'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally produces Level-4 product includes monthly averaged datasets of the diffuse attenuation coefficient of light at 490 nm (Kd490) for multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI at 300m of resolution) (at 1 km resolution) and Sentinel3A-OLCI observations (at 300m resolution). Kd490 is the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates the water column. It is directly related to the presence of absorbing and scattering matter in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. For the multi-sensor dataset, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by the GOS. The QAA allows the inversion of the radiative transfer equations to compute the Inherent Optical Properties. Level-4 product includes monthly averages along with the standard deviation and the number of observations in the period of integration. '''Processing information:''' Multi-sensor products are constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Hence, the single sensor OLCI data set is also distributed after BRDF correction. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution (300m for Sentinel3A-OLCI) using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll, kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. Time averages are computed on the delayed-time data. '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names :''' *dataset-oc-med-opt-multi-l4-kd490_1km_monthly-rt-v02 *dataset-oc-med-opt-olci-l4-kd490_300m_monthly-rt '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00117

'''Short description:''' Near Real-Time mono-mission satellite-based 2D full wave spectral product. These very complete products enable to characterise spectrally the direction, wave length and multiple sea Sates along CFOSAT track (in boxes of 70km/90km left and right from the nadir pointing). The data format are 2D directionnal matrices. They also include integrated parameters (Hs, direction, wavelength) from the spectrum with and without partitions. '''DOI (product) :''' N/A

'''DEFINITION''' The Mediterranean water mass formation rates are evaluated in 4 areas as defined in the Ocean State Report issue 2 (OSR2, von Schuckmann et al., 2018) section 3.4 (Simoncelli and Pinardi, 2018): (1) the Gulf of Lions for the Western Mediterranean Deep Waters (WMDW); (2) the Southern Adriatic Sea Pit for the Eastern Mediterranean Deep Waters (EMDW); (3) the Cretan Sea for Cretan Intermediate Waters (CIW) and Cretan Deep Waters (CDW); (4) the Rhodes Gyre, the area of formation of the so-called Levantine Intermediate Waters (LIW) and Levantine Deep Waters (LDW). Annual water mass formation rates have been computed using daily mixed layer depth estimates (density criteria Δσ = 0.01 kg/m3, 10 m reference level) considering the annual maximum volume of water above mixed layer depth with potential density within or higher the specific thresholds specified in Table 1 then divided by seconds per year. Annual mean values are provided using the Mediterranean 1/24o eddy resolving reanalysis (Escudier et al. 2020, 2021). Time spans from 1987 to the year preceding the current one [-1Y], operationally extended yearly. '''CONTEXT''' The formation of intermediate and deep water masses is one of the most important processes occurring in the Mediterranean Sea, being a component of its general overturning circulation. This circulation varies at interannual and multidecadal time scales and it is composed of an upper zonal cell (Zonal Overturning Circulation) and two main meridional cells in the western and eastern Mediterranean (Pinardi and Masetti 2000). The objective is to monitor the main water mass formation events using the eddy resolving Mediterranean Sea Reanalysis (MEDSEA_MULTIYEAR_PHY_006_004, Escudier et al. 2020, 2021) and considering Pinardi et al. (2015) and Simoncelli and Pinardi (2018) as references for the methodology. The Mediterranean Sea Reanalysis can reproduce both Eastern Mediterranean Transient and Western Mediterranean Transition phenomena and catches the principal water mass formation events reported in the literature. This will permit constant monitoring of the open ocean deep convection process in the Mediterranean Sea and a better understanding of the multiple drivers of the general overturning circulation at interannual and multidecadal time scales. Deep and intermediate water formation events reveal themselves by a deep mixed layer depth distribution in four Mediterranean areas: Gulf of Lions, Southern Adriatic Sea Pit, Cretan Sea and Rhodes Gyre. '''KEY FINDINGS''' The Western Mediterranean Deep Water (WMDW) formation events in the Gulf of Lion appear to be larger after 1999 consistently with Schroeder et al. (2006, 2008) related to the Eastern Mediterranean Transient event. This modification of WMDW after 2005 has been called Western Mediterranean Transition. WMDW formation events are consistent with Somot et al. (2016) and the event in 2009 is also reported in Houpert et al. (2016). The Eastern Mediterranean Deep Water (EMDW) formation in the Southern Adriatic Pit region displays a period of water mass formation between 1988 and 1993, in agreement with Pinardi et al. (2015), in 1996, 1999 and 2000 as documented by Manca et al. (2002). Weak deep water formation in winter 2006 is confirmed by observations in Vilibić and Šantić (2008). An intense deep water formation event is detected in 2012-2013 (Gačić et al., 2014). Last years are characterized by large events starting from 2017 (Mihanovic et al., 2021). Cretan Intermediate Water formation rates present larger peaks between 1989 and 1993 with the ones in 1992 and 1993 composing the Eastern Mediterranean Transient phenomena. The Cretan Deep Water formed in 1992 and 1993 is characterized by the highest densities of the entire period in accordance with Velaoras et al. (2014). The Levantine Deep Water formation rate in the Rhode Gyre region presents the largest values between 1992 and 1993 in agreement with Kontoyiannis et al. (1999). '''DOI (product):''' https://doi.org/10.48670/mds-00318

