the ocean. The values are computed from models’ daily output. The mean value over a reference period (1993-2014) and over the last full year are provided for the ensemble product and the individual reanalysis, as well as the standard deviation for the ensemble product over the reference period (1993-2014). The values are given in Sverdrup (Sv). '''CONTEXT''' The ocean transports heat and mass by vertical overturning and horizontal circulation, and is one of the fundamental dynamic components of the Earth’s energy budget (IPCC, 2013). There are spatial asymmetries in the energy budget resulting from the Earth’s orientation to the sun and the meridional variation in absorbed radiation which support a transfer of energy from the tropics towards the poles. However, there are spatial variations in the loss of heat by the ocean through sensible and latent heat fluxes, as well as differences in ocean basin geometry and current systems. These complexities support a pattern of oceanic heat transport that is not strictly from lower to high latitudes. Moreover, it is not stationary and we are only beginning to unravel its variability. '''CMEMS KEY FINDINGS''' The mean transports estimated by the ensemble global reanalysis are comparable to estimates based on observations; the uncertainties on these integrated quantities are still large in all the available products. At Drake Passage, the multi-product approach (product no. 2.4.1) is larger than the value (130 Sv) of Lumpkin and Speer (2007), but smaller than the new observational based results of Colin de Verdière and Ollitrault, (2016) (175 Sv) and Donohue (2017) (173.3 Sv). Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00247

'''This product has been archived''' For operational and online products, please visit https://marine.copernicus.eu '''Short description:''' This product consists of vertical profiles of the concentration of nitrates, phosphates and silicates, computed for each Argo float equipped with an oxygen sensor. The method called CANYON (Carbonate system and Nutrients concentration from hYdrological properties and Oxygen using a Neural-network) is based on a neural-network trained using high quality nutrient data collected over the last 30 years (GLODAPv2 data base, https://www.glodap.info/). The method is applied to each Argo float equipped with an oxygen sensor using as input the properties measured by the float (pressure, temperature, salinity, oxygen), and its date and position. '''DOI (product) :''' https://doi.org/10.48670/moi-00048 '''Product Citation:''' Please refer to our Technical FAQ for citing products: http://marine.copernicus.eu/faq/cite-cmems-products-cmems-credit/?idpage=169.

'''Short description:''' The NWSHELF_ANALYSISFORECAST_PHY_LR_004_001 is produced by a coupled hydrodynamic-biogeochemical model system with tides, implemented over the North East Atlantic and Shelf Seas at 7 km of horizontal resolution and 24 vertical levels. The product is updated daily, providing 7-day forecast for temperature, salinity, currents, sea level and mixed layer depth. Products are provided at quarter-hourly, hourly, daily de-tided (with Doodson filter), and monthly frequency. '''DOI (product) :''' https://doi.org/10.48670/mds-00367

'''Short description:''' For the Mediterranean Sea - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are processed homogeneously starting from the L2OCN products. '''DOI (product) :''' https://doi.org/10.48670/mds-00342

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261