'''DEFINITION''' Ocean salt content (OSC) is defined and represented here as the volume average of the integral of salinity in the Mediterranean Sea from z1 = 0 m to z2 = 300 m depth: ¯S=1/V ∫V S dV Time series of annual mean values area averaged ocean salt content are provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and are evaluated in the upper 300m excluding the shelf areas close to the coast with a depth less than 300 m. The total estimated volume is approximately 5.7e+5 km3. '''CONTEXT''' The freshwater input from the land (river runoff) and atmosphere (precipitation) and inflow from the Black Sea and the Atlantic Ocean are balanced by the evaporation in the Mediterranean Sea. Evolution of the salt content may have an impact in the ocean circulation and dynamics which possibly will have implication on the entire Earth climate system. Thus monitoring changes in the salinity content is essential considering its link to changes in: the hydrological cycle, the water masses formation, the regional halosteric sea level and salt/freshwater transport, as well as for their impact on marine biodiversity. The OMI_CLIMATE_OSC_MEDSEA_volume_mean is based on the “multi-product” approach introduced in the seventh issue of the Ocean State Report (contribution by Aydogdu et al., 2023). Note that the estimates in Aydogdu et al. (2023) are provided monthly while here we evaluate the results per year. Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24°horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4°horizontal resolution (GLOBAL_REANALYSIS_PHY_001_031, GLORYS, C-GLORS, ORAS5, FOAM, DOI: https://doi.org/10.48670/moi-00024, Desportes et al., 2022) • Two observation-based products: CORA (INSITU_GLO_TS_REP_OBSERVATIONS_013_001_b, DOI: https://doi.org/10.17882/46219, Szekely et al., 2022) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012, DOI: https://doi.org/10.48670/moi-00052, Grenier et al., 2021). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The Mediterranean Sea salt content shows a positive trend in the upper 300 m with a continuous increase over the period 1993-2021 at rate of 7.0*10-3 ±3.1*10-4 psu yr-1. The overall ensemble mean of different products is 38.57 psu. During the early 1990s in the entire Mediterranean Sea there is a large spread in salinity with the observational based datasets showing a higher salinity, while the reanalysis products present relatively lower salinity. The maximum spread between the period 1993–2021 occurs in the 1990s with a value of 0.12 psu, and it decreases to as low as 0.02 psu by the end of the 2010s. '''DOI (product):''' https://doi.org/10.48670/mds-00325

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Level-4 product including the daily interpolated chlorophyll field with no data voids starting from the multi-sensor (MODIS-Aqua, NOAA-20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and the monthly averaged chlorophyll concentration for the multi-sensor (at 1 km resolution) and Sentinel-OLCI Level-3 (at 300m resolution). Chlorophyll field are obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. The interpolated gap-free Level-4 Chl concentration is estimated by means of a modified version of the DINEOF algorithm by GOS (Volpe et al., 2018). DINEOF is an iterative procedure in which EOF are used to reconstruct the entire field domain. As first guess, it uses the SeaWiFS-derived daily climatological values at missing pixels and satellite observations at valid pixels. The other Level-4 dataset is the time averages of the L3 fields and includes the standard deviation and the number of observations in the monthly period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Level-4 includes both monthly time averages and the daily-interpolated fields. Time averages are computed on the delayed-time data. The interpolated product starts from the L3 products at 1 km resolution. At the first iteration, DINEOF procedure uses, as first guess for each of the missing pixels the relative daily climatological pixel. A procedure to smooth out spurious spatial gradients is applied to the daily merged image (observation and climatology). From the second iteration, the procedure uses, as input for the next one, the field obtained by the EOF calculation, using only a number of modes: that is, at the second round, only the first two modes, at the third only the first three, and so on. At each iteration, the same smoothing procedure is applied between EOF output and initial observations. The procedure stops when the variance explained by the current EOF mode exceeds that of noise. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the pre+D2sence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l4-chl_1km_monthly-rt-v02 *dataset-oc-med-chl-multi-l4-interp_1km_daily-rt-v02 *dataset-oc-med-chl-olci-l4-chl_300m_monthly-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00113

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261

''' Short description: ''' For the Mediterranean Sea - the CNR diurnal sub-skin Sea Surface Temperature (SST) product provides daily gap-free (L4) maps of hourly mean sub-skin SST at 1/16° (0.0625°) horizontal resolution over the CMEMS Mediterranean Sea (MED) domain, by combining infrared satellite and model data (Marullo et al., 2014). The implementation of this product takes advantage of the consolidated operational SST processing chains that provide daily mean SST fields over the same basin (Buongiorno Nardelli et al., 2013). The sub-skin temperature is the temperature at the base of the thermal skin layer and it is equivalent to the foundation SST at night, but during daytime it can be significantly different under favorable (clear sky and low wind) diurnal warming conditions. The sub-skin SST L4 product is created by combining geostationary satellite observations aquired from SEVIRI and model data (used as first-guess) aquired from the CMEMS MED Monitoring Forecasting Center (MFC). This approach takes advantage of geostationary satellite observations as the input signal source to produce hourly gap-free SST fields using model analyses as first-guess. The resulting SST anomaly field (satellite-model) is free, or nearly free, of any diurnal cycle, thus allowing to interpolate SST anomalies using satellite data acquired at different times of the day (Marullo et al., 2014). [https://help.marine.copernicus.eu/en/articles/4444611-how-to-cite-or-reference-copernicus-marine-products-and-services How to cite] '''DOI (product) :''' https://doi.org/10.48670/moi-00170