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''Short description:''' The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR), in Rome operationally distributes Remote Sensing Reflectances (Rrs) and diffuse attenuation coefficient of light at 490 nm (kd490) data. These datasets derived from Rrs multi-sensor (MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS, Sentinel3A-OLCI) spectra at the state-of-the-art algorithms for multi-sensor merging. Single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. Reprocessed (multi-year) products are consistent and homogeneous in terms of format, algorithms and processing software. Rrs is defined as the ratio of upwelling radiance and downwelling irradiance at any wavelength (412, 443, 490, 555, and 670 nm). Kd490 is defined as the diffuse attenuation coefficient of light at 490 nm, and is a measure of the turbidity of the water column, i.e., how visible light in the blue-green region of the spectrum penetrates within the water column. It is directly related to the presence of scattering particles in the water column and is estimated through the ratio between Rrs at 490 and 555 nm. Kd490 is achieved via Mediterranean regional algorithm developed by GOS on the basis of MedBiOp in situ dataset (Volpe et al., 2019). The current day data temporal consistency is evaluated as Quality Index (QI): QI=(CurrentDataPixel-ClimatologyDataPixel)/STDDataPixel where QI is the difference between current data and the relevant climatological field as a signed multiple of climatological standard deviations (STDDataPixel). Inherent Optical Properties (aph443, adg443 and bbp443 at 443nm) are derived via QAAv6 model. '''Processing information:''' Multi-sensor product is constituted by MODIS-AQUA, NOAA20-VIIRS, NPP-VIIRS and Sentinel3A-OLCI. For consistency with NASA L2 dataset, BRDF correction was applied to Sentinel3A-OLCI prior to band shifting and multi sensor merging. Single sensor NASA Level-2 data are destriped and then all Level-2 data are remapped at 1 km spatial resolution using cylindrical equirectangular projection. Afterwards, single sensor Rrs fields are band-shifted, over the SeaWiFS native bands (using the QAAv6 model, Lee et al., 2002) and merged with a technique aimed at smoothing the differences among different sensors. This technique is developed by The Global Ocean Satellite monitoring and marine ecosystem study group (GOS) of the Italian National Research Council (CNR, Rome). Then geophysical fields (i.e. chlorophyll and kd490, bbp, aph and adg) are estimated via state-of-the-art algorithms for better product quality. The entire data set is consistent and processed in one-shot mode (with an unique software version and identical configurations). '''Description of observation methods/instruments:''' Ocean colour technique exploits the emerging electromagnetic radiation from the sea surface in different wavelengths. The spectral variability of this signal defines the so-called ocean colour which is affected by the presence of phytoplankton. '''Quality / Accuracy / Calibration information:''' A detailed description of the calibration and validation activities performed over this product can be found on the CMEMS web portal. '''Suitability, Expected type of users / uses:''' This product is meant for use for educational purposes and for the managing of the marine safety, marine resources, marine and coastal environment and for climate and seasonal studies. '''Dataset names:''' * dataset-oc-med-opt-multi-l3-rrs412_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs490_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs510_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs555_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-rrs670_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-kd490_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-bbp443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-adg443_1km_daily-rep-v02 * dataset-oc-med-opt-multi-l3-aph443_1km_daily-rep-v02 '''Files format:''' *CF-1.4 *INSPIRE compliant '''DOI (product) :''' https://doi.org/10.48670/moi-00116

