'''Short description:''' This product consists of vertical profiles of the concentration of nutrients (nitrates, phosphates, and silicates) and carbonate system variables (total alkalinity, dissolved inorganic carbon, pH, and partial pressure of carbon dioxide), computed for each Argo float equipped with an oxygen sensor. The method called CANYON is based on a neural network trained using nutrient data (GLODAPv2 database) '''DOI (product) :''' https://doi.org/10.48670/moi-00048

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' In wavenumber spectra, the 1hz measurement error is the noise level estimated as the mean value of energy at high wavenumbers (below 20km in term of wave length). The 1hz noise level spatial distribution follows the instrumental white-noise linked to the Surface Wave Height but also connections with the backscatter coefficient. The full understanding of this hump of spectral energy (Dibarboure et al., 2013, Investigating short wavelength correlated errors on low-resolution mode altimetry, OSTST 2013 presentation) still remain to be achieved and overcome with new retracking, new editing strategy or new technology. '''DOI (product) :''' https://doi.org/10.48670/moi-00143

'''This product has been archived''' '''Short description:''' Near-Real-Time mono-mission satellite-based integral parameters derived from the directional wave spectra. Using linear propagation wave model, only wave observations that can be back-propagated to wave converging regions are considered. The dataset parameters includes partition significant wave height, partition peak period and partition peak or principal direction given along swell propagation path in space and time at a 3-hour timestep, from source to land. Validity flags are also included for each parameter and indicates the valid time steps along propagation (eg. no propagation for significant wave height close to the storm source or any integral parameter when reaching the land). The integral parameters at observation point are also available together with a quality flag based on the consistency between each propagated observation and the overall swell field.This product is processed by the WAVE-TAC multi-mission SAR data processing system. It serves in near-real time the main operational oceanography and climate forecasting centers in Europe and worldwide. It processes near-real-time data from the following SAR missions: Sentinel-1A and Sentinel-1B.One file is produced for each mission and is available in two formats: one gathering in one netcdf file all observations related to the same swell field, and for another all observations available in a 3-hour time range, and for both formats, propagated information from source to land. '''DOI (product) :''' https://doi.org/10.48670/moi-00178

'''Short description:''' For the Baltic Sea- The DMI Sea Surface Temperature L3S aims at providing daily multi-sensor supercollated data at 0.03deg. x 0.03deg. horizontal resolution, using satellite data from infra-red radiometers. Uses SST satellite products from these sensors: NOAA AVHRRs 7, 9, 11, 14, 16, 17, 18 , Envisat ATSR1, ATSR2 and AATSR. '''DOI (product) :''' https://doi.org/10.48670/moi-00154

'''This product has been archived'''                For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The low resolution ocean physics analysis and forecast for the North-West European Shelf is produced using a forecasting ocean assimilation model, with tides, at 7 km horizontal resolution. The ocean model is NEMO (Nucleus for European Modelling of the Ocean), using the 3DVar NEMOVAR system to assimilate observations. These are surface temperature, vertical profiles of temperature and salinity, and along track satellite sea level anomaly data. The model is forced by lateral boundary conditions from the UK Met Office North Atlantic Ocean forecast model and by the CMEMS Baltic forecast product [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=BALTICSEA_ANALYSISFORECAST_PHY_003_006 BALTICSEA_ANALYSISFORECAST_PHY_003_006]. The atmospheric forcing is given by the operational UK Met Office Global Atmospheric model. The river discharge is from a daily climatology. Further details of the model, including the product validation are provided in the [http://catalogue.marine.copernicus.eu/documents/QUID/CMEMS-NWS-QUID-004-001.pdf CMEMS-NWS-QUID-004-001]. Products are provided as hourly instantaneous and daily 25-hour, de-tided, averages. The datasets available are temperature, salinity, horizontal currents, sea level, mixed layer depth, and bottom temperature. Temperature, salinity and currents, as multi-level variables, are interpolated from the model 51 hybrid s-sigma terrain-following system to 24 standard geopotential depths (z-levels). Grid-points near to the model boundaries are masked. The product is updated daily, providing a 6-day forecast and the previous 2-day assimilative hindcast. See [http://catalogue.marine.copernicus.eu/documents/PUM/CMEMS-NWS-PUM-004-001_002.pdf CMEMS-NWS-PUM-004-001_002] for further details. '''Associated products:''' This model is coupled with a biogeochemistry model (ERSEM) available as CMEMS product [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=NWSHELF_ANALYSISFORECAST_BGC_004_002 NWSHELF_ANALYSISFORECAST_BGC_004_002] A reanalysis product is available from: [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=NWSHELF_MULTIYEAR_PHY_004_009 NWSHELF_MULTIYEAR_PHY_004_009]. '''DOI (product) :''' https://doi.org/10.48670/moi-00057

