EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification, contaminants and litter. The chosen parameters are relevant for the Marine Strategy Framework Directive (MSFD), in particular for descriptors 5, 8, 9 and 10. The dataset contains standardized, harmonized and validated data collections from beach litter (monitoring and other sources). Datasets concerning beach and seafloor litter data are loaded in a central database after a semi-automated validation phase. Once loaded, a data assessment is performed in order to check data consistency and potential errors are corrected thanks to a feedback loop with data originators. For beach litter, the harmonized datasets contain all unrestricted or SeaDataNet License EMODnet Chemistry data on beach litter data, including 12390 CDI records, in which 11152 refer to monitoring data, 1208 to data from cleaning surveys and 29 to data from research. A relevant part of the monitoring data has been considered for assessment purposes by the European institutions and therefore is tagged as MSFD_monitoring. The temporal range for monitoring data is from 2001-01-01 to 2020-08-26 and includes data from 582 beaches. For data from cleaning, the temporal range is from 2013-03-12 to 2020-04-22 and includes data from 831 beaches. For data from research, the temporal range is from 2014-04-07 to 2016-10-12 and includes data from 21 beaches. EMODnet beach litter data and databases are hosted and maintained by 'Istituto Nazionale di Oceanografia e di Geofisica Sperimentale, Division of Oceanography (OGS/NODC)' from Italy. Data are formatted following Guidelines and forms for gathering marine litter data, which can be found at: https://doi.org/10.6092/15c0d34c-a01a-4091-91ac-7c4f561ab508. The updated vocabularies of admitted values are available in https://nodc.ogs.it/marinelitter/vocab. The harmonized datasets can be downloaded as EMODnet Beach litter data format Version 1.0, which is a spreadsheet file composed of 4 sheets: beach metadata, survey metadata, animals and litter. The original datasets can be searched and downloaded from EMODnet Chemistry Chemistry CDI Data and Discovery Access Service: https://emodnet-chemistry.maris.nl/search

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification, contaminants and litter. The chosen parameters are relevant for the Marine Strategy Framework Directive (MSFD), in particular for descriptors 5, 8, 9 and 10. The dataset contains standardized, harmonized and validated data collections from beach litter (monitoring and other sources). Datasets concerning beach and seafloor litter data are loaded in a central database after a semi-automated validation phase. Once loaded, a data assessment is performed in order to check data consistency and potential errors are corrected thanks to a feedback loop with data originators. For beach litter, the harmonized datasets contain all unrestricted EMODnet Chemistry data on beach litter, including monitoring data, data from cleaning surveys and data from research. A relevant part of the monitoring data has been considered for assessment purposes by the European institutions and therefore is tagged as MSFD_monitoring. EMODnet beach litter data and databases are hosted and maintained by 'Istituto Nazionale di Oceanografia e di Geofisica Sperimentale, Division of Oceanography (OGS/NODC)' from Italy. Data are formatted following Guidelines and forms for gathering marine litter data, which can be found at: https://doi.org/10.6092/15c0d34c-a01a-4091-91ac-7c4f561ab508. The updated vocabularies of admitted values are available in https://nodc.ogs.it/marinelitter/vocab. The harmonized datasets can be downloaded as EMODnet Beach litter data format Version 7.0, which is a spreadsheet file composed of 4 sheets: beach metadata, survey metadata, animals and litter.

