'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261

'''Short description:''' Altimeter satellite along-track sea surface heights anomalies (SLA) computed with respect to a twenty-year [1993, 2012] mean with a 1Hz (~7km) sampling. It serves in delayed-time applications. This product is processed by the DUACS multimission altimeter data processing system. It processes data from all altimeter missions available (e.g. Sentinel-6A, Jason-3, Sentinel-3A, Sentinel-3B, Saral/AltiKa, Cryosat-2, Jason-1, Jason-2, Topex/Poseidon, ERS-1, ERS-2, Envisat, Geosat Follow-On, HY-2A, HY-2B, etc). The system exploits the most recent datasets available based on the enhanced GDR/NTC production. All the missions are homogenized with respect to a reference mission. Part of the processing is fitted to the European Sea area. (see QUID document or http://duacs.cls.fr [http://duacs.cls.fr] pages for processing details). The product gives additional variables (e.g. Mean Dynamic Topography, Dynamic Atmospheric Correction, Ocean Tides, Long Wavelength Errors) that can be used to change the physical content for specific needs (see PUM document for details) “’Associated products”’ A time invariant product https://resources.marine.copernicus.eu/product-detail/SEALEVEL_GLO_PHY_NOISE_L4_STATIC_008_033/INFORMATION describing the noise level of along-track measurements is available. It is associated to the sla_filtered variable. It is a gridded product. One file is provided for the global ocean and those values must be applied for Arctic and Europe products. For Mediterranean and Black seas, one value is given in the QUID document. '''DOI (product):''' https://doi.org/10.48670/moi-00139

'''Short description:''' For the Baltic Sea- The DMI Sea Surface Temperature L3S aims at providing daily multi-sensor supercollated data at 0.03deg. x 0.03deg. horizontal resolution, using satellite data from infra-red radiometers. Uses SST satellite products from these sensors: NOAA AVHRRs 7, 9, 11, 14, 16, 17, 18 , Envisat ATSR1, ATSR2 and AATSR. '''DOI (product) :''' https://doi.org/10.48670/moi-00154

'''Short Description:''' The ocean biogeochemistry reanalysis for the North-West European Shelf is produced using the European Regional Seas Ecosystem Model (ERSEM), coupled online to the forecasting ocean assimilation model at 7 km horizontal resolution, NEMO-NEMOVAR. ERSEM (Butenschön et al. 2016) is developed and maintained at Plymouth Marine Laboratory. NEMOVAR system was used to assimilate observations of sea surface chlorophyll concentration from ocean colour satellite data and all the physical variables described in [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=NWSHELF_MULTIYEAR_PHY_004_009 NWSHELF_MULTIYEAR_PHY_004_009]. Biogeochemical boundary conditions and river inputs used climatologies; nitrogen deposition at the surface used time-varying data. The description of the model and its configuration, including the products validation is provided in the [https://documentation.marine.copernicus.eu/QUID/CMEMS-NWS-QUID-004-011.pdf CMEMS-NWS-QUID-004-011]. Products are provided as monthly and daily 25-hour, de-tided, averages. The datasets available are concentration of chlorophyll, nitrate, phosphate, oxygen, phytoplankton biomass, net primary production, light attenuation coefficient, pH, surface partial pressure of CO2, concentration of diatoms expressed as chlorophyll, concentration of dinoflagellates expressed as chlorophyll, concentration of nanophytoplankton expressed as chlorophyll, concentration of picophytoplankton expressed as chlorophyll in sea water. All, as multi-level variables, are interpolated from the model 51 hybrid s-sigma terrain-following system to 24 standard geopotential depths (z-levels). Grid-points near to the model boundaries are masked. The product is updated biannually, providing a six-month extension of the time series. See [https://documentation.marine.copernicus.eu/PUM/CMEMS-NWS-PUM-004-009-011.pdf CMEMS-NWS-PUM-004-009_011] for details. '''Associated products:''' This model is coupled with a hydrodynamic model (NEMO) available as CMEMS product [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=NWSHELF_MULTIYEAR_PHY_004_009 NWSHELF_MULTIYEAR_PHY_004_009]. An analysis-forecast product is available from: [https://resources.marine.copernicus.eu/?option=com_csw&view=details&product_id=NWSHELF_MULTIYEAR_BGC_004_011 NWSHELF_MULTIYEAR_BGC_004_011]. '''DOI (product) :''' https://doi.org/10.48670/moi-00058

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' In wavenumber spectra, the 1hz measurement error is the noise level estimated as the mean value of energy at high wavenumbers (below 20km in term of wave length). The 1hz noise level spatial distribution follows the instrumental white-noise linked to the Surface Wave Height but also connections with the backscatter coefficient. The full understanding of this hump of spectral energy (Dibarboure et al., 2013, Investigating short wavelength correlated errors on low-resolution mode altimetry, OSTST 2013 presentation) still remain to be achieved and overcome with new retracking, new editing strategy or new technology. '''DOI (product) :''' https://doi.org/10.48670/moi-00144

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- In-situ observation delivered in delayed mode. This In Situ delayed mode product integrates the best available version of in situ oxygen, chlorophyll / fluorescence and nutrients data '''DOI (product) :''' https://doi.org/10.17882/86207