'''DEFINITION''' Ocean acidification is quantified by decreases in pH, which is a measure of acidity: a decrease in pH value means an increase in acidity, that is, acidification. The observed decrease in ocean pH resulting from increasing concentrations of CO2 is an important indicator of global change. The estimate of global mean pH builds on a reconstruction methodology, * Obtain values for alkalinity based on the so called “locally interpolated alkalinity regression (LIAR)” method after Carter et al., 2016; 2018. * Build on surface ocean partial pressure of carbon dioxide (CMEMS product: MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) obtained from an ensemble of Feed-Forward Neural Networks (Chau et al. 2022) which exploit sampling data gathered in the Surface Ocean CO2 Atlas (SOCAT) (https://www.socat.info/) * Derive a gridded field of ocean surface pH based on the van Heuven et al., (2011) CO2 system calculations using reconstructed pCO2 (MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) and alkalinity. The global mean average of pH at yearly time steps is then calculated from the gridded ocean surface pH field. It is expressed in pH unit on total hydrogen ion scale. In the figure, the amplitude of the uncertainty (1σ ) of yearly mean surface sea water pH varies at a range of (0.0023, 0.0029) pH unit (see Quality Information Document for more details). The trend and uncertainty estimates amount to -0.0017±0.0004e-1 pH units per year. The indicator is derived from in situ observations of CO2 fugacity (SOCAT data base, www.socat.info, Bakker et al., 2016). These observations are still sparse in space and time. Monitoring pH at higher space and time resolutions, as well as in coastal regions will require a denser network of observations and preferably direct pH measurements. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020). '''CONTEXT''' The decrease in surface ocean pH is a direct consequence of the uptake by the ocean of carbon dioxide. It is referred to as ocean acidification. The International Panel on Climate Change (IPCC) Workshop on Impacts of Ocean Acidification on Marine Biology and Ecosystems (2011) defined Ocean Acidification as “a reduction in the pH of the ocean over an extended period, typically decades or longer, which is caused primarily by uptake of carbon dioxide from the atmosphere, but can also be caused by other chemical additions or subtractions from the ocean”. The pH of contemporary surface ocean waters is already 0.1 lower than at pre-industrial times and an additional decrease by 0.33 pH units is projected over the 21st century in response to the high concentration pathway RCP8.5 (Bopp et al., 2013). Ocean acidification will put marine ecosystems at risk (e.g. Orr et al., 2005; Gehlen et al., 2011; Kroeker et al., 2013). The monitoring of surface ocean pH has become a focus of many international scientific initiatives (http://goa-on.org/) and constitutes one target for SDG14 (https://sustainabledevelopment.un.org/sdg14). '''CMEMS KEY FINDINGS''' Since the year 1985, global ocean surface pH is decreasing at a rate of -0.0017±0.0004e-1 per year. '''DOI (product):''' https://doi.org/10.48670/moi-00224

