'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces surface chlorophyll of the European region by merging the daily chlorophyll regional products over the Atlantic Ocean, the Baltic Sea, the Black Sea, and the Mediterranean Sea. Single chlorophyll daily images are the Case I – Case II products, which are produced accounting for bio-optical differences in these two water types. The mosaic is built using the following datasets: • dataset-oc-atl-chl-multi_cci-l3-chl_1km_daily-rt-v01 for the North Atlantic Ocean • dataset-oc-bal-chl-modis_a-l3-nn_1km_daily-rt-v01 for the Baltic Sea • dataset-oc-bs-chl-multi-l3-chl_1km_daily-rt-v02 for the Black Sea • dataset-oc-med-chl-multi-l3-chl_1km_daily-rt-v02 for the Mediterranean Sea. '''Processing information:''' All details about the processing can be found in relevant product description: *OCEANCOLOUR_ATL_CHL_L3_NRT_OBSERVATIONS_009_036 *OCEANCOLOUR_BAL_CHL_L3_NRT_OBSERVATIONS_009_049 *OCEANCOLOUR_BS_CHL_L3_NRT_OBSERVATIONS_009_044 *OCEANCOLOUR_MED_CHL_L3_NRT_OBSERVATIONS_009_040 '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' *dataset-oc-eur-chl-multi-l3-chl_1km_daily-rt-v02 '''DOI (product) :''' https://doi.org/10.48670/moi-00095

'''Short description:''' For the Mediterranean Sea - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Near Real-Time Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are updated several times daily to provide the best product timeliness. '''DOI (product) :''' https://doi.org/10.48670/mds-00334

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR) in Rome distributes reprocessed surface chlorophyll concentration (Chl) and phytoplankton functional types (PFT). Input Rrs multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI) spectra at the state-of-the-art algorithms for multi-sensor merging. Single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged. Reprocessed (multi-year) products are consistent and homogeneous in terms of format, algorithms and processing software. Chl is obtained by means of the Mediterranean regional algorithms: an updated version of the MedOC4 (Volpe et al., 2019) and AD4 (Berthon and Zibordi, 2004). Discrimination between the two water types is performed by comparing the satellite spectrum with the average spectrum from in situ measurements. Reference insitu dataset is MedBiOp (Volpe et al., 2019) where Case II spectra are selected with a k-mean cluster analysis (Melin et al., 2015). Merging of Case I and Case II information is performed estimating the Mahalanobis distance between observed and reference spectra and using it as weight for the final value. The PFT provides estimates of Chl concentration of 9 phytoplankton groups: Micro, Nano, Pico, Diato, Dino, Crypto, Hapto, Green and Prokar. Micro consists of Diato and Dino, Nano includes Crypto and Hapto and Pico is referred to Green and Prokar with the adjustment of Brewin et al. (2010) in the ultra-oligotrophic water for Pico and Nano. These classes are estimated via empirical regional functions, correlating Chl concentration with each in-situ PFT fraction computed by a regional diagnostic pigment analysis (Di Cicco et al. 2017). '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll and kd490) are estimated via state-of-the-art algorithms for better product quality. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' * dataset-oc-med-chl-multi-l3-chl_1km_daily-rep-v02 * dataset-oc-med-pft-multi-l3-pft_1km_daily-rep-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00112

'''Short description:''' For the Atlantic Ocean - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are processed homogeneously starting from the L2OCN products. '''DOI (product) :''' https://doi.org/10.48670/mds-00339

'''Short description:''' The Reprocessed (REP) Mediterranean (MED) dataset provides a stable and consistent long-term Sea Surface Temperature (SST) time series over the Mediterranean Sea (and the adjacent North Atlantic box) developed for climate applications. This product consists of daily (nighttime), optimally interpolated (L4), satellite-based estimates of the foundation SST (namely, the temperature free, or nearly-free, of any diurnal cycle) at 0.05° resolution grid covering the period from 1st January 1981 to present (approximately one month before real time). The MED-REP-L4 product is built from a consistent reprocessing of the collated level-3 (merged single-sensor, L3C) climate data record (CDR) v.3.0, provided by the ESA Climate Change Initiative (CCI) and covering the period up to 2021, and its interim extension (ICDR) that allows the regular temporal extension for 2022 onwards. '''DOI (product) :''' https://doi.org/10.48670/moi-00173