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the '''Global''' Ocean '''Satellite Observations''', ACRI-ST company (Sophia Antipolis, France) is providing '''Chlorophyll-a''' and '''Optics''' products [1997 - present] based on the '''Copernicus-GlobColour''' processor. * '''Chlorophyll and Bio''' products refer to Chlorophyll-a, Primary Production (PP) and Phytoplankton Functional types (PFT). Products are based on a multi sensors/algorithms approach to provide to end-users the best estimate. Two dailies Chlorophyll-a products are distributed: ** one limited to the daily observations (called L3), ** the other based on a space-time interpolation: the '''Cloud Free''' (called L4). * '''Optics''' products refer to Reflectance (RRS), Suspended Matter (SPM), Particulate Backscattering (BBP), Secchi Transparency Depth (ZSD), Diffuse Attenuation (KD490) and Absorption Coef. (ADG/CDM). * The spatial resolution is 4 km. For Chlorophyll, a 1 km over the Atlantic (46°W-13°E , 20°N-66°N) is also available for the '''Cloud Free''' product, plus a 300m Global coastal product (OLCI S3A & S3B merged). *Products (Daily, Monthly and Climatology) are based on the merging of the sensors SeaWiFS, MODIS, MERIS, VIIRS-SNPP&JPSS1, OLCI-S3A&S3B. Additional products using only OLCI upstreams are also delivered. * Recent products are organized in datasets called NRT (Near Real Time) and long time-series in datasets called REP/MY (Multi-Year). The NRT products are provided one day after satellite acquisition and updated a few days after in Delayed Time (DT) to provide a better quality. An uncertainty is given at pixel level for all products. To find the '''Copernicus-GlobColour''' products in the catalogue, use the search keyword '''GlobColour'''. See [http://catalogue.marine.copernicus.eu/documents/QUID/CMEMS-OC-QUID-009-030-032-033-037-081-082-083-085-086-098.pdf QUID document] for a detailed description and assessment. '''DOI (product) :''' https://doi.org/10.48670/moi-00075

'''Short description:''' Arctic L3 sea ice product providing concentration, stage-of-development and floe size information retrieved from Sentinel-1 and RCM SAR imagery and GCOM-W AMSR2 microwave radiometer data using a deep learning algorithm and delivered on a 0.5 km grid. '''DOI (product) :''' https://doi.org/10.48670/mds-00343

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global ocean, the ESA Ocean Colour CCI surface Chlorophyll (mg m-3, 4 km resolution) using the OC-CCI recommended chlorophyll algorithm is made available in CMEMS format. Phytoplankton functional types (PFT) products provide daily chlorophyll concentrations of three size-classes, consisting of nano, pico and micro-phytoplankton. L3 products are daily files, while the L4 are monthly composites. ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. A detailed description of calibration & validation is given in the relevant QUID, associated validation reports and quality documentation. '''Processing information:''' ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. The entire CCI data set is consistent and processing is done in one go. Both OC CCI and the REP product are versioned. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Quality / Accuracy / Calibration information:''' Detailed description of cal/val is given in the relevant QUID, associated validation reports and quality documentation.''' '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''DOI (product) :''' https://doi.org/10.48670/moi-00097

This daily High-Resolution (HR) Level 3 gridded wind product is derived from Copernicus Sentinel-1 SAR (Synthetic Aperture Radar) observations, over the Mediterranean Sea ("MED" area). It is based on the European Space Agency (ESA) Level-2 OCN products at the highest available resolution. Although L2-OCN products already contain wind vectors, those are calculated using the CMOD5.n Geophysical Model Function (GMF) applied to the co-polarized (co-pol) VV channel (emitting in Vertical polarization and receiving in Vertical polarization). This VV GMF was mapped from scatterometer sensors (Hersbach et al., 2007) which are only able to use co-pol measurements. However, these co-pol GMF are known to lose sensitivity for wind above 20 m/s. Therefore, wind based on such GMF alone, are known to under-estimate wind speed (Polverari et al., 2022). For the L3 products winds based on SAR, we take advantage of the available cross-polarized (cross-pol) VH channel (emitting in Vertical polarization and receiving in Horizontal polarization) for which GMF were specifically derived based on C-Band SAR (Mouche et al., 2017, Mouche et al., 2019). Winds estimated from the combination of both the co-pol and cross-pol channels are referred to as dual-polarization (or dual-pol) winds. As shown in Mouche et al. (2019), taking advantage of the dual polarization strongly improves the wind estimation for high wind conditions thanks to the much greater VH channel sensitivity compared to VV. These new wind estimations are then gridded with a 0.012 degree resolution (between 0.5 and 1.2 km in zonal direction depending on the latitude and 1.3 km in meridional direction) using a cylindrical equidistant projection, independently for ascending and descending satellite passes and for each satellite (so 4 wind fields are available per day for two satellites). This dataset is generated over all Sentinel-1 mission time series starting from March 2018 and updated in delayed mode with a 4-months delay. It is also produced for 4 other different European areas. This dataset is produced and disseminated in the frame of Copernicus Marine Service.