he Global ARMOR3D L4 Reprocessed dataset is obtained by combining satellite (Sea Level Anomalies, Geostrophic Surface Currents, Sea Surface Temperature) and in-situ (Temperature and Salinity profiles) observations through statistical methods. References : - ARMOR3D: Guinehut S., A.-L. Dhomps, G. Larnicol and P.-Y. Le Traon, 2012: High resolution 3D temperature and salinity fields derived from in situ and satellite observations. Ocean Sci., 8(5):845–857. - ARMOR3D: Guinehut S., P.-Y. Le Traon, G. Larnicol and S. Philipps, 2004: Combining Argo and remote-sensing data to estimate the ocean three-dimensional temperature fields - A first approach based on simulated observations. J. Mar. Sys., 46 (1-4), 85-98. - ARMOR3D: Mulet, S., M.-H. Rio, A. Mignot, S. Guinehut and R. Morrow, 2012: A new estimate of the global 3D geostrophic ocean circulation based on satellite data and in-situ measurements. Deep Sea Research Part II : Topical Studies in Oceanography, 77–80(0):70–81.

'''DEFINITION''' Ocean acidification is quantified by decreases in pH, which is a measure of acidity: a decrease in pH value means an increase in acidity, that is, acidification. The observed decrease in ocean pH resulting from increasing concentrations of CO2 is an important indicator of global change. The estimate of global mean pH builds on a reconstruction methodology, * Obtain values for alkalinity based on the so called “locally interpolated alkalinity regression (LIAR)” method after Carter et al., 2016; 2018. * Build on surface ocean partial pressure of carbon dioxide (CMEMS product: MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) obtained from an ensemble of Feed-Forward Neural Networks (Chau et al. 2022) which exploit sampling data gathered in the Surface Ocean CO2 Atlas (SOCAT) (https://www.socat.info/) * Derive a gridded field of ocean surface pH based on the van Heuven et al., (2011) CO2 system calculations using reconstructed pCO2 (MULTIOBS_GLO_BIO_CARBON_SURFACE_REP_015_008) and alkalinity. The global mean average of pH at yearly time steps is then calculated from the gridded ocean surface pH field. It is expressed in pH unit on total hydrogen ion scale. In the figure, the amplitude of the uncertainty (1σ ) of yearly mean surface sea water pH varies at a range of (0.0023, 0.0029) pH unit (see Quality Information Document for more details). The trend and uncertainty estimates amount to -0.0017±0.0004e-1 pH units per year. The indicator is derived from in situ observations of CO2 fugacity (SOCAT data base, www.socat.info, Bakker et al., 2016). These observations are still sparse in space and time. Monitoring pH at higher space and time resolutions, as well as in coastal regions will require a denser network of observations and preferably direct pH measurements. A full discussion regarding this OMI can be found in section 2.10 of the Ocean State Report 4 (Gehlen et al., 2020). '''CONTEXT''' The decrease in surface ocean pH is a direct consequence of the uptake by the ocean of carbon dioxide. It is referred to as ocean acidification. The International Panel on Climate Change (IPCC) Workshop on Impacts of Ocean Acidification on Marine Biology and Ecosystems (2011) defined Ocean Acidification as “a reduction in the pH of the ocean over an extended period, typically decades or longer, which is caused primarily by uptake of carbon dioxide from the atmosphere, but can also be caused by other chemical additions or subtractions from the ocean”. The pH of contemporary surface ocean waters is already 0.1 lower than at pre-industrial times and an additional decrease by 0.33 pH units is projected over the 21st century in response to the high concentration pathway RCP8.5 (Bopp et al., 2013). Ocean acidification will put marine ecosystems at risk (e.g. Orr et al., 2005; Gehlen et al., 2011; Kroeker et al., 2013). The monitoring of surface ocean pH has become a focus of many international scientific initiatives (http://goa-on.org/) and constitutes one target for SDG14 (https://sustainabledevelopment.un.org/sdg14). '''CMEMS KEY FINDINGS''' Since the year 1985, global ocean surface pH is decreasing at a rate of -0.0017±0.019 decade-1 '''DOI (product):''' https://doi.org/10.48670/moi-00224