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' This product includes the Mediterranean Sea satellite chlorophyll trend map from 1997 to 2020 based on regional chlorophyll reprocessed (REP) product as distributed by CMEMS OC-TAC. This dataset, derived from multi-sensor (SeaStar-SeaWiFS, AQUA-MODIS, NOAA20-VIIRS, NPP-VIIRS, Envisat-MERIS and Sentinel3A-OLCI) (at 1 km resolution) Rrs spectra produced by CNR using an in-house processing chain, is obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 (off-shore) waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 (coastal) waters, Berthon and Zibordi, 2004). The processing chain and the techniques used for algorithms merging are detailed in Colella et al. (2021). The trend map is obtained by applying Colella et al. (2016) methodology, where the Mann-Kendall test (Mann, 1945; Kendall, 1975) and Sens’s method (Sen, 1968) are applied on deseasonalized monthly time series, as obtained from the X-11 technique (see e. g. Pezzulli et al. 2005), to estimate, trend magnitude and its significance. The trend is expressed in % per year that represents the relative changes (i.e., percentage) corresponding to the dimensional trend [mg m-3 y-1] with respect to the reference climatology (1997-2014). Only significant trends (p < 0.05) are included. '''CONTEXT''' Phytoplankton are key actors in the carbon cycle and, as such, recognised as an Essential Climate Variable (ECV). Chlorophyll concentration - as a proxy for phytoplankton - respond rapidly to changes in environmental conditions, such as light, temperature, nutrients and mixing (Colella et al. 2016). The character of the response depends on the nature of the change drivers, and ranges from seasonal cycles to decadal oscillations (Basterretxea et al. 2018). The Mediterranean Sea is an oligotrophic basin, where chlorophyll concentration decreases following a specific gradient from West to East (Colella et al. 2016). The highest concentrations are observed in coastal areas and at the river mouths, where the anthropogenic pressure and nutrient loads impact on the eutrophication regimes (Colella et al. 2016). The the use of long-term time series of consistent, well-calibrated, climate-quality data record is crucial for detecting eutrophication. Furthermore, chlorophyll analysis also demands the use of robust statistical temporal decomposition techniques, in order to separate the long-term signal from the seasonal component of the time series. '''CMEMS KEY FINDINGS''' Chlorophyll trend in the Mediterranean Sea, for the period 1997-2020, is negative over most of the basin. Positive trend areas are visible only in the southern part of the western Mediterranean basin, in the Gulf of Lion, Rhode Gyre and partially along the Croatian coast of the Adriatic Sea. On average the trend in the Mediterranean Sea is about -0.5% per year. Nevertheless, as shown by Salgado-Hernanz et al. (2019) in their analysis (related to 1998-2014 satellite observations), there is not a clear difference between western and eastern basins of the Mediterranean Sea. In the Ligurian Sea, the trend switch to negative values, differing from the positive regime observed in the trend maps of both Colella et al. (2016) and Salgado-Hernanz et al. (2019), referred, respectively, to 1998-2009 and 1998-2014 time period, respectively. The waters offshore the Po River mouth show weak negative trend values, partially differing from the markable negative regime observed in the 1998-2009 period (Colella et al., 2016), and definitely moving from the positive trend observed by Salgado-Hernanz et al. (2019). Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00260