'''Short description:''' For the Atlantic Ocean - The product contains daily Level-3 sea surface wind with a 1km horizontal pixel spacing using Synthetic Aperture Radar (SAR) observations and their collocated European Centre for Medium-Range Weather Forecasts (ECMWF) model outputs. Products are processed homogeneously starting from the L2OCN products. '''DOI (product) :''' https://doi.org/10.48670/mds-00339

'''DEFINITION''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) produced by the Plymouth Marine Laboratory (PML) using the ESA Ocean Colour Climate Change Initiative processor (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT''' Phytoplankton and chlorophyll concentration as their proxy respond rapidly to changes in their physical environment. In the Mediterranean Sea, these changes are seasonal and are mostly determined by light and nutrient availability (Gregg and Rousseaux, 2014). By comparing annual mean values to the climatology, we effectively remove the seasonal signal at each grid point, while retaining information on peculiar events during the year. In particular, chlorophyll anomalies in the Mediterranean Sea can then be correlated with the North Atlantic Oscillation (NAO) and El Niño Southern Oscillation (ENSO) (Basterretxea et al 2018, Colella et al 2016). '''CMEMS KEY FINDINGS''' The 2019 average chlorophyll anomaly in the Mediterranean Sea is 1.02 mg m-3 (0.005 in log10 [mg m-3]), with a maximum value of 73 mg m-3 (1.86 log10 [mg m-3]) and a minimum value of 0.04 mg m-3 (-1.42 log10 [mg m-3]). The overall east west divided pattern reported in 2016, showing negative anomalies for the Western Mediterranean Sea and positive anomalies for the Levantine Sea (Sathyendranath et al., 2018b) is modified in 2019, with a widespread positive anomaly all over the eastern basin, which reaches the western one, up to the offshore water at the west of Sardinia. Negative anomaly values occur in the coastal areas of the basin and in some sectors of the Alboràn Sea. In the northwestern Mediterranean the values switch to be positive again in contrast to the negative values registered in 2017 anomaly. The North Adriatic Sea shows a negative anomaly offshore the Po river, but with weaker value with respect to the 2017 anomaly map.

'''DEFINITION:''' The regional annual chlorophyll anomaly is computed by subtracting a reference climatology (1997-2014) from the annual chlorophyll mean, on a pixel-by-pixel basis and in log10 space. Both the annual mean and the climatology are computed employing the regional products as distributed by CMEMS, derived by application of the regional chlorophyll algorithms over remote sensing reflectances (Rrs) provided by the ESA Ocean Colour Climate Change Initiative (ESA OC-CCI, Sathyendranath et al., 2018a). '''CONTEXT:''' Phytoplankton – and chlorophyll concentration as their proxy – respond rapidly to changes in their physical environment. In the North Atlantic region these changes present a distinct seasonality and are mostly determined by light and nutrient availability (González Taboada et al., 2014). By comparing annual mean values to a climatology, we effectively remove the seasonal signal at each grid point, while retaining information on potential events during the year (Gregg and Rousseaux, 2014). In particular, North Atlantic anomalies can then be correlated with oscillations in the Northern Hemisphere Temperature (Raitsos et al., 2014). Chlorophyll anomalies also provide information on the status of the North Atlantic oligotrophic gyre, where evidence of rapid gyre expansion has been found for the 1997-2012 period (Polovina et al. 2008, Aiken et al., 2017, Sathyendranath et al., 2018b). '''CMEMS KEY FINDINGS:''' The average chlorophyll anomaly in the North Atlantic is -0.02 log10(mg m-3), with a maximum value of 1.0 log10(mg m-3) and a minimum value of -1.0 log10(mg m-3). That is to say that, in average, the annual 2019 mean value is slightly lower (96%) than the 1997-2014 climatological value. A moderate increase in chlorophyll concentration was observed in 2019 over the Bay of Biscay and regions close to Iceland and Greenland, such as the Irminger Basin and the Denmark Strait. In particular, the annual average values for those areas are around 160% of the 1997-2014 average (anomalies > 0.2 log10(mg m-3)). While the significant negative anomalies reported for 2016-2017 (Sathyendranath et al., 2018c) in the area west of the Ireland and Scotland coasts continued to manifest, the Irish and North Seas returned to their normative regime during 2019, with anomalies close to zero. A change in the anomaly sign (positive to negative) was also detected for the West European Basin, with annual values as low as 60% of the 1997-2014 average. This reduction in chlorophyll might be matched with negative anomalies in sea level during the period, indicating a dominance of upwelling factors over stratification.