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- Gridded objective analysis fields of temperature and salinity using profiles from the in-situ near real time database are produced monthly. Objective analysis is based on a statistical estimation method that allows presenting a synthesis and a validation of the dataset, providing a support for localized experience (cruises), providing a validation source for operational models, observing seasonal cycle and inter-annual variability. '''DOI (product) :''' https://doi.org/10.48670/moi-00037

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' Global Ocean- Gridded objective analysis fields of temperature and salinity using profiles from the reprocessed in-situ global product CORA (INSITU_GLO_TS_REP_OBSERVATIONS_013_001_b) using the ISAS software. Objective analysis is based on a statistical estimation method that allows presenting a synthesis and a validation of the dataset, providing a validation source for operational models, observing seasonal cycle and inter-annual variability. '''DOI (product) :''' https://doi.org/10.48670/moi-00038

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' Global Ocean- in-situ reprocessed Carbon observations. This product contains observations and gridded files from two up-to-date carbon and biogeochemistry community data products: Surface Ocean Carbon ATlas SOCATv2021 and GLobal Ocean Data Analysis Project GLODAPv2.2021. The SOCATv2022-OBS dataset contains >25 million observations of fugacity of CO2 of the surface global ocean from 1957 to early 2022. The quality control procedures are described in Bakker et al. (2016). These observations form the basis of the gridded products included in SOCATv2020-GRIDDED: monthly, yearly and decadal averages of fCO2 over a 1x1 degree grid over the global ocean, and a 0.25x0.25 degree, monthly average for the coastal ocean. GLODAPv2.2022-OBS contains >1 million observations from individual seawater samples of temperature, salinity, oxygen, nutrients, dissolved inorganic carbon, total alkalinity and pH from 1972 to 2020. These data were subjected to an extensive quality control and bias correction described in Olsen et al. (2020). GLODAPv2-GRIDDED contains global climatologies for temperature, salinity, oxygen, nitrate, phosphate, silicate, dissolved inorganic carbon, total alkalinity and pH over a 1x1 degree horizontal grid and 33 standard depths using the observations from the previous iteration of GLODAP, GLODAPv2. SOCAT and GLODAP are based on community, largely volunteer efforts, and the data providers will appreciate that those who use the data cite the corresponding articles (see References below) in order to support future sustainability of the data products. '''DOI (product) :''' https://doi.org/10.48670/moi-00035

'''Short description:''' Global Ocean- in-situ Near Real time Carbon observations. The In Situ Thematic Assembly Centre (INS TAC) integrates near real-time in situ observation data. This Near-Real Time product contains observations of temperature, salinity and fugacity of carbon dioxide from the surface ocean. These data are collected from ICOS Ocean Thematic Centre (https://otc.icos-cp.eu/home) operational stations, using Standard Operating Procedures for the ocean carbon community. The data are quality controlled using the software QuinCe, which provides automatic Quality Control in the form of range checks, constant value and excessive gradient detection. This product is updated with new observations at a maximum frequency of once a day, depending on the connection capabilities of the platform.

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' In wavenumber spectra, the 1hz measurement error is the noise level estimated as the mean value of energy at high wavenumbers (below 20km in term of wave length). The 1hz noise level spatial distribution follows the instrumental white-noise linked to the Surface Wave Height but also connections with the backscatter coefficient. The full understanding of this hump of spectral energy (Dibarboure et al., 2013, Investigating short wavelength correlated errors on low-resolution mode altimetry, OSTST 2013 presentation) still remain to be achieved and overcome with new retracking, new editing strategy or new technology. '''DOI (product) :''' https://doi.org/10.48670/moi-00143

