Moving 10-years analysis of ammonium at Mediterranean Sea for each season : - winter (January-March), - spring (April-June), - summer (July-September), - autumn (October-December). Every year of the time dimension corresponds to the 10-year centered average of the winter season. Decades span from 1977-1986 until 2004-2013. Observational data span from 1970 to 2013. Depth range (IODE standard depths): -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0, -30.0, -20.0, -10.0, -5.0, -0.0. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. Profiles were interpolated at standard depths using weighted parabolic interpolation algorithm (Reiniger and Ross, 1968). GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5. DIVA settings: A constant value for signal-to-noise ratio was used equal to 3. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Originators of Italian data sets-List of contributors: o Brunetti Fabio (OGS) o Cardin Vanessa, Bensi Manuel doi:10.6092/36728450-4296-4e6a-967d-d5b6da55f306 o Cardin Vanessa, Bensi Manuel, Ursella Laura, Siena Giuseppe doi:10.6092/f8e6d18e-f877-4aa5-a983-a03b06ccb987 o Cataletto Bruno (OGS) o Cinzia Comici Cinzia (OGS) o Civitarese Giuseppe (OGS) o DeVittor Cinzia (OGS) o Giani Michele (OGS) o Kovacevic Vedrana (OGS) o Mosetti Renzo (OGS) o Solidoro C.,Beran A.,Cataletto B.,Celussi M.,Cibic T.,Comici C.,Del Negro P.,De Vittor C.,Minocci M.,Monti M.,Fabbro C.,Falconi C.,Franzo A.,Libralato S.,Lipizer M.,Negussanti J.S.,Russel H.,Valli G., doi:10.6092/e5518899-b914-43b0-8139-023718aa63f5 o Celio Massimo (ARPA FVG) o Malaguti Antonella (ENEA) o Fonda Umani Serena (UNITS) o Bignami Francesco (ISAC/CNR) o Boldrini Alfredo (ISMAR/CNR) o Marini Mauro (ISMAR/CNR) o Miserocchi Stefano (ISMAR/CNR) o Zaccone Renata (IAMC/CNR) o Lavezza, R., Dubroca, L. F. C., Ludicone, D., Kress, N., Herut, B., Civitarese, G., Cruzado, A., Lefèvre, D., Souvermezoglou, E., Yilmaz, A., Tugrul, S., and Ribera d'Alcala, M.: Compilation of quality controlled nutrient profiles from the Mediterranean Sea, doi:10.1594/PANGAEA.771907, 2011.

Moving 10-years analysis of Ammonium at Northeast Atlantic Ocean for each season: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December. Every year of the time dimension corresponds to the 10-year centred average of each season. Decades span : - from 1984-1993 until 2005-2014 (winter) - from 1980-1989 until 2005-2014 (spring) - from 1980-1989 until 2005-2014 (summer) - from 1980-1989 until 2005-2014 (autumn) Observational data span from 1962 to 2014. Depth range (IODE standard depths): -3000.0, -2500.0, -2000.0, -1750, -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -20.0, -10.0, -5.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5 DIVA settings. Signal to noise ratio and correlation length were optimized and filtered vertically and a seasonally-averaged profile was used. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no, Advection constraint applied: no. Units: umol/l

This gridded product visualizes 1960 - 2014 water body ammonium concentration (umol/l) in the North Sea domain, for each season (winter: December – February; spring: March – May; summer: June – August; autumn: September – November). It is produced as a Diva 4D analysis, version 4.6.9: a reference field of all seasonal data between 1960-2014 was used; results were logit transformed to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. Every step of the time dimension corresponds to a 10-year moving average for each season. The depth dimension allows visualizing the gridded field at various depths.

Water body ammonium - Monthly Climatology for the European Seas for the period 1960-2020 on the domain from longitude -45.0 to 70.0 degrees East and latitude 24.0 to 83.0 degrees North. Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.9, using GEBCO 30sec topography for the spatial connectivity of water masses. Horizontal correlation length and vertical correlation length vary spatially depending on the topography and domain. Depth range: 0.0, 5.0, 10.0, 15.0, 20.0, 25.0, 30.0, 35.0, 40.0, 45.0, 50.0, 55.0, 60.0, 65.0, 70.0, 75.0, 80.0, 85.0, 90.0, 95.0, 100.0, 125.0, 150.0, 175.0, 200.0, 225.0, 250.0, 275.0, 300.0, 325.0, 350.0, 375.0, 400.0, 425.0, 450.0, 475.0, 500.0, 550.0, 600.0, 650.0, 700.0, 750.0, 800.0, 850.0, 900.0, 950.0, 1000.0, 1050.0, 1100.0, 1150.0, 1200.0, 1250.0, 1300.0, 1350.0, 1400.0, 1450.0, 1500.0, 1550.0, 1600.0, 1650.0, 1700.0, 1750.0, 1800.0, 1850.0, 1900.0, 1950.0, 2000.0, 2100.0, 2200.0, 2300.0, 2400.0, 2500.0, 2600.0, 2700.0, 2800.0, 2900.0, 3000.0, 3100.0, 3200.0, 3300.0, 3400.0, 3500.0, 3600.0, 3700.0, 3800.0, 3900.0, 4000.0, 4100.0, 4200.0, 4300.0, 4400.0, 4500.0, 4600.0, 4700.0, 4800.0, 4900.0, 5000.0, 5100.0, 5200.0, 5300.0, 5400.0, 5500.0 m. Units: umol/l. The horizontal resolution of the produced DIVAnd analysis is 0.25 degrees.

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (20 parameters), and covers the North East Atlantic Ocean with 2400 CDI records divided per matrices: 122 in biota (as time series), 1689 in water (as vertical profiles), 589 in sediment (478 Vertical profiles and 111 Time series). Vertical profiles temporal range is from 1970-07-29 to 2017-02-28. Time series temporal range is from 1979-02-28 to 2014-10-21. Data were aggregated and quality controlled by ‘IFREMER / IDM / SISMER - Scientific Information Systems for the SEA’ from France. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names” ,but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 20 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search