'''Short description:''' For the Mediterranean Sea - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Near Real-Time Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are updated several times daily to provide the best product timeliness. '''DOI (product) :''' https://doi.org/10.48670/mds-00334

'''This product has been archived'''                For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' Experimental altimeter satellite along-track sea surface heights anomalies (SLA) computed with respect to a twenty-year [1993, 2012] mean with a 5Hz (~1.3km) sampling. All the missions are homogenized with respect to a reference mission (see QUID document or http://duacs.cls.fr [http://duacs.cls.fr] pages for processing details). The product gives additional variables (e.g. Mean Dynamic Topography, Dynamic Atmosphic Correction, Ocean Tides, Long Wavelength Errors, Internal tide, …) that can be used to change the physical content for specific needs This product was generated as experimental products in a CNES R&D context. It was processed by the DUACS multimission altimeter data processing system. '''DOI (product) :''' https://doi.org/10.48670/moi-00137

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' For the European Ocean- The L3 multi-sensor (supercollated) product is built from bias-corrected L3 mono-sensor (collated) products at the resolution 0.02 degrees. If the native collated resolution is N and N < 0.02 the change (degradation) of resolution is done by averaging the best quality data. If N > 0.02 the collated data are associated to the nearest neighbour without interpolation nor artificial increase of the resolution. A synthesis of the bias-corrected L3 mono-sensor (collated) files remapped at resolution R is done through a selection of data based on the following hierarchy: AVHRR_METOP_B, VIIRS_NPP, SLSTRA, SEVIRI, AVHRRL-19, MODIS_A, MODIS_T, AMSR2. This hierarchy can be changed in time depending on the health of each sensor. '''DOI (product) :''' https://doi.org/10.48670/moi-00163

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces Level-4 product includes monthly averaged datasets of the diffuse attenuation coefficient of light at 490 nm (Kd490) for multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI observations (at 300m resolution). Kd490 is the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates the water column. It is directly related to the presence of absorbing and scattering matter in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. For the multi-sensor dataset, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by the GOS. The QAA allows the inversion of the radiative transfer equations to compute the Inherent Optical Properties. Level-4 product includes monthly averages along with the standard deviation and the number of observations in the period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Time averages are computed on the delayed-time data. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names :''' *dataset-oc-med-opt-multi-l4-kd490_1km_monthly-rt-v02 *dataset-oc-med-opt-olci-l4-kd490_300m_monthly-rt '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00117

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally distributes Remote Sensing Reflectances (Rrs) and diffuse attenuation coefficient of light at 490 nm (kd490) data. These datasets derived from Rrs multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI) spectra at the state-of-the-art algorithms for multi-sensor merging. Single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. Reprocessed (multi-year) products are consistent and homogeneous in terms of format, algorithms and processing software. Rrs is defined as the ratio of upwelling radiance and downwelling irradiance at any wavelength (412, 443, 490, 555, and 670 nm). Kd490 is defined as the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates within the water column. It is directly related to the presence of scattering particles in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. Kd490 is achieved via Mediterranean regional algorithm developed by GOS on the basis of MedBiOp in situ dataset (Volpe et al., 2019). The current day data temporal consistency is evaluated as Quality Index (QI): QI=(CurrentDataPixel-ClimatologyDataPixel)/STDDataPixel where QI is the difference between current data and the relevant climatological field as a signed multiple of climatological standard deviations (STDDataPixel). Inherent Optical Properties (aph443, adg443 and bbp443 at 443nm) are derived via QAAv6 model. '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll and kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' * dataset-oc-med-opt-multi-l3-rrs412_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs490_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs510_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs555_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs670_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-kd490_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-bbp443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-adg443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-aph443_1km_daily-rep-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00116

'''Short description:''' For the '''Mediterranean Sea''' Ocean '''Satellite Observations''', the Italian National Research Council (CNR – Rome, Italy), is providing multi-years '''Bio-Geo_Chemical (BGC)''' regional datasets: * '''''plankton''''' with the phytoplankton chlorophyll concentration (CHL) evaluated via region-specific algorithms (Case 1 waters: Volpe et al., 2019, with new coefficients; Case 2 waters, Berthon and Zibordi, 2004), and the interpolated '''gap-free''' Chl concentration (to provide a "cloud free" product) estimated by means of a modified version of the DINEOF algorithm (Volpe et al., 2018); moreover, daily climatology for chlorophyll concentration is provided. * '''''pp''''' with the Integrated Primary Production (PP). '''Upstreams''': SeaWiFS, MODIS, MERIS, VIIRS-SNPP & JPSS1, OLCI-S3A & S3B for the '''"multi"''' products, and OLCI-S3A & S3B for the '''"olci"''' products '''Temporal resolutions''': monthly and daily (for '''"gap-free"''' and climatology data) '''Spatial resolution''': 1 km for '''"multi"''' and 300 meters for '''"olci"''' To find this product in the catalogue, use the search keyword '''"OCEANCOLOUR_MED_BGC_L4_MY"'''. '''DOI (product) :''' https://doi.org/10.48670/moi-00300