'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Level-4 product including the daily interpolated chlorophyll field with no data voids starting from the multi-sensor (MODIS-Aqua, NOAA-20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and the monthly averaged chlorophyll concentration for the multi-sensor (at 1 km resolution) and Sentinel-OLCI Level-3 (at 300m resolution). Chlorophyll field are obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. The interpolated gap-free Level-4 Chl concentration is estimated by means of a modified version of the DINEOF algorithm by GOS (Volpe et al., 2018). DINEOF is an iterative procedure in which EOF are used to reconstruct the entire field domain. As first guess, it uses the SeaWiFS-derived daily climatological values at missing pixels and satellite observations at valid pixels. The other Level-4 dataset is the time averages of the L3 fields and includes the standard deviation and the number of observations in the monthly period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Level-4 includes both monthly time averages and the daily-interpolated fields. Time averages are computed on the delayed-time data. The interpolated product starts from the L3 products at 1 km resolution. At the first iteration, DINEOF procedure uses, as first guess for each of the missing pixels the relative daily climatological pixel. A procedure to smooth out spurious spatial gradients is applied to the daily merged image (observation and climatology). From the second iteration, the procedure uses, as input for the next one, the field obtained by the EOF calculation, using only a number of modes: that is, at the second round, only the first two modes, at the third only the first three, and so on. At each iteration, the same smoothing procedure is applied between EOF output and initial observations. The procedure stops when the variance explained by the current EOF mode exceeds that of noise. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the pre+D2sence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l4-chl_1km_monthly-rt-v02 *dataset-oc-med-chl-multi-l4-interp_1km_daily-rt-v02 *dataset-oc-med-chl-olci-l4-chl_300m_monthly-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00113

'''This product has been archived'''                For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The IBI-MFC provides a high-resolution wave analysis and forecast product (run twice a day by Nologin with the support of CESGA in terms of supercomputing resources), covering the European waters, and more specifically the Iberia–Biscay–Ireland (IBI) area. The last 2 years before now (historic best estimates) as well as hourly instantaneous forecasts with a horizon of up to 10 days (updated on a daily basis) are available on the catalogue. The IBI wave model system is based on the MFWAM model and runs on a grid of 5 km of horizontal resolution forced with the ECMWF hourly wind data. The system assimilates significant wave height (SWH) altimeter data and CFOSAT wave spectral data (supplied by Météo-France), and it is forced by currents provided by the IBI ocean circulation system. The product offers hourly instantaneous fields of different wave parameters, including Wave Height, Period and Direction for total spectrum and fields of Wind Wave (or wind sea), Primary Swell Wave and Secondary Swell for partitioned wave spectra. Additionally, the IBI wave system is set up to provide internally some key parameters adequate to be used as forcing in the IBI NEMO ocean model forecast run. '''Product Citation''': Please refer to our Technical FAQ for citing products.[http://marine.copernicus.eu/faq/cite-cmems-products-cmems-credit/?idpage=169] '''DOI (Product)''': https://doi.org/10.48670/moi-00025

"''Short description:''' The IBI-MFC provides a high-resolution ocean analysis and forecast product (daily run by Nologin with the support of CESGA in terms of supercomputing resources), covering the European waters, and more specifically the Iberia–Biscay–Ireland (IBI) area. The last 2 years before now (historic best estimates) as well as forecasts of different temporal resolutions with a horizon of 10 days (updated on a daily basis) are available on the catalogue. The system is based on a eddy-resolving NEMO model application at 1/36º horizontal resolution, being Mercator-Ocean in charge of the model code development. The hydrodynamic forecast includes high frequency processes of paramount importance to characterize regional scale marine processes: tidal forcing, surges and high frequency atmospheric forcing, fresh water river discharge, wave forcing in forecast, etc. A weekly update of IBI downscaled analysis is also delivered as historic IBI best estimates. The product offers 3D daily and monthly ocean fields, as well as hourly mean and 15-minute instantaneous values for some surface variables. Daily and monthly averages of 3D Temperature, 3D Salinity, 3D Zonal, Meridional and vertical Velocity components, Mix Layer Depth, Sea Bottom Temperature and Sea Surface Height are provided. Additionally, hourly means of surface fields for variables such as Sea Surface Height, Mix Layer Depth, Surface Temperature and Currents, together with Barotropic Velocities are delivered. Doodson-filtered detided mean sea level and horizontal surface currents are also provided. Finally, 15-minute instantaneous values of Sea Surface Height and Currents are also given. '''DOI (Product)''': https://doi.org/10.48670/moi-00027