'''DEFINITION''' Ocean salt content (OSC) is defined and represented here as the volume average of the integral of salinity in the Mediterranean Sea from z1 = 0 m to z2 = 300 m depth: ¯S=1/V ∫V S dV Time series of annual mean values area averaged ocean salt content are provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and are evaluated in the upper 300m excluding the shelf areas close to the coast with a depth less than 300 m. The total estimated volume is approximately 5.7e+5 km3. '''CONTEXT''' The freshwater input from the land (river runoff) and atmosphere (precipitation) and inflow from the Black Sea and the Atlantic Ocean are balanced by the evaporation in the Mediterranean Sea. Evolution of the salt content may have an impact in the ocean circulation and dynamics which possibly will have implication on the entire Earth climate system. Thus monitoring changes in the salinity content is essential considering its link to changes in: the hydrological cycle, the water masses formation, the regional halosteric sea level and salt/freshwater transport, as well as for their impact on marine biodiversity. The OMI_CLIMATE_OSC_MEDSEA_volume_mean is based on the “multi-product” approach introduced in the seventh issue of the Ocean State Report (contribution by Aydogdu et al., 2023). Note that the estimates in Aydogdu et al. (2023) are provided monthly while here we evaluate the results per year. Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24°horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4°horizontal resolution (GLOBAL_REANALYSIS_PHY_001_031, GLORYS, C-GLORS, ORAS5, FOAM, DOI: https://doi.org/10.48670/moi-00024, Desportes et al., 2022) • Two observation-based products: CORA (INSITU_GLO_TS_REP_OBSERVATIONS_013_001_b, DOI: https://doi.org/10.17882/46219, Szekely et al., 2022) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012, DOI: https://doi.org/10.48670/moi-00052, Grenier et al., 2021). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The Mediterranean Sea salt content shows a positive trend in the upper 300 m with a continuous increase over the period 1993-2021 at rate of 7.0*10-3 ±3.1*10-4 psu yr-1. The overall ensemble mean of different products is 38.57 psu. During the early 1990s in the entire Mediterranean Sea there is a large spread in salinity with the observational based datasets showing a higher salinity, while the reanalysis products present relatively lower salinity. The maximum spread between the period 1993–2021 occurs in the 1990s with a value of 0.12 psu, and it decreases to as low as 0.02 psu by the end of the 2010s. '''DOI (product):''' https://doi.org/10.48670/mds-00325

'''DEFINITION''' The time series are derived from the regional chlorophyll reprocessed (MY) product as distributed by CMEMS (OCEANCOLOUR_MED_BGC_L3_NRT_009_141). This dataset, derived from multi-sensor (SeaStar-SeaWiFS, AQUA-MODIS, NOAA20-VIIRS, NPP-VIIRS, Envisat-MERIS and Sentinel3-OLCI) Rrs spectra produced by CNR using an in-house processing chain, is obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 (off-shore) waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 (coastal) waters, Berthon and Zibordi, 2004). The processing chain and the techniques used for algorithms merging are detailed in Colella et al. (2023). Monthly regional mean values are calculated by performing the average of 2D monthly mean (weighted by pixel area) over the region of interest. The deseasonalized time series is obtained by applying the X-11 seasonal adjustment methodology on the original time series as described in Colella et al. (2016), and then the Mann-Kendall test (Mann, 1945; Kendall, 1975) and Sens’s method (Sen, 1968) are subsequently applied to obtain the magnitude of trend. This OMI has been introduced since the 2nd issue of Ocean State Report in 2017. '''CONTEXT''' Phytoplankton and chlorophyll concentration as a proxy for phytoplankton respond rapidly to changes in environmental conditions, such as light, temperature, nutrients and mixing (Colella et al. 2016). The character of the response depends on the nature of the change drivers, and ranges from seasonal cycles to decadal oscillations (Basterretxea et al. 2018). Therefore, it is of critical importance to monitor chlorophyll concentration at multiple temporal and spatial scales, in order to be able to separate potential long-term climate signals from natural variability in the short term. In particular, phytoplankton in the Mediterranean Sea is known to respond to climate variability associated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al. 2018, Colella et al. 2016). '''KEY FINDINGS''' In the Mediterranean Sea, the average chlorophyll trend for the 1997–2024 period is slightly negative, at -0.77 ± 0.59% per year, reinforcing the findings of the previous releases. This result contrasts with the analysis by Sathyendranath et al. (2018), which reported increasing chlorophyll concentrations across all European seas. From around 2010–2011 onward, excluding the 2018–2019 period, a noticeable decline in chlorophyll levels is evident in the deseasonalized time series (green line) and in the observed maxima (grey line), particularly from 2015. This sustained decline over the past decade contributes to the overall negative trend observed in the Mediterranean Sea. '''DOI (product):''' https://doi.org/10.48670/moi-00259

