'''This product has been archived'''                For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' Experimental altimeter satellite along-track sea surface heights anomalies (SLA) computed with respect to a twenty-year [1993, 2012] mean with a 5Hz (~1.3km) sampling. All the missions are homogenized with respect to a reference mission (see QUID document or http://duacs.cls.fr [http://duacs.cls.fr] pages for processing details). The product gives additional variables (e.g. Mean Dynamic Topography, Dynamic Atmosphic Correction, Ocean Tides, Long Wavelength Errors, Internal tide, …) that can be used to change the physical content for specific needs This product was generated as experimental products in a CNES R&D context. It was processed by the DUACS multimission altimeter data processing system. '''DOI (product) :''' https://doi.org/10.48670/moi-00137

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces surface chlorophyll of the European region by merging the daily chlorophyll regional products over the Atlantic Ocean, the Baltic Sea, the Black Sea, and the Mediterranean Sea. Single chlorophyll daily images are the Case I – Case II products, which are produced accounting for bio-optical differences in these two water types. The mosaic is built using the following datasets: • dataset-oc-atl-chl-multi_cci-l3-chl_1km_daily-rt-v01 for the North Atlantic Ocean • dataset-oc-bal-chl-modis_a-l3-nn_1km_daily-rt-v01 for the Baltic Sea • dataset-oc-bs-chl-multi-l3-chl_1km_daily-rt-v02 for the Black Sea • dataset-oc-med-chl-multi-l3-chl_1km_daily-rt-v02 for the Mediterranean Sea. '''Processing information:''' All details about the processing can be found in relevant product description: *OCEANCOLOUR_ATL_CHL_L3_NRT_OBSERVATIONS_009_036 *OCEANCOLOUR_BAL_CHL_L3_NRT_OBSERVATIONS_009_049 *OCEANCOLOUR_BS_CHL_L3_NRT_OBSERVATIONS_009_044 *OCEANCOLOUR_MED_CHL_L3_NRT_OBSERVATIONS_009_040 '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-eur-chl-multi-l3-chl_1km_daily-rt-v02 '''DOI (product) :''' https://doi.org/10.48670/moi-00095

'''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS MY Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2021 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' The coastal and shelf waters, especially between 30 and 400N that showed active oligotrophication flags for 2020 have reduced in 2021 and a reversal to eutrophic flags can be seen in places. Again, the eutrophication index is positive only for a small number of coastal locations just north of 40oN in 2021, however south of 40oN there has been a significant increase in eutrophic flags, particularly around the Azores. In general, the 2021 indicator map showed an increase in oligotrophic areas in the Northern Atlantic and an increase in eutrophic areas in the Southern Atlantic. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. '''DOI (product):''' https://doi.org/10.48670/moi-00195

'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces Level-4 product includes monthly averaged datasets of the diffuse attenuation coefficient of light at 490 nm (Kd490) for multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI observations (at 300m resolution). Kd490 is the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates the water column. It is directly related to the presence of absorbing and scattering matter in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. For the multi-sensor dataset, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by the GOS. The QAA allows the inversion of the radiative transfer equations to compute the Inherent Optical Properties. Level-4 product includes monthly averages along with the standard deviation and the number of observations in the period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Time averages are computed on the delayed-time data. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names :''' *dataset-oc-med-opt-multi-l4-kd490_1km_monthly-rt-v02 *dataset-oc-med-opt-olci-l4-kd490_300m_monthly-rt '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00117

'''DEFINITION''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) produced by the Plymouth Marine Laboratory (PML) using the ESA Ocean Colour Climate Change Initiative processor (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT''' Phytoplankton and chlorophyll concentration as their proxy respond rapidly to changes in their physical environment. In the Mediterranean Sea, these changes are seasonal and are mostly determined by light and nutrient availability (Gregg and Rousseaux, 2014). By comparing annual mean values to the climatology, we effectively remove the seasonal signal at each grid point, while retaining information on peculiar events during the year. In particular, chlorophyll anomalies in the Mediterranean Sea can then be correlated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al 2018, Colella et al 2016). '''CMEMS KEY FINDINGS''' The 2019 average chlorophyll anomaly in the Mediterranean Sea is 1.02 mg m-3 (0.005 in log10 [mg m-3]), with a maximum value of 73 mg m-3 (1.86 log10 [mg m-3]) and a minimum value of 0.04 mg m-3 (-1.42 log10 [mg m-3]). The overall east west divided pattern reported in 2016, showing negative anomalies for the Western Mediterranean Sea and positive anomalies for the Levantine Sea (Sathyendranath et al., 2018b) is modified in 2019, with a widespread positive anomaly all over the eastern basin, which reaches the western one, up to the offshore water at the west of Sardinia. Negative anomaly values occur in the coastal areas of the basin and in some sectors of the Alboràn Sea. In the northwestern Mediterranean the values switch to be positive again in contrast to the negative values registered in 2017 anomaly. The North Adriatic Sea shows a negative anomaly offshore the Po river, but with weaker value with respect to the 2017 anomaly map.