'''Short description:''' This product provides daily (nighttime), gap-free (Level-4, L4) maps of foundation Sea Surface Temperature (SST) - that is, the SST free from diurnal warming - over the Mediterranean Sea, at high (HR, 1/16°) and ultra-high (UHR, 1/100°) spatial resolutions, covering the period from 2008 to present. Each map represents nighttime SST values (centered at 00:00 UTC) and is produced by the Italian National Research Council – Institute of Marine Sciences (CNR-ISMAR). L4 maps are generated by selecting only the highest-quality SST observations from upstream Level-2 (L2) data acquired within a short local nighttime window, in order to minimize cloud contamination and avoid the effects of the diurnal cycle. The main L2 sources currently ingested include SLSTR from Sentinel-3A and -3B, VIIRS from NOAA-21, NOAA-20, and Suomi-NPP, AVHRR from Metop-B and -C, and SEVIRI. A two-step algorithm allows to interpolate SST data at high and ultra-high spatial resolution, applying statistical techniques (Buongiorno Nardelli et al., 2013; Buongiorno Nardelli et al., 2015). Additionally, from 2024 onwards, an improved first-guess field has been used in the generation of the MED UHR L4 data, enhancing the product's spatial resolution of SST features and the accuracy of SST gradients via machine learning techniques (Fanelli et al., 2024). '''DOI (product) :''' https://doi.org/10.48670/moi-00172

'''This product has been archived''' For operationnal and online products, please visit https://marine.copernicus.eu '''DEFINITION''' This product includes the Mediterranean Sea satellite chlorophyll trend map from 1997 to 2020 based on regional chlorophyll reprocessed (REP) product as distributed by CMEMS OC-TAC. This dataset, derived from multi-sensor (SeaStar-SeaWiFS, AQUA-MODIS, NOAA20-VIIRS, NPP-VIIRS, Envisat-MERIS and Sentinel3A-OLCI) (at 1 km resolution) Rrs spectra produced by CNR using an in-house processing chain, is obtained by means of the Mediterranean Ocean Colour regional algorithms: an updated version of the MedOC4 (Case 1 (off-shore) waters, Volpe et al., 2019, with new coefficients) and AD4 (Case 2 (coastal) waters, Berthon and Zibordi, 2004). The processing chain and the techniques used for algorithms merging are detailed in Colella et al. (2021). The trend map is obtained by applying Colella et al. (2016) methodology, where the Mann-Kendall test (Mann, 1945; Kendall, 1975) and Sens’s method (Sen, 1968) are applied on deseasonalized monthly time series, as obtained from the X-11 technique (see e. g. Pezzulli et al. 2005), to estimate, trend magnitude and its significance. The trend is expressed in % per year that represents the relative changes (i.e., percentage) corresponding to the dimensional trend [mg m-3 y-1] with respect to the reference climatology (1997-2014). Only significant trends (p < 0.05) are included. '''CONTEXT''' Phytoplankton are key actors in the carbon cycle and, as such, recognised as an Essential Climate Variable (ECV). Chlorophyll concentration - as a proxy for phytoplankton - respond rapidly to changes in environmental conditions, such as light, temperature, nutrients and mixing (Colella et al. 2016). The character of the response depends on the nature of the change drivers, and ranges from seasonal cycles to decadal oscillations (Basterretxea et al. 2018). The Mediterranean Sea is an oligotrophic basin, where chlorophyll concentration decreases following a specific gradient from West to East (Colella et al. 2016). The highest concentrations are observed in coastal areas and at the river mouths, where the anthropogenic pressure and nutrient loads impact on the eutrophication regimes (Colella et al. 2016). The the use of long-term time series of consistent, well-calibrated, climate-quality data record is crucial for detecting eutrophication. Furthermore, chlorophyll analysis also demands the use of robust statistical temporal decomposition techniques, in order to separate the long-term signal from the seasonal component of the time series. '''CMEMS KEY FINDINGS''' Chlorophyll trend in the Mediterranean Sea, for the period 1997-2020, is negative over most of the basin. Positive trend areas are visible only in the southern part of the western Mediterranean basin, in the Gulf of Lion, Rhode Gyre and partially along the Croatian coast of the Adriatic Sea. On average the trend in the Mediterranean Sea is about -0.5% per year. Nevertheless, as shown by Salgado-Hernanz et al. (2019) in their analysis (related to 1998-2014 satellite observations), there is not a clear difference between western and eastern basins of the Mediterranean Sea. In the Ligurian Sea, the trend switch to negative values, differing from the positive regime observed in the trend maps of both Colella et al. (2016) and Salgado-Hernanz et al. (2019), referred, respectively, to 1998-2009 and 1998-2014 time period, respectively. The waters offshore the Po River mouth show weak negative trend values, partially differing from the markable negative regime observed in the 1998-2009 period (Colella et al., 2016), and definitely moving from the positive trend observed by Salgado-Hernanz et al. (2019). Note: The key findings will be updated annually in November, in line with OMI evolutions. '''DOI (product):''' https://doi.org/10.48670/moi-00260