'''DEFINITION''' We have derived an annual eutrophication and eutrophication indicator map for the North Atlantic Ocean using satellite-derived chlorophyll concentration. Using the satellite-derived chlorophyll products distributed in the regional North Atlantic CMEMS MY Ocean Colour dataset (OC- CCI), we derived P90 and P10 daily climatologies. The time period selected for the climatology was 1998-2017. For a given pixel, P90 and P10 were defined as dynamic thresholds such as 90% of the 1998-2017 chlorophyll values for that pixel were below the P90 value, and 10% of the chlorophyll values were below the P10 value. To minimise the effect of gaps in the data in the computation of these P90 and P10 climatological values, we imposed a threshold of 25% valid data for the daily climatology. For the 20-year 1998-2017 climatology this means that, for a given pixel and day of the year, at least 5 years must contain valid data for the resulting climatological value to be considered significant. Pixels where the minimum data requirements were met were not considered in further calculations. We compared every valid daily observation over 2021 with the corresponding daily climatology on a pixel-by-pixel basis, to determine if values were above the P90 threshold, below the P10 threshold or within the [P10, P90] range. Values above the P90 threshold or below the P10 were flagged as anomalous. The number of anomalous and total valid observations were stored during this process. We then calculated the percentage of valid anomalous observations (above/below the P90/P10 thresholds) for each pixel, to create percentile anomaly maps in terms of % days per year. Finally, we derived an annual indicator map for eutrophication levels: if 25% of the valid observations for a given pixel and year were above the P90 threshold, the pixel was flagged as eutrophic. Similarly, if 25% of the observations for a given pixel were below the P10 threshold, the pixel was flagged as oligotrophic. '''CONTEXT''' Eutrophication is the process by which an excess of nutrients – mainly phosphorus and nitrogen – in a water body leads to increased growth of plant material in an aquatic body. Anthropogenic activities, such as farming, agriculture, aquaculture and industry, are the main source of nutrient input in problem areas (Jickells, 1998; Schindler, 2006; Galloway et al., 2008). Eutrophication is an issue particularly in coastal regions and areas with restricted water flow, such as lakes and rivers (Howarth and Marino, 2006; Smith, 2003). The impact of eutrophication on aquatic ecosystems is well known: nutrient availability boosts plant growth – particularly algal blooms – resulting in a decrease in water quality (Anderson et al., 2002; Howarth et al.; 2000). This can, in turn, cause death by hypoxia of aquatic organisms (Breitburg et al., 2018), ultimately driving changes in community composition (Van Meerssche et al., 2019). Eutrophication has also been linked to changes in the pH (Cai et al., 2011, Wallace et al. 2014) and depletion of inorganic carbon in the aquatic environment (Balmer and Downing, 2011). Oligotrophication is the opposite of eutrophication, where reduction in some limiting resource leads to a decrease in photosynthesis by aquatic plants, reducing the capacity of the ecosystem to sustain the higher organisms in it. Eutrophication is one of the more long-lasting water quality problems in Europe (OSPAR ICG-EUT, 2017), and is on the forefront of most European Directives on water-protection. Efforts to reduce anthropogenically-induced pollution resulted in the implementation of the Water Framework Directive (WFD) in 2000. '''CMEMS KEY FINDINGS''' The coastal and shelf waters, especially between 30 and 400N that showed active oligotrophication flags for 2020 have reduced in 2021 and a reversal to eutrophic flags can be seen in places. Again, the eutrophication index is positive only for a small number of coastal locations just north of 40oN in 2021, however south of 40oN there has been a significant increase in eutrophic flags, particularly around the Azores. In general, the 2021 indicator map showed an increase in oligotrophic areas in the Northern Atlantic and an increase in eutrophic areas in the Southern Atlantic. The Third Integrated Report on the Eutrophication Status of the OSPAR Maritime Area (OSPAR ICG-EUT, 2017) reported an improvement from 2008 to 2017 in eutrophication status across offshore and outer coastal waters of the Greater North Sea, with a decrease in the size of coastal problem areas in Denmark, France, Germany, Ireland, Norway and the United Kingdom. '''DOI (product):''' https://doi.org/10.48670/moi-00195