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome, distributes Level-4 product including the daily interpolated chlorophyll field with no data voids starting from the multi-sensor (MODIS-Aqua, NOAA-20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and the monthly averaged chlorophyll concentration for the multi-sensor (at 1 km resolution) and Sentinel-OLCI Level-3 (at 300m resolution). Chlorophyll field are obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Case 1 waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 waters, Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average water type spectral signature from in situ measurements for both water types. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where pure Case II spectra are selected using a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between the observed and reference spectra and using it as weight for the final merged value. The interpolated gap-free Level-4 Chl concentration is estimated by means of a modified version of the DINEOF algorithm by GOS (Volpe et al., 2018). DINEOF is an iterative procedure in which EOF are used to reconstruct the entire field domain. As first guess, it uses the SeaWiFS-derived daily climatological values at missing pixels and satellite observations at valid pixels. The other Level-4 dataset is the time averages of the L3 fields and includes the standard deviation and the number of observations in the monthly period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Level-4 includes both monthly time averages and the daily-interpolated fields. Time averages are computed on the delayed-time data. The interpolated product starts from the L3 products at 1 km resolution. At the first iteration, DINEOF procedure uses, as first guess for each of the missing pixels the relative daily climatological pixel. A procedure to smooth out spurious spatial gradients is applied to the daily merged image (observation and climatology). From the second iteration, the procedure uses, as input for the next one, the field obtained by the EOF calculation, using only a number of modes: that is, at the second round, only the first two modes, at the third only the first three, and so on. At each iteration, the same smoothing procedure is applied between EOF output and initial observations. The procedure stops when the variance explained by the current EOF mode exceeds that of noise. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the pre+D2sence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-med-chl-multi-l4-chl_1km_monthly-rt-v02 *dataset-oc-med-chl-multi-l4-interp_1km_daily-rt-v02 *dataset-oc-med-chl-olci-l4-chl_300m_monthly-rt-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00113

'''Short description:''' For the Mediterranean Sea - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are processed homogeneously starting from the L2OCN products. '''DOI (product) :''' https://doi.org/10.48670/mds-00342

'''DEFINITION:''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) provided by the ESA Ocean Colour Climate Change Initiative (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT:''' Phytoplankton – and chlorophyll concentration as their proxy – respond rapidly to changes in their physical environment. In the North Atlantic region these changes present a distinct seasonality and are mostly determined by light and nutrient availability (González Taboada et al., 2014). By comparing annual mean values to a climatology, we effectively remove the seasonal signal at each grid point, while retaining information on potential events during the year (Gregg and Rousseaux, 2014). In particular, North Atlantic anomalies can then be correlated with oscillations in the Northern Hemisphere Temperature (Raitsos et al., 2014). Chlorophyll anomalies also provide information on the status of the North Atlantic oligotrophic gyre, where evidence of rapid gyre expansion has been found for the 1997-2012 period (Polovina et al. 2008, Aiken et al., 2017, Sathyendranath et al., 2018b). '''CMEMS KEY FINDINGS:''' The average chlorophyll anomaly in the North Atlantic is -0.02 log10(mg m-3), with a maximum value of 1.0 log10(mg m-3) and a minimum value of -1.0 log10(mg m-3). That is to say that, in average, the annual 2019 mean value is slightly lower (96%) than the 1997-2014 climatological value. A moderate increase in chlorophyll concentration was observed in 2019 over the Bay of Biscay and regions close to Iceland and Greenland, such as the Irminger Basin and the Denmark Strait. In particular, the annual average values for those areas are around 160% of the 1997-2014 average (anomalies > 0.2 log10(mg m-3)). While the significant negative anomalies reported for 2016-2017 (Sathyendranath et al., 2018c) in the area west of the Ireland and Scotland coasts continued to manifest, the Irish and North Seas returned to their normative regime during 2019, with anomalies close to zero. A change in the anomaly sign (positive to negative) was also detected for the West European Basin, with annual values as low as 60% of the 1997-2014 average. This reduction in chlorophyll might be matched with negative anomalies in sea level during the period, indicating a dominance of upwelling factors over stratification.

'''Short description:''' For the Mediterranean Sea - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Near Real-Time Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are updated several times daily to provide the best product timeliness. '''DOI (product) :''' https://doi.org/10.48670/mds-00334