'''DEFINITION''' Ocean heat content (OHC) is defined here as the deviation from a reference period (1993-2014) and is closely proportional to the average temperature change from z1 = 0 m to z2 = 700 m depth: OHC=∫_(z_1)^(z_2)ρ_0 c_p (T_yr-T_clim )dz [1] with a reference density of = 1030 kgm-3 and a specific heat capacity of cp = 3980 J kg-1 °C-1 (e.g. von Schuckmann et al., 2009). Time series of annual mean values area averaged ocean heat content is provided for the Mediterranean Sea (30°N, 46°N; 6°W, 36°E) and is evaluated for topography deeper than 300m. '''CONTEXT''' Knowing how much and where heat energy is stored and released in the ocean is essential for understanding the contemporary Earth system state, variability and change, as the oceans shape our perspectives for the future. The quality evaluation of MEDSEA_OMI_OHC_area_averaged_anomalies is based on the “multi-product” approach as introduced in the second issue of the Ocean State Report (von Schuckmann et al., 2018), and following the MyOcean’s experience (Masina et al., 2017). Six global products and a regional (Mediterranean Sea) product have been used to build an ensemble mean, and its associated ensemble spread. The reference products are: • The Mediterranean Sea Reanalysis at 1/24 degree horizontal resolution (MEDSEA_MULTIYEAR_PHY_006_004, DOI: https://doi.org/10.25423/CMCC/MEDSEA_MULTIYEAR_PHY_006_004_E3R1, Escudier et al., 2020) • Four global reanalyses at 1/4 degree horizontal resolution (GLOBAL_MULTIYEAR_PHY_ENS_001_031): GLORYS, C-GLORS, ORAS5, FOAM • Two observation based products: CORA (INSITU_GLO_PHY_TS_OA_MY_013_052) and ARMOR3D (MULTIOBS_GLO_PHY_TSUV_3D_MYNRT_015_012). Details on the products are delivered in the PUM and QUID of this OMI. '''CMEMS KEY FINDINGS''' The ensemble mean ocean heat content anomaly time series over the Mediterranean Sea shows a continuous increase in the period 1993-2022 at rate of 1.38±0.08 W/m2 in the upper 700m. After 2005 the rate has clearly increased with respect the previous decade, in agreement with Iona et al. (2018). '''DOI (product):''' https://doi.org/10.48670/moi-00261