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, acidity and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). ITS-90 water temperature and Water body salinity variables have been also included (as-is) to complete the Eutrophication and Acidity data. If you use these variables for calculations, please refer to SeaDataNet for having the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets . This aggregated dataset contains all unrestricted EMODnet Chemistry data on Eutrophication and Acidity (14 parameters with quality flag indicators), and covers the North Sea with 587584 CDI records. Data were aggregated and quality controlled by 'Aarhus University, Department of Bioscience, Marine Ecology Roskilde' from Denmark. Regional datasets concerning eutrophication and acidity are automatically harvested and resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all Sea Regions ( https://doi.org/10.6092/9f75ad8a-ca32-4a72-bf69-167119b2cc12). When not present in original data, Water body nitrate plus nitrite was calculated by summing up the Nitrates and Nitrites. Same procedure was applied for Water body dissolved inorganic nitrogen (DIN) which was calculated by summing up the Nitrates, Nitrites and Ammonium. Quality flags for Water body dissolved inorganic nitrogen (DIN) should be disregarded since that currently they are not based on the original quality flags of nitrite, nitrate and ammonium. Parameter names are based on P35, EMODnet Chemistry aggregated parameter names vocabulary, which is available at: https://www.bodc.ac.uk/resources/vocabularies/vocabulary_search/P35/. Detailed documentation is available at: https://dx.doi.org/10.6092/4e85717a-a2c9-454d-ba0d-30b89f742713 Explore and extract data at: https://emodnet-chemistry.webodv.awi.de/eutrophication>NorthSea The aggregated dataset can be downloaded as ODV collection and spreadsheet, which is composed of metadata header followed by tab separated values. This spreadsheet can be imported to ODV Software for visualisation (More information can be found at: http://www.seadatanet.org/Standards-Software/Software/ODV). The original datasets can be searched and downloaded from EMODnet Chemistry Chemistry CDI Data and Discovery Access Service: https://emodnet-chemistry.maris.nl/search

This product displays the stations where hexachlorobenzene has been measured in biota and the values present in EMODnet Chemistry infrastructure are not compliant with EQSD, i.e for the substance, in that station, quality values found in EMODnet validated dataset can be equal to 6 or Q and values are above the 30% of the value established by EQSD for hexachlorobenzene in biota. It is necessary to take into account that LOD/LOQ can change with time. These products aggregate data by station, producing only one final value for each station. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This product displays the stations present in EMODnet validated dataset where anthracene levels have been measured in sediment. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This product displays the stations where DDT has been measured and the values present in EMODnet Chemistry infrastructure are either above or below the limit of detection or quantification (LOD/LOQ), i.e for the substance, in that station, quality values found in EMODnet validated dataset can be equal to 6, Q or 1. It is necessary to take into account that LOD/LOQ can change with time. These products aggregate data by station, producing only one final value for each station (above, below or above/below). EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This product displays the stations where naphthalene has been measured and the values present in EMODnet Chemistry infrastructure are always below the limit of detection or quantification (LOD/LOQ), i.e quality values found in EMODnet validated dataset can be equal to 6 or Q. It is necessary to take into account that LOD/LOQ can change with time. These products aggregate data by station, producing only one final value for each station (above, below or above/below). EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This product displays the stations present in EMODnet validated dataset where DDT levels have been measured in water. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This product displays the stations present in EMODnet validated dataset where benzo[A]pyrene levels have been measured in sediment. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0

This product displays the stations where benzo[A]pyrene has been measured in biota and the values present in EMODnet Chemistry infrastructure are not compliant with EQSD, i.e for the substance, in that station, quality values found in EMODnet validated dataset can be equal to 6 or Q and values are above the 30% of the value established by EQSD for benzo[A]pyrene in biota. It is necessary to take into account that LOD/LOQ can change with time. These products aggregate data by station, producing only one final value for each station. EMODnet Chemistry has included the gathering of contaminants data since the beginning of the project in 2009. For the maps for EMODnet Chemistry Phase III, it was requested to plot data per matrix (water,sediment, biota), per biological entity and per chemical substance. The series of relevant map products have been developed according to the criteria D8C1 of the MSFD Directive, specifically focusing on the requirements under the new Commission Decision 2017/848 (17th May 2017). The Commission Decision points to relevant threshold values that are specified in the WFD, as well as relating how these contaminants should be expressed (units and matrix etc.) through the related Directives i.e. Priority substances for Water. EU EQS Directive does not fix any threshold values in sediments. On the contrary Regional Sea Conventions provide some of them, and these values have been taken into account for the development of the visualization products. To produce the maps the following process has been followed: 1. Data collection through SeaDataNet standards (CDI+ODV) 2. Harvesting, harmonization, validation and P01 code decomposition of data 3. SQL query on data sets from point 2 4. Production of map with each point representing at least one record that match the criteria The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols. Preliminary processing were necessary to harmonize all the data : • For water: contaminants in the dissolved phase; • For sediment: data on total sediment (regardless of size class) or size class < 2000 μm • For biota: contaminant data will focus on molluscs, on fish (only in the muscle), and on crustaceans • Exclusion of data values equal to 0