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global ocean, the ESA Ocean Colour CCI surface Chlorophyll (mg m-3, 4 km resolution) using the OC-CCI recommended chlorophyll algorithm is made available in CMEMS format. Phytoplankton functional types (PFT) products provide daily chlorophyll concentrations of three size-classes, consisting of nano, pico and micro-phytoplankton. L3 products are daily files, while the L4 are monthly composites. ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. A detailed description of calibration & validation is given in the relevant QUID, associated validation reports and quality documentation. '''Processing information:''' ESA-CCI data are provided by Plymouth Marine Laboratory at 4km resolution. These are processed using the same in-house software as in the operational processing. The entire CCI data set is consistent and processing is done in one go. Both OC CCI and the REP product are versioned. Standard masking criteria for detecting clouds or other contamination factors have been applied during the generation of the Rrs, i.e., land, cloud, sun glint, atmospheric correction failure, high total radiance, large solar zenith angle (actually a high air mass cutoff, but approximating to 70deg zenith), coccolithophores, negative water leaving radiance, and normalized water leaving radiance at 555 nm 0.15 Wm-2 sr-1 (McClain et al., 1995). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so called ocean colour which is affected by the presence of phytoplankton. By comparing reflectances at different wavelengths and calibrating the result against in-situ measurements, an estimate of chlorophyll content can be derived. '''Quality / Accuracy / Calibration information:''' Detailed description of cal/val is given in the relevant QUID, associated validation reports and quality documentation.''' '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''DOI (product) :''' https://doi.org/10.48670/moi-00097

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the Global Ocean- In-situ observation delivered in delayed mode. This In Situ delayed mode product integrates the best available version of in situ oxygen, chlorophyll / fluorescence and nutrients data '''DOI (product) :''' https://doi.org/10.17882/86207

'''Short description:''' For the Global Ocean- In-situ observation yearly delivery in delayed mode. The In Situ delayed mode product designed for reanalysis purposes integrates the best available version of in situ data for temperature and salinity measurements. These data are collected from main global networks (Argo, GOSUD, OceanSITES, World Ocean Database) completed by European data provided by EUROGOOS regional systems and national system by the regional INS TAC components. It is updated on a yearly basis. The time coverage has been extended in the past by integration of EN4 data for the period 1950-1990. Acces through CMEMS Catalogue after registration: http://marine.copernicus.eu/ '''Detailed description: ''' Ocean circulation models need information on the interior of the ocean to be able to generate accurate forecast. This information is only available from in-situ measurement. However this information is acquired all around the world and not easily available to the operational users. Therefore, INS TAC , by connecting to a lot of international networks, collects, controls and disseminates the relevant in-situ data to operational users . For reanalysis purposes, operational centres needs to access to the best available datasets with the best possible coverage and where additional quality control procedures have been performed. This dataset suits research community needs Each year, a new release of this product is issued containing all the observations gathered by the INS TAC global component operated by Coriolis. '''Processing information:''' From the near real time INS TAC product validated on a daily and weekly basis for forecasting purposes, a scientifically validated product is created . It s a ""reference product"" updated on a yearly basis. This product has been controlled using an objective analysis (statistical tests) method and a visual quality control (QC). This QC procedure has been developed with the main objective to improve the quality of the dataset to the level required by the climate application and the physical ocean re-analysis activities. It provides T and S weekly gridded fields and individual profiles both on their original level and interpolated level. The measured parameters, depending on the data source, are : temperature, salinity. The reference level of measurements is immersion (in meters) or pressure (in decibars). The EN4 data were converted to the CORA NetCDF format without any additional validation. '''Quality/accuracy/calibration information:''' The process is done in two steps using two different time windows, corresponding to two runs of objective analysis, with an additional visual QC inserted between. The first run was done on a window of three weeks, to capture the most doubtful profiles which were then checked visually by an operator to decide whether or not it was bad data or real oceanic phenomena. The second run was done on a weekly basis to fit the modelling needs. '''Suitability, Expected type of users / uses: ''' The product is designed for assimilation into operational models operated by ocean forecasting centres for reanalysis purposes or for research community. These users need data aggregated and quality controlled in a reliable and documented manner.